XRD and Microstructural Analyses on Biodegradable Mg Alloys

Article Preview

Abstract:

Stainless steels, titanium and titanium alloys are the most widely used artificial surgical biomaterials for a long time. These alloys with non-degradability properties present long-term adverse effects or stress shielding and require a second surgery for a complete healing. The ongoing scientific research to avoid this problem found a new kind of biocompatible alloys for implants made of biodegradable materials witch should be used as alternative. Among the various biodegradable materials, magnesium alloys have unique biodegradability properties in the physiological environment, have stimulatory effects on new bone formation and have an elastic modulus similar to that of human bone. Roentgen structural analysis was used to detail the global chemical composition analysis, especially the analysis to determine the phase-pick sites characteristic diffraction and crystallographic orientation parameters Miller constituent phases. On studied alloys Mg and Mg2Ca type compounds with different crystallographic orientations were identified. The results obtained on the Mg-Ca and Mg-Ca-Si systems will be correlated with results from previous tests and analyses, to finally obtain an alloy with biodegradability that may be controlled.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

79-84

Citation:

Online since:

March 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] R.C. Zeng, W. Dietzel, F. Witte, et al. Progress and challenge for magnesium alloys as biomaterials, Adv. Eng. Mater. 10 (2008) B3-B14.

DOI: 10.1002/adem.200800035

Google Scholar

[2] K.Y. Chiu, M.H. Wong, F.T. Cheng, et al. Characterization and corrosion studies of fluoride conversion coating on degradable Mg implants, Surf. Coat. Technol. 202 (2007) 590-598.

DOI: 10.1016/j.surfcoat.2007.06.035

Google Scholar

[3] Z. Li, X. Gu, S. Lou, Y. Zheng, The development of binary Mg-Ca alloys for use as biodegradable materials within bone, J. Biomater. 29 (2008) 1329-1344.

DOI: 10.1016/j.biomaterials.2007.12.021

Google Scholar

[4] T.N. Kirkland, N. Birbilis, J. Walker, In-vitro dissolution of magnesium–calcium binary alloys: clarifying the unique role of calcium additions in bioresorbable magnesium implant alloys. J. Biomed. Mater. Res. B 95 (2010) 91-100.

DOI: 10.1002/jbm.b.31687

Google Scholar

[5] K. Oh-ishi, R. Watanabe, C.L. Mendis, K. Hono, Age-hardening response of Mg– 0. 3 at. %Ca alloys with different Zn contents, Mat. Sci. Eng. 526 (2009) 177-184.

DOI: 10.1016/j.msea.2009.07.027

Google Scholar

[6] J. Jayaraj, C.L. Mendis, T. Ohkubo, et al., Enhanced precipitation hardening of Mg–Ca alloy by Al addition. Scr Mater 2010; 63: 831–4.

DOI: 10.1016/j.scriptamat.2010.06.028

Google Scholar

[7] Z.I.N. Abidin, D. Martin, A. Atrens, Corrosion of high purity Mg, AZ91, ZE41 and Mg2Zn0. 2Mn in Hank's solution at room temperature, Corros. Sci. 53 (2011) 862-872.

DOI: 10.1016/j.corsci.2010.10.008

Google Scholar

[8] Y. Wan, G. Xiong, H. Luo, et al. Preparation and characterization of a new biomedical magnesium–calcium alloy, Mater. Des. 29 (2008) 2034-(2037).

DOI: 10.1016/j.matdes.2008.04.017

Google Scholar

[9] G. Wu, Y. Fan, H. Gao, C. Zhai, et al. The effect of Ca and rare earth elements on the microstructure, mechanical properties and corrosion behavior of AZ91D. Mater Sci Eng 408 (2005) 255-263.

DOI: 10.1016/j.msea.2005.08.011

Google Scholar