Effect of Aluminum Source on the Structural and Thermal Properties of Partially Phosphorylated Polyvinyl Alcohol Composite (PPVA) - Aluminum Phosphate (PPVA-AlPO4) Nanocomposite

Article Preview

Abstract:

Partially phosphorylated poly vinyl alcohol (PPVA) was mixed with two different aluminum (Al) sources (aluminum nitrate and aluminum hydroxide) to produce a PPVA-AlPO4 composite. Transgravimetric analysis (TGA) shows that the weight residue of PPVA-AlPO4 composite using aluminum nitrate is higher than aluminum hydroxide. X-Ray diffraction (XRD) analysis shows the occurrence of multiple phases of PPVA-AlPO4 composite using aluminum nitrate and three broad peaks at range of 2-6, 6-18 and 24-36 ̊ using aluminum hydroxide.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

291-294

Citation:

Online since:

July 2016

Keywords:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] K. Lee, S. Jeong, and J. Cho, Roles of surface chemistry on safety and electrochemistry in lithium ion batteries, Acc. Chem. Res., vol. 46, no. 5, p.1161–1170, (2013).

DOI: 10.1021/ar200224h

Google Scholar

[2] D. Chen, L. He, and S. Shang, Study on aluminum phosphate binder and related Al2O3-SiC ceramic coating, Mater. Sci. Eng. A384, p.29–35, (2003).

DOI: 10.1016/s0921-5093(02)00643-3

Google Scholar

[3] V. A. do R. Monteiro, E. F. ´. de Souza, M. M. M. de Azevedo, and F. Galembeck, Aluminum Polyphosphate Nanoparticles: Preparation, Particle Size Determination, and Microchemistry., J. Colloid Interface Sci., vol. 217, no. 2, p.237–248, (1999).

DOI: 10.1006/jcis.1999.6381

Google Scholar

[4] N. Wang, Flame Retardancy of Polymer Nanocomposites based on Layered Aluminum Phosphate and Computational Study of Intercalation of Amines into α-Zirconium Phosphate and Adsorption of a Model Organic Pollutant, (2011).

Google Scholar

[5] R. H. P. Devamani and A. M., Synthesis and Characterization of Aluminium Phosphate Nanoparticles, Int. J. Appl. Sci. Eng. Res., vol. 1, no. 6, p.769–775, Dec. (2012).

Google Scholar

[6] E. Palacios, P. Leret, M. J. de la Mata, J. F. Fernández, A. H. De Aza, and M. a. Rodríguez, Influence of the pH and ageing time on the acid aluminum phosphate synthesized by precipitation, CrystEngComm, vol. 15, no. 17, p.3359, (2013).

DOI: 10.1039/c3ce00011g

Google Scholar

[7] C. -S. Yang and K. -Y. Kau, Synthesis of Morphology Processable α-AlPO4 Nanoparticles , Nanowires and Multi-strand Nano-ropes, J. Chinese Chem. Soc., vol. 52, p.477–487, (2005).

DOI: 10.1002/jccs.200500069

Google Scholar

[8] J. -G. Lee, B. Kim, J. Cho, Y. -W. Kim, and B. Park, Effect of AlPO4-Nanoparticle Coating Concentration on High-Cutoff-Voltage Electrochemical Performances in LiCoO2, J. Electrochem. Soc., vol. 151, no. 6, p. A801, (2004).

DOI: 10.1149/1.1723495

Google Scholar

[9] F. Gutiérrez-Mora, K. C. Goretta, D. Singh, J. L. Routbort, S. Sambasivan, K. a. Steiner, J. Adabie, and K. K. Rangan, High-temperature deformation of amorphous AlPO4-based nano-composites, J. Eur. Ceram. Soc., vol. 26, no. 7, p.1179–1183, Jan. (2006).

DOI: 10.1016/j.jeurceramsoc.2004.12.036

Google Scholar

[10] K. Kandori, N. Ikeguchi, A. Yasukawa, and T. Ishikawa, Synthesis of Mesoporous Spherical Aluminum Phosphate Particles Using Metal Ions, J. Colloid Interface Sci., vol. 202, no. 2, p.369–376, Jun. (1998).

DOI: 10.1006/jcis.1998.5414

Google Scholar

[11] A. M. Saat, N. A. Latiff, S. Yaakup, and M. R. Johan, Synthesis and characterisation of composite partially phosphorylated polyvinyl alcohol – aluminium phosphate as protective coating, Mater. Res. Innov., vol. 18, no. 6, p.310–313, (2014).

DOI: 10.1179/1432891714z.000000000974

Google Scholar

[12] B. Boonchom and S. Kongtaweelert, Study of kinetics and thermodynamics of the dehydration reaction of AlPO4 · H2O, J. Therm. Anal. Calorim., vol. 99, no. 2, p.531–538, Jun. (2010).

DOI: 10.1007/s10973-009-0113-5

Google Scholar

[13] R. J. Kalbasi and E. Izadi, Hydrothermal synthesis of pure AlPO4-5 without fluoride medium: synthesis, characterization and application as a support, J. Porous Mater., vol. 20, p.547–556, Sep. (2013).

DOI: 10.1007/s10934-012-9627-5

Google Scholar

[14] M. M. Beppu, Emilia Celma De Oliveira Lima, and Fernando Galembeck, Aluminum Phosphate Particles Containing Closed Pores : Preparation , Characterization , and Use as a White Pigment, J. Colloid Interface Sci., vol. 178, p.93–103, (1996).

DOI: 10.1006/jcis.1996.0097

Google Scholar