Preparation and Performance of Mesoporous TiO2 Photocatalyst with P123 as Template

Article Preview

Abstract:

In this paper, a series of mesoporous TiO2 photocatalyst were prepared by hydrothermal method using block copolymer P123 as template and Ti (OBu)4 as titanium source. The microstructure and spectroscopy performance of the prepared TiO2 were characterized by means of XRD, SEM, TEM, BET, and BJH analysis, and the photocatalytic activity of mesoporous TiO2 were examined by measuring the photodegradation of methyl orange , then discussed the best prepared conditions of mesoporous TiO2 photocatalyst. The results showed that the products were all anatase mesoporous TiO2 nanopowder, the average particle size is about 7nm and all have the Langmuir type IV pore structure. The best prepared condition: hydrothermal temperature is 160°C, hydrothermal time is 24h, mesoporous TiO2 photocatalyst has the BET surface area of 146m2/g , it’s photocatalytic degradation rate is 97.07% in an hour.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

198-202

Citation:

Online since:

February 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Arpita Sarkar, Nam Joong Jeon, Jun Hong Noh, Well-Organized Mesoporous TiO2 Photoelectrodes by Block Copolymer-Induced Sol-Gel Assembly for Inorganic-Organic Hybrid Perovskite Solar Cells, J. Journal of Physical Chemistry. 118 (2014) 16688-16693.

DOI: 10.1021/jp412655p

Google Scholar

[2] K. Zimny, T. Roques-Carmes, C. Carteret, Synthesis and Photoactivity of Ordered Mesoporous Titania with a Semicrystalline Framework, J. Journal of Physical Chemistry. 116 (2012) 6585-6594.

DOI: 10.1021/jp212428k

Google Scholar

[3] Xiangcun Li, Wenji Zheng, Gaohong He, Morphology Control of TiO2 Nanoparticle in Microemulsion and Its Photocatalytic Property, J. ACS Sustainable Chemistry & Engineering. 2 (2014) 288-295.

DOI: 10.1021/sc400328u

Google Scholar

[4] Rahmatollah Rahimi, Masoumeh Mahjoub Moghaddas, Solmaz Zargari, Synthesis of Mesoporous V-TiO2 with Different Surfactants: The Effect of Surfactant Type on Photocatalytic Properties, J. Advanced Materials Research. 702 (2013) 56-61.

DOI: 10.4028/www.scientific.net/amr.702.56

Google Scholar

[5] Norihiro Suzuki, Tatsuo Kimura, Yusuke Yamauchi, General synthesis of fibrous mesoporous metal oxides in polycarbonate membrane, J. Journal of Materials Chemistry. 20 (2010) 5294-5300.

DOI: 10.1039/c0jm00277a

Google Scholar

[6] K. Assaker, C. Carteret, P. Durand, Hydrothermal Stability of Ordered Surfactant-Templated Titania, J. Journal of Physical Chemistry. 117 (2013) 16500-16508.

DOI: 10.1021/jp405517w

Google Scholar

[7] Lars Robben, Adel A. Ismail, Sven Jare Lohmeier, Facile Synthesis of Highly Ordered Mesoporous and Well Crystalline TiO2: Impact of Different Gas Atmosphere and Calcination Temperatures on Structural Properties, J. Chemistry of Materials. 24 (2012).

DOI: 10.1021/cm203203b

Google Scholar

[8] Anthony Lannoy, Rudina Bleta, Cecile Machut, Block copolymer-cyclodextrin supramolecular assemblies as soft templates for the synthesis of titania materials with controlled crystallinity, porosity and photocatalytic activity, J. RSC Advances. 4 (2014).

DOI: 10.1039/c4ra05994h

Google Scholar

[9] Wenheng Jing, Wei Huang, Weihong Xing, Fabrication of Supported Mesoporous TiO2 Membranes: Matching the Assembled and Interparticle Pores for an Improved Ultrafiltration Performance, J. ACS Applied Materials & Interfaces. 1 (2009) 1607-1612.

DOI: 10.1021/am900246m

Google Scholar

[10] Easwaramoorthi Ramasamy, Changshin Jo, Arockiam Anthonysamy, Soft-Template Simple Synthesis of Ordered Mesoporous Titanium Nitride-Carbon Nanocomposite for High Performance Dye-Sensitized Solar Cell Counter Electrodes, J. Chemistry of Materials. 24 (2012).

DOI: 10.1021/cm203672g

Google Scholar