Paper Titles

Optical and Scintillation Properties of Cr Doped Y₃Ga₅O₁₂ Crystal for Infra-Red Scintillators
p.92

Growth and Luminescence Properties of Ce and Ca Co-Doped LiGdF₄-LiF Eutectic Scintillator
p.96

Effect of Annealing Temperature on Structure and Mechanical Property of Magnetron Sputtered c-BN Films
p.104

Engineering of Lead-Free Piezoelectrics in Alkali Niobate Ceramic System: Improvement in Density by Two-Step Mixing Process
p.108

Iron Composite Anodes for Fabricating All-Solid-State Iron-Air Rechargeable Batteries
p.114

Chemical Reactivity and Cathode Properties of LaCoO₃ on Lanthanum Silicate Oxyapatite Electrolyte
p.120

Preparation of Layered Double Hydroxide and its Graphene Composite Films as Electrodes for Photoelectrochemical Cells
p.129

Mesoporous Hollow Carbon Derived from Soft-Templated Hydrothermal Process for Supercapacitor Electrode
p.134

Highly (004)-Oriented Texture of γ-LiAlO₂ Films by Laser Chemical Vapor Deposition
p.141

HomeKey Engineering MaterialsKey Engineering Materials Vol. 616Iron Composite Anodes for Fabricating...

Iron Composite Anodes for Fabricating All-Solid-State Iron-Air Rechargeable Batteries

Article Preview

Abstract:

Hydroxide ion conductors containing KOH were prepared for application in an all-solid-state Fe–air battery. ZrO₂ and Mg–Al layered double hydroxide (LDH) were employed as the matrix materials. The ionic conductivity and conducting ion species were evaluated by impedance and electromotive force measurements. Repeated charge and discharge were achieved by using negative electrodes composed of the solid electrolyte and iron oxide-supported carbon.

You might also be interested in these eBooks

Advanced Ceramics and Novel Processing

Info:

Periodical:

Key Engineering Materials (Volume 616)

Pages:

114-119

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.616.114

Citation:

Cite this paper

Online since:

June 2014

Authors:

Taku Tsuneishi, Takuma Esaki, Hisatoshi Sakamoto, Kazushi Hayashi, G. Kawamura, Hiroyuki Muto, Atsunori Matsuda

Keywords:

Fe-Air Battery, Hydroxide Ion Conductor, Solid Electrolyte

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2014 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] A. Débart, A.J. Paterson, J. Bao, P.G. Bruce, α-MnO2 nanowires: a catalyst for the O2 electrode in rechargeable lithium batteries, Angew. Chem. Int. Ed. 47 (2008) 4521–4524.

DOI: 10.1002/anie.200705648

[2] F. Mizuno, S. Nakanishi, Y. Kotani, S. Yokoishi, H. Iba, Rechargeable Li–air batteries with carbonate-based liquid electrolytes, Electrochemistry 78 (2010) 403–405.

DOI: 10.5796/electrochemistry.78.403

[3] A.K. Thapa, Y. Hidaka, H. Hagiwara, S. Ida, T. Ishihara, Mesoporous β-MnO2 air electrode modified with Pd for rechargeability in Lithium–air battery, J. Electrochem. Soc. 158 (2011) A1483–A1489.

DOI: 10.1149/2.090112jes

[4] B.T. Hang, T. Watanabe, M. Egashira, S. Okada, J. Yamaki, S. Hata, S.-H. Yoon, I. Mochida, The electrochemical properties of Fe2O3-loaded carbon electrodes for iron–air battery anodes, J. Power Sources 150 (2005) 261–271.

DOI: 10.1016/j.jpowsour.2005.02.028

[5] B.T. Hang, S.-H. Yoon, S. Okada, J. Yamaki, Effect of metal-sulfide additives on electrochemical properties of nano-sized Fe2O3-loaded carbon for Fe/air battery anodes, J. Power Sources 168 (2007) 522–532.

DOI: 10.1016/j.jpowsour.2007.02.067

[6] A. Ito, L. Zhao, S. Okada, J. Yamaki, Synthesis of nano-Fe3O4-loaded tubular carbon nanofibers and their application as negative electrodes for Fe/air batteries, J. Power Sources 196 (2011) 8154–8159.

DOI: 10.1016/j.jpowsour.2011.05.043

[7] H. Kitamura, L. Zhao, B. T. Hang, S. Okada, J. Yamaki, Effect of charge current density on electrochemical performance of Fe/C electrodes in alkaline solutions, J. Electrochem. Soc. 159 (2012) A720–A724.

DOI: 10.1149/2.049206jes

[8] K. Manohar, S. Malkhandi, B. Yang, C. Yang, G.K.S. Prakash, S.R. Narayanan, A high-performance rechargeable iron electrode for large-scale battery-based energy storage, J. Electrochem. Soc. 159 (2012) A1209–A1214.

DOI: 10.1149/2.034208jes

[9] G.M. Wu, S.J. Lin, C.C. Yang, Alkaline Zn–air and Al–air cells based on novel solid PVA/PAA polymer electrolyte membranes, J. Membr. Sci. 280 (2006) 802–808.

DOI: 10.1016/j.memsci.2006.02.037

[10] C. Iwakura, H. Murakami, S. Nohara, N. Furukawa, H. Inoue, Charge–discharge characteristics of nickel/zinc battery with polymer hydrogel electrolyte, J. Power Sources 152 (2005) 291–294.

DOI: 10.1016/j.jpowsour.2005.03.175

[11] C. Iwakura, S. Nohara, N. Furukawa, H. Inoue, The possible use of polymer gel electrolytes in nickel/metal hydride battery, Solid State Ionics 192 (2002) 487–492.

DOI: 10.1016/s0167-2738(02)00092-9

[12] C.-C. Yang, Study of alkaline nanocomposite polymer electrolytes based on PVA–ZrO2–KOH, Mater. Sci. Eng. B 131 (2006) 256–262.

DOI: 10.1016/j.mseb.2006.04.036

[13] K. Tadanaga, Y. Furukawa, A. Hayashi, M. Tatsumisago, Direct ethanol fuel cell using hydrotalcite clay as a hydroxide ion conductive electrolyte, Adv. Mater. 22 (2010) 4401–4404.

DOI: 10.1002/adma.201001766

[14] H. Inoue, Y. Inada, S. Okuda, E. Higuchi, S. Nobara, Inorganic hydrogel electrolyte with liquidlike ionic conductivity, Electrochem. Solid-State lett. 12, (2009) A58–A60.

DOI: 10.1149/1.3059000

[15] H.-S. Kim, Y. Yamazaki, J.-D. Kim, T. Kudo, I. Honma, High ionic conductivity of Mg–Al layered double hydroxides at intermediate temperature (100–200 °C) under saturated humidity condition (100% RH), Solid State Ionics 181 (2010) 883–888.

DOI: 10.1016/j.ssi.2010.04.037

[16] A. Matsuda, H. Sakamoto, T. Kishimoto, K. Hayashi T. Kugimiya, H. Muto, Preparation of hydroxide ion conductive KOH–ZrO2 electrolyte for all-solid-state iron/air secondary battery, Solid State Ionics in press (.

DOI: 10.1016/j.ssi.2013.10.053