Determination of Formaldehyde in Water-Borne Coatings by HPLC

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Abstract:

A method for determination of formaldehyde in water-borne coatings by high-performance liquid chromatographic was proposed. Ultrasonic water extraction method was used instead of the traditional steam distillation method can be more rapid and efficient extraction of target, filtered and derivatived with DNPH. The extract was separated by C18 column with an elution composed of acetonitrile and water, and detected at 352nm. The detection limit was 0.1mg/L. The method showed good linear correlation, R2 was 0.9997 at the range of 0.1mg/L ~ 20 mg/L. Recovery was 95% ~105%. This method is simple, effective and sensitive.

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355-359

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January 2017

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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[1] D.F. Wu,Y.H. Wu. Investigation of occupational contact dermatitis caused by formaldehyde, J. Journal of labour medicine. 18(2001) 226.

Google Scholar

[2] M. Kat, K. Am. Respiratory health of plywood workers occupationally exposed to formaldehyde, J. Arch Environ Health. 45(1990)288-294.

DOI: 10.1080/00039896.1990.10118748

Google Scholar

[3] J. Shaham, R. Gurvieh, Z. Kaufman. Sister chromatid exchange in pathology staff occupationally exposed to formaldehyde, J. Mutat Res. 514( 2002)115-123.

DOI: 10.1016/s1383-5718(01)00334-5

Google Scholar

[4] J. Shaham, Y. Bomstein, A. DNA-Protein crosslinks, a biomarker of exposure to formaldehyde in vitro and in vivo studies , J. Carcinogenesis. l7(1996)121-125.

DOI: 10.1093/carcin/17.1.121

Google Scholar

[5] P. Sritharathikhun, M. Oshima, S. MotomizuOn-line collection/concentration of trace amounts of formaldehyde in air with chromate membrane cell and its sensitive determination by flow injection technique coupled with spectrophotometric and fluorometric detection,J. Talanta. 67(2005).

DOI: 10.1016/j.talanta.2005.04.037

Google Scholar

[6] B. Horstkotte, E. Werner and S. Wiedemeier. At-lined determination of formaldehyde in bioprocesses by sequential injection analysis, J. AnalyticaChimicaActa. 559(2006)248–256.

DOI: 10.1016/j.aca.2005.11.085

Google Scholar

[7] G. Burini and R. Coli. Determination of formaldehyde in spirits by high-performance liquid chromatography with diode-array detection after derivatization, J. Analytica ChimicaActa. 511(2004) 155–158.

DOI: 10.1016/j.aca.2004.01.025

Google Scholar

[8] P.A. MartosandJ. Pawliszyn. Sampling and determination of formaldehyde using solid-phase microextraction with on-fiber derivatization,J. AnalyticalChemistry. 7(1998)2311–2320.

DOI: 10.1021/ac9711394

Google Scholar

[9] R.T. Rivero and V. Topiwala. Quantitative determination of formaldehyde in cosmetics using a combined solid-phase microextraction–isotope dilution mass spectrometry method,J. Journal of Chromatography A. 1029(2004)217–222.

DOI: 10.1016/j.chroma.2003.12.054

Google Scholar