Nanostructured Polymetallic Powders to Create New Functional Materials on its Base

Abstract:

In the paper, the particle morphology is considered and the slices of phase diagrams of nanosystems agreeable to the synthesis conditions are constructed according to the data obtained earlier by authors, as well as new results of the study of nanostructured Fe-Co, Fe-Ni, Co-Ni, Fe-Co-Ni, Fe-Pt, Cu-Ni and Ni-Cd powders. It is found that all considered polymetallic systems have common nature of the particle size spatial organization, i.e., 7-20 nm nanocrystals (for different systems) form highly compact aggregates (40-100 nm) which put together into loose porous agglomerates (up to 200-250 nm) and then into unconsolidated micron size formation of cloud type. It is classified uncovered features of nanostructured polymetallic phase diagrams in comparison with phase diagrams of bulk systems. Magnetic properties of nanosystems are studied.

• Periodical: Key Engineering Materials (Volume 670)
• Pages: 49-54
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.670.49
• Online since: October 2015
• Authors: Yuriy A. Zaharov*, Valeriy M. Pugachev, Kseniya A. Datiy, Anna N. Popova, Anastasiya S. Valnyukova, Artem S. Bogomyakov, Vadim G. Dodonov
• Keywords: Magnetic Properties, Nanoparticles, Nanostructured Multicomponent Metal Systems, Phase Diagrams

References

[1] Xia Younan, Yujie Xiong, Byungkwon Lim, Sara E. Skrabalak. Shape-Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics, Angew Chem Int Ed Engl.; 48(1) (2009) 60-103.

DOI: 10.1002/anie.200802248

[2] H. J. Gysling, Nanoinks in inkjet metallization – Evolution of simple additive-type metal patterning, Curr Opin Colloid Interface Sci. 19 (2014) 155-162.

DOI: 10.1016/j.cocis.2014.03.013

[3] B. O. Istemi, L. Gang, Ch. Hongseok, Zh. Huijuan, Shape effects on nanoparticle engulfment for metal matrix nanocomposites, J. Cryst. Growth. 422 (2015) 62-68.

[4] A.D. Pomogailo, A.S. Rozenberg, I.E. Ufland Metal nanoparticles in polymers (Nanochasticy metallov v polimerah – in Russian). Moscow: Chemistry. (2000) 672.

[5] D. M. O'Carroll, Nanotechnology Applications for Clean Water (Second Edition): Department of Civil and Environmental Engineering, The University of Western Ontario, London, Ontario, Canada. (2014) 441-456.

[6] V.V. Sviridov, V.N. Vorobiyova, T.V. Gaevskaya, L.I. Stepanova Chemical deposition of metal in aqua solutions Minsk, Ed.: Universitetskoe (Minsk, Ed.: Universitetskoe – in Russian). (1987) 270.

[7] J.H. Park, S.C. Kweon, S.W. Kim Structural and magnetic properties of electrospun FeCoNi magnetic nano-fibers with nanogranular phases, J Nanopart Res. 14 (2012) 729-737.

DOI: 10.1007/s11051-012-0729-4

[8] E. Motamedi, M. Talebi Atouei, M.Z. Kassaee, Comparison of nitrate removal from water via graphene oxide coated Fe, Ni and Co nanoparticles, Mater. Res. Bull. 54 (2014) 34-40.

DOI: 10.1016/j.materresbull.2014.02.019

[9] Q. Nguen, C. N. Chinnasamy, S. D. Yoon, et al., J. Appl. Phys. 103 (2008) 07D532.

[10] Yu. A. Zaharov, V. M. Pugachev, A. N. Popova, Chemical synthesis, structure and magnetic properties of nanocrystalline Fe-Co alloys. Materials Letters. 74 (2012) 173-175.

DOI: 10.1016/j.matlet.2012.01.090

[11] Yu. A. Zaharov, V. M. Pugachev, V. G. Dodonov et al., Nanosize Powders of Transition Metals Binary Systems, Journal of Physics: Conference Series. 345 (2012) 012024.

DOI: 10.1088/1742-6596/345/1/012024

[12] Yu. A. Zaharov, V. M. Pugachev, O. V. Vasilteva et al. Nanostructed powders of nickel-copper system, Bulletin of Kemerovo State University (Vestnik Kemerovskogo gosudarstvennogo universiteta – in Russian). 3-3 (2014) 201-210.

[13] Yu. A. Zakharov, V. M. Pugachev, A. N. Popova, V. G. Dodonov, Yu. V. Karpushkina, B. P. Tolochko, A. S. Bogomyakov, V. V. Kriventsov, Structure of nanosize bimetals Fe-Co and Fe-Ni, Bulletin of the Russian Academy of Sciences: Physics. 77 (2013).

DOI: 10.3103/s106287381302041x

[14] D. I. Svergun, L. A. Feygin X-ray and Neutron Small-Angle Scattering Moscow, Science (Moskva, Nauka – in Russian), (1986) 280.

[15] N. Ya. Selyakov, G. V. Kurdyumov, N. T. Gudtsov, J. App. Phys. (ZHurnal prikladnoj fiziki – in Russian). 4 (1927) 51-82.

[16] A. N. Popova, Yu. A. Zakharov, V. M. Pugachev, V. G. Dodonov, Density of nanostructed powders of Fe-Co and Fe-Ni systems, J. Adv. Mat. (Perspektivnye materialy – in Russian). 13 (2011) 699-704.

[17] A. S. Valnyukova, V. M. Pugachev, Yu. A. Zakharov, Synthesis and crystal structure of nanostructured Ni-Cd system, Bulletin of Kemerovo State University (Vestnik Kemerovskogo gosudarstvennogo universiteta – in Russian). 3-3 (2014) 178-181.

[18] X. Liu, H. Kanda, A. Morisako, J. Phys. Conf. Ser. 266 (2011) 012037.

[19] Y. M. Kim, Ch. Datall, J. Magn. Mater. 2 (2001) 1507-1509.

[20] T. Ghodselahi, A. Arman, Magnetoresistance of Cu-Ni nanoparticles in hydrogenated amorphous carbon thin films, J. Mater. Sci.: Mater. Electron. 26 (2015) 4193-4197.

DOI: 10.1007/s10854-015-2965-8

[21] Yu. V. Khlebnikova, D. P. Rodionov, I. V. Gervas'eva, et al., Conditions of sharp cube texture formation in thin tapes of Cu-Ni alloys for second-generation high-temperature superconductors, Technical Physics Letters. 41 (2015) 341-343.

DOI: 10.1134/s1063785015040094