Synthesis and Luminescence Properties of a Blue-Emitting Sr3NaLu(PO4)3F:Eu2+ Phosphor

Article Preview

Abstract:

A novel blue-emitting Sr3NaLu (PO4)3F:Eu2+ phosphor for white light-emitting diodes (w-LEDs) have been successfully prepared via the solid-state reaction. The crystal structure and phase of the prepared phosphors were investigated using X-ray diffraction (XRD). The band gap of Sr3NaLu (PO4)3F was estimated to be about 5.79 eV from the diffuse reflection spectrum. The Sr3NaLu (PO4)3F:0.05Eu2+ phosphor exhibits an intense and broad excitation band ranging from 200 to 450 nm in the near ultraviolet region and produces a bright blue emission band with the CIE chromaticity coordinates of x = 0.133 and y = 0.148 under the excitation of 365 nm, which were ascribed to the 4f-5d transitions of Eu2+. Moreover, the fluorescence decay curves were also investigated in detail. All the results suggest that Sr3NaLu (PO4)3F:Eu2+ might be a promising blue-emitting phosphor used in w-LEDs.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

623-627

Citation:

Online since:

January 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Z.F. Yang, D.H. Xu, J.Y. Sun, Y.M. Sun and H.Y. Du: Opt. Eng. Vol. 54 (2015) No. 10, p.105102.

Google Scholar

[2] C. Liang, H.P. You, Y.B. Fu, X.M. Teng, K. Liu and J.H. He: Dalton Trans. Vol. 44 (2015) No. 17, p.8100.

Google Scholar

[3] Z.G. Xia, S.H. Miao, M.Y. Chen, M.S. Molokeev and Q.L. Liu: Inorg. Chem. Vol. 54 (2015) No. 16, p.7684.

Google Scholar

[4] J.Y. Sun and D.P. Cui: J. Am. Ceram. Soc. Vol. 97 (2014) No. 3, p.843.

Google Scholar

[5] Z.G. Xia and J.Q. Zhuang: Luminescence Vol. 27 (2012) No. 5, p.379.

Google Scholar

[6] Y.H. Jin, Y.H. Hu, Y.R. Fu, L. Chen, G.F. Ju and Z.F. Mu: J. Mater. Chem. C Vol. 3 (1995) No. 36, p.9435.

Google Scholar

[7] D.H. Xu, Z.F. Yang, J.Y. Sun, X.D. Gao and J.N. Du: J. Mater. Sci. Mater. Electron Vol. 27 (2016) No. 8, p.8370.

Google Scholar

[8] N.N. Feng, Y. Tian, L. Wang, C.E. Cui, Q.F. Shi and P. Huang: J. Alloys Compd. (2016) Vol. 654 (2016) No. 5, p.133.

Google Scholar

[9] J.H. Zheng, L.L. Ying, Q.J. Cheng, Z.Q. Guo, L. H Cai, Y.J. Lu and C. Chen: Mater. Res. Bull. Vol. 654 (2016), p.51.

Google Scholar

[10] Z.F. Yang, D.H. Xu, J.Y. Sun, J.N. Du and X.D. Gao: Mater. Sci. Eng. B Vol. 211(2016), p.13.

Google Scholar