Effects of NaNbO3 Crystals on Electrical Properties of K0.5Na0.5NbO3 Ceramics

Article Preview

Abstract:

Lead-free (K0.5Na0.5)NbO3 (KNN) piezoelectric ceramics were studied and synthesized by the seed-induced method. NaNbO3 crystal was used as seed and prepared by molten salt synthesis (MSS). The average particles size of NaNbO3 seed crystal was about 1-3 mm. Then, the NaNbO3 seed was mixed with KNN powder and ball milled for 24 h. The mixed powder was calcined at 700-900 °C and sintered at 1100 °C. The phase structure and morphology of the ceramics were investigated by X-ray diffraction and scanning electron microscope and the electrical properties were studied. The results indicated that all samples showed a pure perovskite phase. The highest density of the ceramic was 93% compared to the theoretical density. The results showed that NaNbO3seed crystal improved piezoelectric properties of KNN ceramics.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

126-130

Citation:

Online since:

May 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] J. Wu, D. Xiao, J. Zhu, Potassium–Sodium Niobate Lead-Free Piezoelectric Materials: Past, Present, and Future of Phase Boundaries, Chem. Rev. 115 (2015) 2559–2595.

DOI: 10.1021/cr5006809

Google Scholar

[2] H. Birol, D. Damjanovic, N. Setter, Preparation and characterization of (K0. 5Na0. 5) NbO3 ceramics, J. Eur. Ceram. Soc. 26 (2006) 861–866.

DOI: 10.1016/j.jeurceramsoc.2004.11.022

Google Scholar

[3] Z. Li, A. Wu, P. M. Vilarinho, Perovskite Phase Stabilization of Pb(Zn1/3Ta2/3)O3 Ceramics Induced by PbTiO3 Seeds, Chem. Mater. 16 (2004) 717-723.

DOI: 10.1021/cm030592v

Google Scholar

[4] L. Wu, J. L. Zhang, C. L. Wang, J. C. Li, Influence of Compositional Ratio K/Na on Physical Properties in (KxNa1−x)NbO3 Ceramics, J. Appl. Phys. 103 (2008) 084116.

DOI: 10.1063/1.2907866

Google Scholar

[5] J. Fang, X. H. Wang, Z. B. Tian, C. F. Zhong, L. T. Li, R. Z. Zuo, Two-Step Sintering: An Approach to Broaden the Sintering Temperature Range of Alkaline Niobate-Based Lead-Free Piezoceramics, J. Am. Ceram. Soc. 93 (2010) 3552–5.

DOI: 10.1111/j.1551-2916.2010.04085.x

Google Scholar

[6] H. Ge, Y. Hou, C. Xia, M. Zhu, H. Wang, H. Yan, Preparation and Piezoelectricity of NaNbO3 High-Density Ceramics by Molten Salt Synthesis, J. Am. Ceram. Soc. 94 (2011) 4329–34.

DOI: 10.1111/j.1551-2916.2011.04685.x

Google Scholar

[7] H.E. Mgbemere, R.P. Herber, G.A. Schneider, Investigation of the dielectric and piezoelectric properties of potassium sodium niobate ceramics close to the phase boundary at (K0. 35Na0. 65)NbO3 and partial substitutions with lithium and antimony, J. Eur. Ceram. Soc. 29 (2009).

DOI: 10.1016/j.jeurceramsoc.2009.05.021

Google Scholar