Study of Sorption on Natural Minerals under Environmental Conditions

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This paper presents a comparative study of the adsorption activity of the grass meal of lady's mantle aerial part (Alchemilla vulgaris) and modern adsorption materials – activated carbon (carbolenum) and hydrolyzed lignin (polyphepane) towards model substances (markers of adsorption). The model substances were used to effectively simulate a group of toxic substances with different molar mass and degree of ionogenicity in the environment that simulates gastric and intestinal juices. It was shown that hydrolized lignin had the highest protein adsorption activity and activated carbon appeared the most active in sorbing toxicants with low molar mass. The grass meal of lady's mantle aerial parts (Alchemilla vulgaris) was able to moderately absorb both high-molar mass and low-molar mass substances at an average degree of dispersion of the raw material. It is supposed that it was mainly due to the high-porous structure of the material. This shows the versatility of the enterosorbent under development.

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358-362

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February 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] V.G. Nikolaev, V.A. Samsonov, Analysis of medical use of carbon adsorbents in China and additional possibilities in this field achieved in Ukraine, Artificial Cells, Nanomed. and Biotech. 42 (2014) 1–5.

DOI: 10.3109/21691401.2013.856017

Google Scholar

[2] I.M. Smolyakova, V.Y. Andreeva, G.I. Kalinkina, S.N. Avdeenko, P.P. Shchetinin, Development of extraction techniques and standardization methods for a common lady's mantle (Alchemilla vulgaris) extract, Pharm. Chem. J. 45 (2012) 675–678.

DOI: 10.1007/s11094-012-0702-7

Google Scholar

[3] V.O. Njokua, M.A. Islama, M. Asif, B.H. Hameed, Utilization of sky fruit husk agricultural waste to produce high quality activated carbon for the herbicide bentazon adsorption, Chem. Eng. J. 251 (2014) 183–191.

DOI: 10.1016/j.cej.2014.04.015

Google Scholar

[4] N.I. Ursova, The role of enterosorbents in treatment of endogenous intoxication syndrome, Curr. Pediatr. [Voprosy sovremennoy pediatrii – in Russian]. 11 (2012) 26–31.

DOI: 10.15690/vsp.v11i6.489

Google Scholar

[5] V.K. Guptaa, B. Guptaa, A. Rastogic, S. Agarwald, A. Nayak, A comparative investigation on adsorption performances of mesoporous activated carbon prepared from waste rubber tire and activated carbon for a hazardous azo dye – Acid Blue 113, J. Hazard. Mater. 186 (2011).

DOI: 10.1016/j.jhazmat.2010.11.091

Google Scholar

[6] A.M.M. Vargas, A.L. Cazetta, M.H. Kunita, T.L. Silva, V.C. Almeida, Adsorption of methylene blue on activated carbon produced from flamboyant pods (Delonix regia): Study of adsorption isotherms and kinetic models, Chem. Eng. J. 168 (2011) 722–730.

DOI: 10.1016/j.cej.2011.01.067

Google Scholar

[7] Y. Lia, Q. Dua, T. Liua, X. Pengb, J. Wanga, J. Suna, Y. Wanga, S. Wua, Z. Wanga, Y. Xiaa, L. Xiaa, Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes, Chem. Eng. Res. Des. 91 (2013).

Google Scholar

[8] D.A. Markelov, O.V. Nitsak, I.I. Garashchenko, Comparative study of the adsorption activity of medicinal sorbents, Pharm. Chem. J. 42 (2008) 405–408.

DOI: 10.1007/s11094-008-0138-2

Google Scholar

[9] D.V. Onishchenko, V.P. Reva, B.A. Voronov, Adsorption activity of carbon nanotubes formed from brown sphagnum moss in mechanical activation, J. Anal. Chem+. 69 (2014) 403–407.

DOI: 10.1134/s1061934814050074

Google Scholar

[10] N.V. Garyntseva, I.G. Sudakova, B.N. Kuznetsov, Properties of Enterosorbents Obtained from Acetic Acid Lignins of Abies, Aspen and Birch Wood, Journal of Siberian Federal University. Chemistry [Zhurnal sibirskogo federal'nogo universiteta. Himija – in Russian]. 4 (2011).

Google Scholar

[11] I.A. Muraviev, Yu.G. Pshukov, Theoretical foundations of the method of production of liquid extracts repercolation with complete cycle: guidelines, Pyatigorsk [in Russian], (1985).

Google Scholar

[12] E. Ekramia, F. Dadashiana, M. Arami, Adsorption of methylene blue by waste cotton activated carbon: equilibrium, kinetics, and thermodynamic studies, Des. Water Treat. (2015) DOI: 10. 1080/19443994. 2015. 1015173.

DOI: 10.1080/19443994.2015.1015173

Google Scholar

[13] A.F. Hassana, A.M. Abdel-Mohsen, M.M.G. Fouda, Comparative study of calcium alginate, activated carbon, and their composite beads on methylene blue adsorption, Carbohyd. Polym. 102 (2014) 192–198.

DOI: 10.1016/j.carbpol.2013.10.104

Google Scholar