Surface Morphology Analysis and Mechanical Characterization of Electrospun Nanofibrous Structure

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The extraordinary properties of nanofibrous structure have gained ever-increasing appeal as an attractive candidate in a myriad of applications, especially for the water filtration. This type of structure has permeability due to its porous structure. Electrospinning is one of the most viable approaches in fabricating nanofibrous web that exhibits novel and outstanding performance in membrane separation as compared to those produced through conventional methods. Thus, the optimization of electrospinning processes is actively pursued by many researchers in order to obtain the best structure suitable for real-life applications. In this study, the surface morphology analysis and mechanical characterization of nanofibrous structure are addressed. For this purpose, polyvinylidene fluoride (PVDF) is considered. The polymeric nanofibrous structures are fabricated through electrospinning technique. Parameters such as polymer concentration and applied voltage for electrospinning process were varied and the resulting morphology of the structure were observed using SEM. In addition, the macroscopic mechanical responses of the structure were probed by means of tensile tests with special attention given to membrane anisotropy and behavior under cyclic loading.

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89-93

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July 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] Z. Zhao, J. Li, X. Yuan, X. Li, Y. Zhang and J. Sheng, Preparation and properties of electrospun poly(vinylidene fluoride) membranes. J. Appl. Polym. Sci. 97 (2005) 466-474.

DOI: 10.1002/app.21762

Google Scholar

[2] E. S. Cozza, O. Monticelli, E. Marsano and P. Cebe, On the electrospinning of PVDF: influence of the experimental conditions on the nanofiber properties. Polym. Int. 62 (2013) 41-48.

DOI: 10.1002/pi.4314

Google Scholar

[3] Y. Liao, R. Wang, M. Tian, C. Qiu and A. G. Fane, Fabrication of polyvinylidene fluoride (PVDF) nanofiber membranes by electro-spinning for direct contact membrane distillation. J. Membr. Sci. 425-426 (2013) 30-39.

DOI: 10.1016/j.memsci.2012.09.023

Google Scholar

[4] M. Boffito, E. Bernadi, S. Sartori, G. Ciardelli and M. P. Sassi, A mechanical characterization of polymer scaffolds and films at the macroscale and nanoscale. J. Biomed. Mater. Res. A 103 (2015) 162-169.

DOI: 10.1002/jbm.a.35147

Google Scholar

[5] R. Inai, M. Kotaki and S. Ramakrishna, Structure and properties of electrospun PLLA single nanofibers. Nanotechnology 16 (2005) 2008-2213.

DOI: 10.1088/0957-4484/16/2/005

Google Scholar

[6] K. Hwang, B. Kwon and H. Byun, Preparation of PVdF nanofiber membranes by electrospinning and their use as secondary battery separators. J. Membr. Sci. 378 (2011)111-116.

DOI: 10.1016/j.memsci.2011.06.005

Google Scholar

[7] J. M. Deitzel, J. Kleinmeyer, D. Harris, N. C. B. Tan, The effect of processing variables on the morphology of electrospun nanofibers and textiles, Polym. 42(1) (2001) 261-272.

DOI: 10.1016/s0032-3861(00)00250-0

Google Scholar