Effect of the Interdiffusion at the Polymer/Polymer Interface on the Flexural Properties of Over-Moulded Short Glass Fibre/Glass Fabric Reinforced PA6 Composites

Abstract:

The injection over-moulding of 30wt% short glass fibre reinforced PA6 (SGF from Solvay Engineering Plastics) onto consolidated unbalanced (87/13) 70wt% glass fabric reinforced PA6 (Continuous Fibre Reinforced Thermoplastic (CFRT) from Solvay Engineering Plastics) was investigated with the objective to optimise the flexural and interlaminar shearing of the complex. Among the processing parameters, the temperature of the fabric before injection and the over-moulded melt temperature associated to the mould temperature (cooling rate of the complex) were revealed as the main parameters directing the mechanical properties of the complex. Moreover, the flexural modulus and the apparent interlaminar shear strength fall down critically in the main direction (chain direction of the fabric) under a CFRT temperature of 150°C. The effect of the SGF/CFRT interface was quantified in term of quadratic distance of diffusion through the interface. First, the 1D cooling of the complex was simulated according to the heat transfer module of COMSOL Multiphysics® in order to determinate the variation of the temperature field during the cooling stage of process. The calculations were achieved with an initial CFRT temperature of 23, 100, 150 and 200°C, the mould and SGF melt temperatures were kept constant. The diffusion theory has then been applied to calculate the variation of the auto-diffusion coefficient through the thickness during the complex cooling, the diffusion is supposed occurring only at a temperature above the PA6 crystallisation temperature (185°C). The calculation of the quadratic distance of diffusion through the thickness confirmed the mechanical results. Under a CFRT temperature of 150°C, the ability to the molecular diffusion at the interface becomes non-existent. The melt temperature of the SGF PA6 has to be sufficient to melt the CFRT PA6 interface, the time of diffusion directed by both the CFRT and mould temperatures (cooling rate) has to be long enough to allow the molecular diffusion from the material to the other.

• Periodical: Key Engineering Materials (Volumes 611-612)
• Pages: 821-828
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.611-612.821
• Online since: May 2014
• Authors: Eric Lafranche*, Thierry Renault, Patricia Krawczak
• Keywords: Continuous Glass Fibre Composite, Injection Over-Moulding, Mechanical Property, Molecular Diffusion, Polyamide 6

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