Assessment of Moisture Absorbing Power of Iron Oxide Pigments by pH Metry Method

Abstract:

The urgency of the problem concerning the rapid assessment of moisture absorbing power of powdery substances is discussed in the given article. The theoretical prerequisites for the determination of moisture absorbing power by an acid-base interaction in the system “solid body-water” are considered. The advantages of the pH analytic signal of aqueous suspension are shown. Some practical recommendations of the new experimental data processing and interpretation by pH metry used for the assessment of moisture absorbing power of powdery substances are developed. It is shown that the velocity of mass transfer analytic signal undergoes changes with time depending on functional groups of the surface. These functional groups are initially predetermined by the inner structure of the object of the research. The explanation of the deceleration mechanism of acid-base reaction interaction in the system “solid body-water” is supplied. It allows examining the hydrophilic behavior (hydrophobic behavior) of the surface of the polycrystalline substance.

• Periodical: Key Engineering Materials (Volume 683)
• Pages: 301-305
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.683.301
• Online since: February 2016
• Authors: Kseniya Ikonnikova*, Lyubov Ikonnikova, Ekaterina Koltunova
• Keywords: Acid-Base Properties, Centers of Broensted, Functional Groups, Hydrophilic Behavior, Hydrophobic Behavior, Ion Exchange, Iron-Oхide Pigment, Materials Technology, Surface, Water-Repellent Property, Wetting Ability

References

[1] Е.F. Belenky, I.V. Riskin, Chemistry and Technology of Pigments. Edition 4. Chemistry, St. Petersburg, (in Russian), (1974).

[2] A.R.M. Cornell, U. Schwertmann, The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses. Wiley-VCH Verlag GmbH and Co. KgaA, (2003).

[3] J. Drbohlavova, R. Hrdy, V. Adam, R. Kizek, О. Schneeweiss, J. Hubalek, Preparation and properties of various magnetic nanoparticles. Sensors. 9/4 (2009) 2352-2362.

DOI: 10.3390/s90402352

[4] S. Laurent, D. Forge, M. Port, A. Roch, C. Robic, E. L. Vander, R.N. Muller, Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations and biological applications. Chem. Rev. 108/6 (2008).

DOI: 10.1021/cr068445e

[5] B.С. Catherine, A.S.G. Curtis, Functionalisation of magnetic nanoparticles for applications in biomedicine. J. Phys. D: Applied Physics. 36/13 (2003) 198-206.

[6] О.D. Lukashevich, N.Т. Usova, V.А. Kutugin, V.А. Lotov, The use of secondary products of water treatment in the production of iron oxide for building materials. Water: Technology and ecology. Problems and Solutions (in Russian). 2 (2011) 30-38.

[7] L.F. Ikonnikova, K.V. Ikonnikova, E.A. Koltunova, Energy and resource saving raw materials for dactyloscopy. MATEC Web of Conferences 19 (2014).

DOI: 10.1051/matecconf/20141901017

[8] Yu.G. Frolov, The Course of Colloid Сhemistry. Surface Effects and Disperse systems. LC TND Al'yans Publlishing, Moscow (in Russian), (2004).

[9] T Kobayashi, Pigment dispersion in water-reducible paints. Progress in Organic Coatings, 28/2 (1996) 79-87.

DOI: 10.1016/0300-9440(95)00608-7

[10] S. Lefebure, E. Dubois, V. Cabuil, S. Neveu, R. Massart, Monodisperse magnetic nanoparticles: preparation and dispersion in water and oils. J. Mater. Res. 13/10 (1998) 2975-2981.

DOI: 10.1557/jmr.1998.0407

[11] K.M. Lee, M.S. Corensen, J.K. Klabunde, G.C. Hadjipanayis, synthesis and characterization of stable colloidal Fe3O4 particles in W/O microemulsions. IEEE Transactions on Magnetics, 28/5 (1992) 3180-3182.

DOI: 10.1109/20.179751

[12] S.A. Jadhav, R. Bongiovanni, D.L. Marchisio, D. Fontana, C. Egger, Surface modification of iron oxide (Fe2O3) pigment particles with amino-functional polysiloxane for improved dispersion stability and hydrophobicity. Pigment and Resin Technol., 43/4 (2014).

DOI: 10.1108/prt-07-2013-0057

[13] G.D. Ransinchung, B. Kumar, V. Kumar, Assessment of water absorption and chloride ion penetration of pavement quality concrete admixed with wollastonite and microsilica. Const. and Building Mater., 23/2 (2009) 1168-1177.

DOI: 10.1016/j.conbuildmat.2008.06.011

[14] L. Cao, T.P. Price, M. Weiss, D. Gao, Super water- and oil-repellent surfaces on intrinsically hydrophilic and oleophilic porous silicon films. Langmuir, 24/5 (2008). 1640-1643.

DOI: 10.1021/la703401f

[15] M. Grundner, H. Jacob, Investigations on hydrophilic and hydrophobic silicon (100) wafer surfaces by X-ray photoelectron and high-resolution electron energy loss-spectroscopy. Applied Physics A Solids and Surfaces, 39/2 (1986) 73-82.

DOI: 10.1007/bf00616822

[16] K.V. Ikonnikova, L.F. Ikonnikova, T.S. Minakova, Yu.S. Sarkisov, The theory and practice of pH metric definition of acid-base properties of the solid body surface, Tomsk: Publishing House of Tomsk Polytechnic University (in Russian), 2011. Access mode: http: /elibrary. ru/item. asp?id=22974277.

[17] R.G. Beits, Determination of pH. Theory and Practice. Chemistry, St. Petersburg (in Russian), (1972).

[18] S.A. Kuznetsova, L.F. Ikonnikova, V.V. Kozik, Gas-sensing properties of antimony-doped SnO2. Inorg. Mater., 43/6 (2007) 622-626.

DOI: 10.1134/s002016850706012x

[19] A.A. Zhigal'skii, L.F. Ikonnikova, T.S. Minakova, V.A. Mukhachev, P.E. Troyan, Temperature dependence of the dielectric strength of zinc sulfide films. Rus. Phys. J., 39/6 (1996) 576-578.

DOI: 10.1007/bf02437024

[20] S. Morrison, Chemical Physics of Solid Surfaces. Mir, Moscow (in Russian), (1980).

[21] G. Parfit, K. Rochester, Adsorption From Solutions on Solid Surfaces. Mir, Moscow (in Russian), (1986).

[22] М. Jarlbring, L. Gunneriusson, B. Hussmann, W. Forsling, Surface complex characteristics of synthetic maghemite and hematite in aqueous suspensions. J. Colloid Interface Sci., 285/1 (2005).

DOI: 10.1016/j.jcis.2004.11.005

[23] C.K. Sia, Mohd, S. Hakimi, P. Ong, K.J. Fie, Iron oxide rust as raw material for the production of red pigment in paint industry. Appl. Mechanics and Mater., 660 (2014) 229-233.

DOI: 10.4028/www.scientific.net/amm.660.229

[24] T. Hiemstra, W.H. Van Riemsdijk, Adsorption and surface oxidation of Fe(II) on metal (hydr) oxides. Geochim. Cosmochim. Acta, 71/24 (2007) 5913-5933.

DOI: 10.1016/j.gca.2007.09.030

[25] W. Wu, Q. He, C. Jiang, Magnetic iron oxide nanoparticles: Synthesis and surface functionalization strategies. Nanoscale Res. Let. 3/11 (2008) 397-415.

DOI: 10.1007/s11671-008-9174-9

[26] Z.P. Chen, Y. Zhang, S. Zhang, J.G. Xia, J.W. Liu, K. Xu & N. Gu, Preparation and characterization of water-soluble monodisperse magnetic iron oxide anoparticles via surface double-exchange with DMSA. Colloids Surf. A, 316/1-3 (2008) 210-216.

DOI: 10.1016/j.colsurfa.2007.09.017

[27] T.V. Kuznetsova, I.V. Kudryashov, V.V. Timashev. Physical Chemistry of Binding Materials: Study Quide for Chemistry-technological Specialties of Institutes of Higher Education. Higher school, Moscow (in Russian), (1989).