Compatibilization Efficiency of Polybutadiene-Grafted Maleic Anhydride in Ethylene-Propylene Diene Rubber/Epoxidized Natural Rubber Blends

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This research aims to investigate the efficiency of polybutadiene-grafted maleic anhydride (PB-g-MAH) as the compatibilizer for ethylene-propylene diene rubber and epoxidized natural rubber (EPDM/ENR) blends. PB-g-MAH was varied from 0-10 parts per hundred parts of rubber (phr), and the cure characteristics, mechanical and dynamic properties of 70/30 EPDM/ENR blends with and without compatibilizer were evaluated. It was found that the minimum torque, maximum torque, scorch and cure times of the blends increased after adding PB-g-MAH, whereas cure rate decreased. The morphology of the blend is improved by the addition of PB-g-MAH in small amounts, owing to an improved compatibility of these rubbers confirmed by dynamic mechanical property. The hardness and oil resistance increased with increasing PB-g-MAH content. Of all blends investigated, the blend compatibilized with 2-4 phr of PB-g-MAH shows the optimum mechanical properties and thermal resistance.

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45-49

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August 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] S.H. Botros, M.L. Tawfic, Compatibility and thermal stability of EPDM/NBR elastomer blends, J. Elastom. Plast. 37 (2005) 299-317.

DOI: 10.1177/0095244305050004

Google Scholar

[2] S. Prasertsri, P. Amnuay, K. Sripan and P. Nuinu, Role of hydroxyl-terminated polybutadiene in changing properties of EPDM/ENR blends, Adv. Mater. Research 844 (2014) 349-352.

DOI: 10.4028/www.scientific.net/amr.844.349

Google Scholar

[3] M.L. Celestin, B.G. Soares, Compatibilization efficiency of carboxylated nitrile rubber and epoxy pre-polymer in nitrile/acrylic rubber blends, Polimeros, 23 (2013) 139-145.

DOI: 10.1590/s0104-14282013005000024

Google Scholar

[4] S. Prasertsri, N. Rattanasom, Fumed and precipitated silica reinforced natural rubber composites prepared from latex system: Mechanical and dynamic properties, Polym. Test. 31 (2012) 593-605.

DOI: 10.1016/j.polymertesting.2012.03.003

Google Scholar

[5] Information on http: /www. crayvalley. com/docs/technical-paper/ricobond-maleinized-polybutadiene. pdf.

Google Scholar

[6] G.N. Onyeagoro, Reactive compatibilization of natural rubber (NR)/carboxylated nitrile rubber (XNBR) blends by maleic anhydride-grafted-polyisoprene (MAPI) and epoxy resin dual compatibilizers, Int. Ref. J. Eng. Sci. 2 (2013) 7-16.

Google Scholar

[7] S.H. Botros, M.L. Tawfic, Synthesis and characteristics of MAH-g-EPDM compatibilized EPDM/NBR rubber blends, J. Elastom. Plast. 38 (2006) 349-365.

DOI: 10.1177/0095244306065889

Google Scholar