Fabrication of Superhydrophobic Ni-SiO2 Nanocomposite Coating with Excellent Corrosion Resistance on Mild Steel

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Superhydrophobic surfaces were fabricated on mild steel substrate by electrochemical deposition technique. The morphology of superhydrophobic coating shows a hierarchical structure, the contact angle of water on which is up to 160.1° and the sliding angle is about 1°. The corrosion resistance of as-prepared samples was measured by potentiodynamic polarization curves. The results show that the sample with superhydrophobicity provided better protection against corrosion. The corrosion potential of the sample was found a remarkable drift positively and the corrosion current density decreased sharply compared with which show high adhesion. This route may offer a potential possibility to fabricate superhydrophobic surfaces in large scale in industry and easy to generalize it to other metal materials.

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14-19

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November 2016

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Peng, B. Bhushan. Mechanically durable superoleophobic aluminum surfaces with microstep and nanoreticula hierarchical structure for self-cleaning and anti-smudge properties, J. Colloid Interface Sci. 461 (2016) 273-284.

DOI: 10.1016/j.jcis.2015.09.027

Google Scholar

[2] U. Eduok, R. Suleiman, M. Khaled, R. Akid, Enhancing water repellency and anticorrosion properties of a hybrid silica coating on mild steel, Prog. Org. Coat. 93 (2016) 97-108.

DOI: 10.1016/j.porgcoat.2016.01.006

Google Scholar

[3] S. Zheng, C. Li, Q. Fu, W. Hu, T. Xiang, Q. Wang, M. Du, X. Liu, Z. Chen, Development of stable superhydrophobic coatings on aluminum surface for corrosion-resistant, self-cleaning, and anti-icing applications, Mater. Des. 93 (2016): 261-270.

DOI: 10.1016/j.matdes.2015.12.155

Google Scholar

[4] Z. Zheng, Y. Liu, Y. Bai, J. Zhang, Z. Han, L. Ren, Fabrication of biomimetic hydrophobic patterned graphene surface with ecofriendly anti-corrosion properties for Al alloy, Colloids Surf., A 500 (2016): 64-71.

DOI: 10.1016/j.colsurfa.2016.04.008

Google Scholar

[5] T. Nishino, M Meguro, K Nakamae, M Matsushita, The lowest surface free energy based on -CF3 alignment, Langmuir 15. 13 (1999), 4321-4323.

DOI: 10.1021/la981727s

Google Scholar

[6] A Ganne, V. Lebed, A. Gavrilov, Combined wet chemical etching and anodic oxidation for obtaining the superhydrophobic meshes with anti-icing performance, Colloids Surf., A 499 (2016): 150-155.

DOI: 10.1016/j.colsurfa.2016.04.019

Google Scholar

[7] X. Zhang, R. Chen, Y. Liu, J. Hu, Electrochemically generated sol–gel films as inhibitor containers of superhydrophobic surfaces for the active corrosion protection of metals, J. Mater. Chem. A 4 (2016): 649-656.

DOI: 10.1039/c5ta07443f

Google Scholar

[8] B. Wu, M. Zhou, J. Li, X. Ye, G. Li, L. Cai, Superhydrophobic surfaces fabricated by microstructuring of stainless steel using a femtosecond laser, Appl. Surf. Sci. 256 (2009): 61-66.

DOI: 10.1016/j.apsusc.2009.07.061

Google Scholar

[9] L. Jiang, Y. Zhao, J. Zhai, A lotus‐leaf‐like superhydrophobic surface: a porous microsphere/nanofiber composite film prepared by electrohydrodynamics, Angew. Chem. 116 (2004): 4438-4441.

DOI: 10.1002/ange.200460333

Google Scholar

[10] W. Stöber, A. Fink, E. Bohn, Controlled growth of monodisperse silica spheres in the micron size range, J. Colloid Interface Sci. 26 (1968) 62-69.

DOI: 10.1016/0021-9797(68)90272-5

Google Scholar

[11] H. Chen, Z. Sun, J. Shao, Investigation on FT-IR spectroscopy for eight different sources of SiO2, J. Chin. Ceram. Soc. 30 (2011) 934-937.

Google Scholar

[12] W. Wang, F. Hou, H. Wang, H. Guo, Fabrication and characterization of Ni–ZrO2 composite nano-coatings by pulse electrodeposition, Scripta Mater. 53 (2005) 613-618.

DOI: 10.1016/j.scriptamat.2005.04.002

Google Scholar

[13] A.B.D. Cassie, S. Baxter, Wettability of porous surfaces, Trans. Faraday Soc. 40 (1944) 546-551.

DOI: 10.1039/tf9444000546

Google Scholar

[14] Z. Cheng, L. Hao, A. Chen, Q. Song, C. Chen. A rapid one-step process for fabrication of superhydrophobic surface by electrodeposition method, Electrochim. Acta 59 (2012) 168-171.

DOI: 10.1016/j.electacta.2011.10.045

Google Scholar

[15] B. Bhushan, E. Her, Fabrication of superhydrophobic surfaces with high and low adhesion inspired from rose petal, Langmuir 26 (2010) 8207-8217.

DOI: 10.1021/la904585j

Google Scholar

[16] T. Liu, S. Chen, S. Cheng, J. Tian, X. Chang, Y. Yin, Corrosion behavior of super-hydrophobic surface on copper in seawater, Electrochim. Acta 52 (2007) 8003-8007.

DOI: 10.1016/j.electacta.2007.06.072

Google Scholar