Prediction and Analysis on Chemorheology of MeHHPA/Hydantoin Epoxy Resin

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Abstract:

Hydantoin epoxy resin, with a hydantoin group, is a kind of low viscosity nitrigen-containing epoxy resin. We prepared methyl hexahydrophalic anhydride (MeHHPY)/ hydantin epoxy resin, in which MeHHPA was used as cure agent. Non-isothermal differential scanning calorimetry was examined to follow the curing process. The variation of viscosity was measured the isothermal curing process by rotating viscometer respectively (70-90°C). A viscosity model, which parameters were determined by Arrhenius equation, was established on the basis of experimental data at three different temperatures. As the result showed, there is a minimum deviation comparing the dual Arrhenius viscosity model data and experimental data in the temperature range of this research. The potential of artificial neural network techniques (ANN) was employed to analyze and predict the chemorheological behavior of MeHHPA/hydatoin epoxy resin. A three layer feed forward ANN model having two input neurons, one output neuron and fourteen hidden neurons was developed to predict the chemorheologica behaviour of MeHHPA/hydatoin epoxy resin. The learning of ANN was accomplished by a backpropagation algorithm. The results display that prediction model has very good accuracy in the process of the whole experiment. Through the established ANN model, the variation characteristic of viscosity can be exactly predicted. Studying on chemorheology by ANN model can help to formulate and optimize technical process.

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497-502

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January 2017

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[1] Subo Wang, and Lisheng Wan. Study of Phosphorus Flame Retardant Epoxy Resin. Chemical progress, Vol. 19 (2007), No. 1, pp.159-164. (In Chinese).

Google Scholar

[2] Chengyin Ma, Yuanxiong Wu and Jie Meng. Synthesis of 5, 5-dimethyl Hydantoin Epoxy Resin. Syntheic Resin and Plastics, Vol. 25, (2008) No. 26 , pp.39-32. (In Chinese).

Google Scholar

[3] Feng Shi, Yuexin Duan and Zhiyong Liang. Maleimide Resin System for RTM Chemorheology, Composte Materials, Vol. 23 (2006) , No. 1 , pp.56-63. (In Chinese).

Google Scholar

[4] Tiansu Liu, Xiangbao Chen and Baoyan Zhang. Rheological Properties of Low Temperature Curing Epoxy System L0-1A, Journal of aeronautical materials, Vol. 26 (2006), No. 2, pp.41-43. (In Chinese).

Google Scholar

[5] Xiang Liu, Xiaobin Hong and KaiXie. Low Temperature Curing Bisphenol F Epoxy Resin System of Chemical Rheological Model. Composed materials, Vol. 26, (2009), No. 2, pp.85-89.

Google Scholar

[6] Junying Yang and Yu Xi Jia, etc. Enhancements of the Simulation Method on the Edge Effect in Resin Transfer Molding Processes. Materials Science and Engineering A, Vol. 478 (2008), No. 478, p.384–389.

DOI: 10.1016/j.msea.2007.07.044

Google Scholar

[7] Yanyu Ding and Yuxi Jia, etc. Reactive Mold Filling in Resin Transfer Molding Processes with Edge Effects. Journal of Applied Polymer Science, Vol. 113 (2009), No. 113, p.3815–3822.

DOI: 10.1002/app.30345

Google Scholar

[8] F. Teyssandier and B. J. Love. Cure Advancement of Urethane Networks Using a Sigmoidal Chemorheological Mode. POLYMER ENGINEERING AND SCIENCE, Vol. 50 (2010) No. 3, pp.499-503.

DOI: 10.1002/pen.21560

Google Scholar

[9] Hamed Haddadi and Mohammad H. Chemorheological Analyses of a Reaction Injection Moulding Polyurethane Formulation. Iranian Polymer Journal, Vol. 15 (2006), No. 12, pp.967-977.

Google Scholar

[10] C. Domínguez and M. V. Alonso. Chemorheological Study of the Curing Kinetics of a Phenolic Resol Resin Gelled. European Polymer Journal, Vol. 46 (2010), No. 1, p.50–57.

DOI: 10.1016/j.eurpolymj.2009.09.004

Google Scholar

[11] K. C. Yung and J. Wang. Chemorheological Study of Phosphorylated Flame Retardant Epoxies. Plastics, Rubber and Composites, Vol. 40, (2011), NO. 1, pp.25-31.

DOI: 10.1179/174328911x12940139029248

Google Scholar