Formation and Evolution of Chemical-Physical Complex Network during Vulcanization in Carbon Black Filled Natural Rubber (NR)

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The formation and evolution of chemical-physical complex network during vulcanization in carbon black (CB) filled NR was investigated in this work. The results showed that the cross-linking density increased with increase of CB content. The variation of torque during vulcanization was attributed to crosslinks of macromolecular chains. The critical content of CB for the forming of CB network was between 30phr and 40phr (weight percentage). The CB content did not affect the glass transition temperature (Tg) obviously.

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27-31

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November 2016

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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DOI: 10.1021/ie50596a044

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