A Novel Chloropyrifos Electrochemical Sensor Based on Polyaniline/Carbon Nanotubes Composite

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Polyaniline nanofibers were prepared chemically in both emiraldine base (EB) and emiraldine salt (ES) forms. The composite of polyaniline emiraldine salt with single walled carbon nanotubes (SWCNTs) was developed. Electrochemical sensors based on polyaniline nanofibers and its composite have been developed for the detection of chloropyrifos. Chloropyrifos exhibits one well defined reduction peak. The maximum peak current was linearly related to chloropyrifos concentration in the range from 0.2 μM to 1.4 μM. It was found that the SWCNTs improved the sensitivity of the polyaniline base graphite electrode from 3.0 mA/μM for polyaniline base to 9.69 mA/μM for ES-SWCNTs composite electrode.

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99-102

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April 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] F. Masood, R. Anjum, M. Ahmad, and A. Malik. (2012). Environmental Protection Strategies for Sustainable Development. Dordrecht: Springer Netherlands. 229–260.

DOI: 10.1007/978-94-007-1591-2_7

Google Scholar

[2] R. Krieger, Hayes. (2010). 3rd Handbook of Pesticide Toxicology.

Google Scholar

[3] S. Y. Gebremariam, M. W. Beutel, D. R. Yonge, M. Flury, and J. B. Harsh. (2012). Reviews of Environmental Contamination and Toxicology. New York, NY: Springer New York. 124 – 129.

DOI: 10.1007/978-1-4614-1463-6_3

Google Scholar

[4] C. Li, C. Wang, Y. Ma, and S. Hu: Microchimica Acta 148 (2004) 27–33.

Google Scholar

[5] S. R. Ali, R. R. Parajuli, Y. Balogun, Y. Ma, and H. He: (2008). A Review. Sensors 8, 8423–8452.

Google Scholar

[6] H. Wanga, P. Yanga, H. Caia, J. Caia, Synth. Met: 162 (2012) 326– 331.

Google Scholar

[7] P. Wanga, Y. Zhengb, B. Li, Synth. Met: 166 (2013) 33– 39.

Google Scholar

[8] S.R. Ali, R. R. Parajuli, Y. Balogun, Y. Ma, H. He: Sensors 8 (2008) 8423-8452.

Google Scholar

[9] A. Sari, M. Talu, Turk. J. Chem.: 22 (1998) 301-307.

Google Scholar

[10] Sh. M. Ebrahim, A.B. Kashyout, M.M. Soliman: J. Polym. Res. 14 (2007) 423–429.

Google Scholar

[11] M.A. Rahman, P. Kumar, D.S. Park, Y.B. Shim: Sens. 8 (2008) 118-141.

Google Scholar

[12] Y. Zhang, Z. Xiao, F. Chen, Y. Ge, J. Wu, X. Hu: Ultrason. Sonochem. 17(2010) 72–77.

Google Scholar