Phase Equilibria in the BaO-SiO2-Al2O3 Ternary System at 1500 °C

Article Preview

Abstract:

Phase equilibria of the BaO-SiO2-Al2O3 ternary system was experimentally investigated using a quenching technique and analyzed by Scanning Electron Microscopy (SEM) equipped with Energy Dispersive Analysis (EDS) and X-ray Powder Diffraction (XRD). A ternary compound was confirmed in the present work. The liquidus composition in equilibrium with the ternary compound at 1500 °C were quantified. The isothermal sections of the BaO-SiO2-Al2O3 ternary system at 1400 °C, 1500 °C, 1600 °C, and 1700 °C were calculated. Based on the data acquired, the isothermal section at 1500 °C was constructed.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

565-571

Citation:

Online since:

July 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] G.N. Maslennikova and M. Ya. Kharitonov, Electroceramics resistant to thermal shocks, Énergiya, Moscow, (1977).

Google Scholar

[2] N.M. Bobkova and L.M. Silich, Alkali-fraee glass ceramics and glass ceramic materials, Navuka I Tekhnika, Minsk, (1992).

Google Scholar

[3] G.N. Shabanova, V.V. Taranenkova, A.N. Korogodskaya and E.V. Khristich, Structure of the BaO-Al2O3-SiO2 system (A review), Glass Ceram., 60 (2003) 43-46.

DOI: 10.1002/chin.200347238

Google Scholar

[4] C.E. Wood and T.L. Joesph, Barium oxide and blast furnace slags, Blast furnace steel plant, 17 (1929) 548-54; Ceram. Abstracts, 8 (1929) 448.

Google Scholar

[5] M.D. Johnston and M. Barati, Distribution of impurity elements in slag-silicon equilibria for oxidative refining of metallurgical silicon for solar cell applications, Sol. Energ. Mat. Sol. C., 94 (2010) 2085-(2090).

DOI: 10.1016/j.solmat.2010.06.025

Google Scholar

[6] MTOX, Release Notes for Version 8. 1 of Mtox Database, National Physical Laboratory, Teddington, UK, (2015).

Google Scholar

[7] R.H. Davies R H, Dinsdale A T, Gisby J A, Robinson J A J, Martin S M, CALPHAD, 2002, 26(2), pp.229-271.

DOI: 10.1016/s0364-5916(02)00036-6

Google Scholar

[8] R.H. Thomas, Phase equilibrium in a portion of the ternary system BaO-Al2O3-SiO2, J. Am. Ceram. Soc., 33(1950) 35-44.

Google Scholar

[9] N.A. Toropov, F.Y. Galakhov and I.A. Bondar, The diagram of state of the ternary system BaO-Al2O3-SiO2, Bull. Acad. Sci. USSR, Division of chemical science (English translation), (1954) 647-655.

DOI: 10.1007/bf01170102

Google Scholar

[10] Von J.E. Planz and H.M. Hesse, Solid-State Reactions in the System BaO-Al2O3-SiO2: II. The formation of celsian by solid-state reactions, Ber. Dtsch. Keram. Ges, 40 (1963) 191-200.

Google Scholar

[11] H.C. Lin and W.R. Foster, Studies in the system BaO-Al2O3-SiO2: I. The polymorphism of celsian, Am. Minerlog. 53 (1968) 134-142.

Google Scholar

[12] W.R. Foster and H.C. Lin, Studies in the system BaO-Al2O3-SiO2: II. The binary system celsian (BaAl2Si2O8)-silica (SiO2), Am. J. Sci., 267 (1969) 134-144.

Google Scholar

[13] H.C. Lin and W.R. Foster, Studies in the system BaO-Al2O3-SiO2: III. The binary system sanbornite-celsian, Minerlog. Mag., 37 (1969) 459-465.

DOI: 10.1180/minmag.1969.037.288.05

Google Scholar

[14] C.E. Semler and W.R. Foster, Studies in the system BaO-Al2O3-SiO2: IV. The system celsian-alumnia and the join celsian-mullite, J. Am. Ceram. Soc., 52 (1969) 678-680.

DOI: 10.1111/j.1151-2916.1969.tb16078.x

Google Scholar

[15] H.C. Lin and W.R. Foster, Studies in the system BaO-Al2O3-SiO2: V. The ternary system sanbornite-celsian-silica, J. Am. Ceram. Soc., 53 (1970) 549-551.

DOI: 10.1111/j.1151-2916.1970.tb15963.x

Google Scholar

[16] C.E. Semler and W.R. Foster, Studies in the system BaO-Al2O3-SiO2: VI. The system celsian-silica-alumina, J. Am. Ceram. Soc., 53 (1970) 595-598.

DOI: 10.1111/j.1151-2916.1970.tb15979.x

Google Scholar

[17] R. Zhang. P. Taskinen, Experimental investigation of liquidus and phase stability in the BaO-SiO2 binary system, J. Alloys Compd., 657 (2016) 770-776.

DOI: 10.1016/j.jallcom.2015.10.165

Google Scholar

[18] G. Purt, Binary System of BaO-Al2O3, Radex-Rundschau, 4 (1960) 198-202.

Google Scholar

[19] N.A. Toropov, F.Y. Galakhov, Phase Diagram of the BaO-Al2O3 System, Dokl. Akad. Nauk SSSR, 82 (1952) 69-70.

Google Scholar

[20] R. Zhang and P. Taskinen, A phase equilibria study and thermodynamic assessment of the BaO-Al2O3 system, Calphad, 51 (2015) 42-50.

DOI: 10.1016/j.calphad.2015.07.003

Google Scholar

[21] J.M. Fields, P.S. Dear, J.J. Brown, J. Am. Ceram. Soc., 55 (1972) 585-588.

Google Scholar