Observation of the Tribo-Film Formation Derived from ZnDTP by Using FT-IR

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To understand the effects of tribo-film formation derived from ZnDTP (zinc dialkyl ditio phosphate) on friction behavior, friction tests were carried out with varying sliding time. The sliding surfaces were analyzed using Fourier transform infrared spectroscopy (FT-IR) and X-ray Photoelectron Spectroscopy (XPS). On the basis of the surface analytical results of the tribo-film, the absorption bands in the region of 1300-1000 cm-1 assigned as polyphosphate appeared in all IR spectra after the sliding. The friction behavior of ZnDTP was related to the intensity change of the IR spectra peak at 1200 cm-1.

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259-263

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April 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] E. S. Yamaguchi, S. H. Roby, M. M. Francisco, S. G. Ruelas, D. Godfrey Antiwear Film Formation by ZnDTP, Detergent, and Dispersant Components of Passenger Car Motor Oils, Tribology Transactions. Vol. 45 (2002), p.425–429.

DOI: 10.1080/10402000208982569

Google Scholar

[2] R. Heuberger, A. Rossi, N. D. Spencer Pressure Dependence of ZnDTP Tribochemical Film Formation: A Combinatorial Approach,: Tribology Letters Vol 28 (2007) p.209–222.

DOI: 10.1007/s11249-007-9267-0

Google Scholar

[3] M. Masuko, H. Sato, A. Suzuki, O. Kurosawa Prevention of oxidative degradation of ZnDTP by microcapsulation and verification of its antiwear performance,. Tribology International. Vol. 41 (2008), p.1097–1102.

DOI: 10.1016/j.triboint.2008.01.005

Google Scholar

[4] J.M. Martin, C. Grossiord, T.L. Mogne, S. Bec, A. Tonck The two-layer structure of Zndtp tribofilms Part I: AES, XPS and XANES analyses,: Tribology International. Vol. 34 (2001), p.523–530.

DOI: 10.1016/s0301-679x(01)00029-9

Google Scholar

[5] M. Aktary, M.T. McDermott, G.A. McAlpine Morphology and Nanomechanical Properties of ZDDP Antiwear Films as a Function of Tribological Contact Time,: Tribology Letters. Vol. 12 (2002), p.155–162.

DOI: 10.1023/a:1014755123184

Google Scholar

[6] H. Spikes The history and mechanisms of ZDDP,: Tribology Letters. Vol. 17 (2004), p.469–489.

DOI: 10.1023/b:tril.0000044495.26882.b5

Google Scholar

[7] H. Cen, A. Morina, A. Neville, R. Pasaribu, I. Nedelcu Effect of water on ZDDP anti-wear performance and related tribochemistry in lubricatedsteel/steelpureslidingcontacts,. Tribology International Vol. 56 (2012), p.47–57.

DOI: 10.1016/j.triboint.2012.06.011

Google Scholar

[8] F. M. Piras, A. Rossi, N.D. Spencer Combined in situ (ATR FT-IR) and ex situ (XPS) study of the ZnDTP-iron surface interaction,: Tribology Letters. Vol. 15 (2003), p.181–191.

Google Scholar

[9] K. Sasaki, N. Inayoshi, K. Tashiro Friction-induced dynamic chemical changes of tricresyl phosphate as lubricant additive observed under boundary lubrication with 2D fast imaging FTIR-ATR spectrometer,: Wear, Vol. 268 (2010), p.911–916.

DOI: 10.1016/j.wear.2009.12.017

Google Scholar

[10] P.Y. Shih, S.W. Yung, T.S. Chin FTIR and XPS studies of P2O5-Na2O-CuO glasses,. Journal of Non-Crystalline Solids. Vol. 244 (1999), p.267–273.

DOI: 10.1016/s0022-3093(99)00011-3

Google Scholar

[11] R. K. Brow An XPS study of oxygen bonding in zinc phosphate and zinc borophosphate glasses,. Journal of Non-Crystalline Solids. Vol. 194 (1996), p.267–273.

DOI: 10.1016/0022-3093(95)00500-5

Google Scholar