Tribological Study of PCL-PEG-PCL Polymer on SiNxHy Base

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Tribological behaviour of polymer and hard coating films is complicated with bio-lubricant. Contacting and kinematic conditions of a knee joint when a person in running was simulated in the study. Substrates of specimens are Ti6Al4V and 316LVM stainless steel. Two kinds of polymer films, PCL-PEG-PCL and mPEG-PCL-mPEG, were used to simulate the tissue of cartilage. The silicon nitride film, SiNxHy prepared by PECVD, was used as a protecting film, and it’s thickness about 1000 nm under the polymer film. The testing device was developed, upper specimen is rotated reversely and the lower one is moved linearly forward and backward for 6 mm. A frequency vibration is applied under the lower specimen to simulate the vibration caused from walking, which is sated 2 Hz. Two torque meters are used for friction measurement in rotational and sliding directions. Experiments simulated vertical vibration, rotary and reciprocating motion. Comparing friction coefficient with different substrates with SiNxHy film, mixture of PCL-PEG-PCL and bovine serum can effectively decrease friction but useless for mPEG-PCL-mPEG. If adhesion of PCL-PEG-PCL polymer can be improved, it has potential in the application of artificial joint.

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264-269

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] G. Petzow, M. Herrmann, in: M. Janson (Ed. ), High Performance Non-Oxide Ceramics II, Structure and Bonding, 102 (2002) 47.

DOI: 10.1007/3-540-45623-6_2

Google Scholar

[2] E. Salgueiredo, M. Vila, M.A. Silva, M.A. Lopes, J.D. Santos, F.M. Costa, R.F. Silva, P.S. Gomes, M.H. Fernandes, Biocompatibility evaluation of DLC-coated Si3N4 substrates for biomedical applications, Diamond & Related Materials 17 (2008).

DOI: 10.1016/j.diamond.2007.08.019

Google Scholar

[3] J.Q. Yao, M.P. Laurent, T.S. Johnson, C.R. Blanchard, R.D. Crowninshield , The influences of lubricant and material on polymer/CoCr sliding friction, Wear 255(2003), 780–784.

DOI: 10.1016/s0043-1648(03)00180-7

Google Scholar

[4] Ewen Northwood, John Fisher, A multi-directional in vitro investigation into friction, damage and wear of innovative chondroplasty materials against articular cartilage, Clinical Biomechanics 22(2007), 834–842.

DOI: 10.1016/j.clinbiomech.2007.03.008

Google Scholar

[5] S. Gea, S. Wang, N. Gitis, M. Vinogradov, J. Xiao, Wear behavior and wear debris distribution of UHMWPE against Si3N4 ball in bi-directional sliding, Wear 264 (2008) 571–578.

DOI: 10.1016/j.wear.2007.05.001

Google Scholar

[6] F. J. Van Natta, J. W. Hill, W. H. Carothers, Studies of polymerization and ring formation XXIII. ε-Caprolactone and its Polymers. The Experimental Station of E. I. Du Pont 118 (1934) 455-457.

DOI: 10.1021/ja01317a053

Google Scholar

[7] M. Lambet, W. Thielemans, Synthesis of Polycaprolactone: a Review. Chem. Soc. Rev. 38 (2009) 3484-3504.

Google Scholar

[8] M. Flieger, M. Kantorova, A. Prell, T. Rezanka, J. Votruba, Biodegradable Plastics from Renewable Sources, Folia Microbiol. 1(2003), 27-44.

DOI: 10.1007/bf02931273

Google Scholar

[9] C. K. S. Pillai, C. P. Sharma, Review Paper: Absorbable Polymeric Surgical Sutures: Chemistry, Production, Properties, Biodegradability, and Performance, J. Biomat. App. 25 (2010) 291-376.

DOI: 10.1177/0885328210384890

Google Scholar

[10] N. Kumar, M. N. V. Ravikumar, A. J. Domb, Biodegradable Block Copolymers, Adv. Drug Del. Rev. 53 (2001), 23-44.

DOI: 10.1016/s0169-409x(01)00219-8

Google Scholar

[11] A. C. Albertsson, I. K. Varma, Recent Developments in Ring Opening Polymerization of lactones for Biomedical Applications, Biomacromol. 4 (2003) 1466-1486.

DOI: 10.1021/bm034247a

Google Scholar

[12] S. Neuss, I. Blomenkamp, R. Stainforth, D. Boltersdorf, M. Jansen, N. Butz, A. Perez-Bouza, R. Knüchel, The use of a shape-memory poly (ε-cappolactone) dimethacrylate network as a tissue engineering scaffold, Biomaterials 30 (2009) 1697–1705.

DOI: 10.1016/j.biomaterials.2008.12.027

Google Scholar