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HomeKey Engineering MaterialsKey Engineering Materials Vol. 717Structure and Electrical Conductivity of...

Structure and Electrical Conductivity of Polystyrene/Carbon Black Composites Prepared by Microlayer Coextrusion

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Abstract:

Electrically conducting composites with a structure of alternating (A-B-A)_n layers were prepared by a novel microlayer coextrusion, which were consisted of alternating layers of polystyrene (PS) and layers of carbon black (CB)-filled polystyrene (PSCB). The co-continuous structure with selective location of CB in PSCB layers was controllable by changing the number of multiplying elements, and decreased the percolation threshold and electrical resistivity of multilayered composites because of the double percolation effect. In addition, the multilayered composites exhibited better mechanical properties than that of the conventional blends, which were related to the layered structure and small size of CB aggregates.

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Material Science and Engineering Seminar

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Periodical:

Key Engineering Materials (Volume 717)

Pages:

38-46

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.717.38

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Online since:

November 2016

Authors:

Chang Jin Li, Liang Zhao Xiong, Cong Ji Yuan, Zhi Wei Jiao, Wei Min Yang*

Keywords:

Carbon Black, Electrically Conducting Composites, Microlayer Coextrusion, Polystyrene

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Turner, J. S. Walter, Multipolymer systems, Science. 208 (1980) 813-818.

[2] H. P. Wang, J. K. Keum, A. Hiltner, E. Baer, Confined crystallization of PEO in nanolayered films impacting structure and oxygen permeability, Macromolecules. 42 (2009) 7055-7066.

DOI: 10.1021/ma901379f

[3] R. Y. F. Liu, Y. Jin, A. Hiltner, E. Baer, Probing nanoscale polymer interactions by forced-assembly, Macromol. Rapid Commun. 24(2003) 943-948.

DOI: 10.1002/marc.200300051

[4] T. Christopher, S. Sarah, A. R. Jo, F. Bradley, S. Daniel, J. Co-extrusion of multilayer poly(m-xylylene adipimide) nanocomposite films for high oxygen barrier packaging applications, Membrane. Sci. 340 (2009) 45-51.

DOI: 10.1016/j.memsci.2009.05.011

[5] Costa, C., Lucera, A., Conte, A., Mastromatteo, M., Speranza, B., Antonacci,A., M. Mastromatteo, Antonacci, A., Effects of passive and active modified atmosphere packaging conditions on ready-to-eat table grape, J. Food. Eng. 102(2011) 115-121.

DOI: 10.1016/j.jfoodeng.2010.08.001

[6] C. D. Mueller, S. Nazarenko, T. Ebeling, T. L. Schuman, A. Hiltner, and E. Baer, Novel structures by microlayer coextrusion—talc-filled PP, PC/SAN, and HDPE/LLDPE, Polym. Eng. Sci. 37(1997) 355-362.

DOI: 10.1002/pen.11678

[7] D. Chisholm and W. J. Schrenk, U.S. Patent 3, 557, 265, (1971).

[8] A. Turner, W. J. Schrenk, and D. S. Chisholm, U.S. Patent 3, 759, 647, (1973).

[9] R. Y. F. Liu, T. E. Bernal-Lara, A. Hiltner, E. Baer, Forced assembly of polymer nanolayers thinner than the interphase, Macromolecule, 38 (2005) 10721-10727.

DOI: 10.1021/ma051649x

[10] D. Jarus, A. Hiltner, E. Baer, Microlayer coextrusion as a route to innovative blend structures, Polym. Eng. Sc. 41 (2001) 2162-2171.

DOI: 10.1002/pen.10911

[12] J. Li, S. Y. Guo, Y. Q. Zhang, Y. Y. Dai, and S. l. Jiang. China Patent 200810147902. 2, (2008).

[13] S. Y. Guo, M. Wang, J. Li, J. B. Shen, S. B, Xu, and Q. Du, China Patent 200620036431. 4, (2006).

[14] Lee, P. C., Dooley, J., Robacki, J., Jenkins, S., Wrisley, R., Improvements in flex oxygen barrier properties of polymeric films by microlayer coextrusion, J. Plast. Film. Sheet. 30(2013)234-247.

DOI: 10.1177/8756087913506728

[15] W. Gao, Y. Zheng, J. B. Shen, S.Y. Guo, Electrical properties of polypropylene-based composites controlled by multilayered distribution of conductive particles, Acs. Appl. Mater. Inter. 7(2014)1541-1549.

DOI: 10.1021/am506773c

[16] J. Zhu, J. Shen, S. Guo, H. J. Sue, Confined distribution of conductive particles in polyvinylidene fluoride-based multilayered dielectrics: Toward high permittivity and breakdown strength, Carbon. 84(2015)355-364.

DOI: 10.1016/j.carbon.2014.12.031

[17] J. B. Shen, M. Wang, J. Li, S.Y. Guo, Simulation of mechanical properties of multilayered propylene-ethylene copolymer/ethylene 1-octene copolymer composites by equivalent box model and its experimental verification, Eur. Polym. J. 45 (2009).

DOI: 10.1016/j.eurpolymj.2009.07.013

[18] A. Rameshwar, S. Volker, L. Katrin, H. M. Goerg, A. Hiltner, E. Baer, Structure and properties of multilayered PET/PC composites, Macromol. Symp, 290(2010) 156-165.

DOI: 10.1002/masy.201050418

[19] J. B. Shen, F. C. Michel, Y. Zhi, Y. Qin, G. Richard, S.Y. Guo, The development of a conductive carbon nanotube (CNT) network in CNT/polypropylene composite films during biaxial stretching, Compos. Part. A-Appl. S. 43(2012) 1448-1453.

DOI: 10.1016/j.compositesa.2012.04.003

[20] J. B. Shen, F. C. Michel, G. Richard, S.Y. Guo, The development of conductive carbon nanotube network in polypropylene-based composites during simultaneous biaxial stretching, Eur. Polym. J. 48 (2012) 930-939.

DOI: 10.1016/j.eurpolymj.2012.03.005

[21] M. Wang, X. J. Sun, L. Su, J. B. Shen, S.Y. Guo, The electrical conductivity of carbon nanotube/carbon black/polypropylene composites prepared through multistage stretching extrusion, Polymer. 53(2012) 1602-1610.

DOI: 10.1016/j.polymer.2012.02.003

[22] S. Nazarenko, E. Baer, and A. Hiltner, Oxygen barrier properties of crystallized and talc-filled poly(ethylene terephthalate), J. Mater. Sci. 37, (1999) 847-857.

DOI: 10.1002/(sici)1099-0488(19990415)37:8<847::aid-polb10>3.0.co;2-3

[23] M. Matthew, E. S. Donald, F. Lionel, A. W. Mason, S. S. James, E. Baer, A. Hiltner, Reduction of dielectric hysteresis in multilayered films via nanoconfinement, Macromolecules. 45(2012) 1954-(1962).

DOI: 10.1021/ma202267r

[24] G. Mohit, Y. J. Li, D. Taneisha, E. Baer, A. Hiltner, and A. S. David, Structure and gas barrier properties of poly (propylene-graft-maleic anhydride)/phosphate glass composites prepared by microlayer coextrusion, Macromolecules. 43(2010).

DOI: 10.1021/ma100391u

[25] Y. Bin, C. Xu, D. Zhu, M. Matsuo, Electrical properties of polyethylene and carbon black particle blends prepared by gelation/crystallization from solution, Carbon. 40 (2002) 195-199.

DOI: 10.1016/s0008-6223(01)00173-7

[26] Y. Bin, M. Kitanaka, D. Zhu, M. Matsuo, Development of highly oriented polyethylene filled with aligned carbon nanotubes by gelation/crystallization from solutions, Macromolecules. 36 (2003) 6213-6219.

DOI: 10.1021/ma0301956

[27] J. G. Simmons, Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film, J. Appl. Phys. 34 (1963) 1793-1803.

DOI: 10.1063/1.1702682

[28] E. K. Sichel, J. I. Gittleman, P. Sheng, Transport properties of the composite material carbon-poly(vinyl chloride), Phys. Rev. B. 18 (1978) 5712-5716.

DOI: 10.1103/physrevb.18.5712

[29] Podsiadlo, P., Kaushik, A. K., Arruda, E. M., Waas, A. M., Shim, B. S., Xu, J., Nandivada, H., Pumplin, B. G., Lahann, J., Ramamoorthy, A., Kotov, N. A., Ultrastrong and stiff layered polymer nanocomposites, Science. 318 (2007) 80-83.

DOI: 10.1126/science.1143176

[30] Russo, G. M., Simon, G. P., Incarnato, L., Correlation between rheological, mechanical, and barrier properties in new copolyamide-based nanocomposite films, Macromolecules. 39(2006) 3855-3864.

DOI: 10.1021/ma052178h

[31] Paul, D. R., Robeson, L. M., Polymer nanotechnology: Nanocomposites, Polymer. 49 (2008) 3187-3204.

DOI: 10.1016/j.polymer.2008.04.017

[32] Bonderer, L. J., Studart, A. R., Gauckler, L. J., Bioinspired design and assembly of platelet reinforced polymer films, Science. 319 (2008) 1069-1073.

DOI: 10.1126/science.1148726