Peparation of 20 wt.% Pt0.5Pd0.5/C Nanoelectrocatalysts by Electroless and their Electrocatalytic Properties

Bing Jie Jin; Yu Hui Zhang; Ke Pan Gao; Cheng Yan Wang

doi:10.4028/www.scientific.net/KEM.727.764

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 727Peparation of 20 wt.% Pt0.5Pd0.5/C...

Peparation of 20 wt.% Pt_0.5Pd_0.5/C Nanoelectrocatalysts by Electroless and their Electrocatalytic Properties

Abstract:

This work presents investigations on preparation of 20 wt. % Pt_0.5Pd_0.5/C nanoelectrocatalysts by electroless and their electrocatalytic properties. The 20 wt. % Pt_0.5Pd_0.5/C nanoelectrocatalysts were prepared by electroless successfully. The optimum experimental conditions of the main effect factors in preparing the PtPd nanoelectrocatalysts are [Pt²⁺ or Pd²⁺] =2-10g/L, [HCHO] =10-20g/L, temperature: 40-60°C, the dosage of protection reagent: 1-3 % of the platinum and palladium content, the agitation rate 400-500r/min. The characterization of 20 wt. % Pt_0.5Pd_0.5/C was performed with cyclic voltammetry (CV) and transmission electron microscope (TEM), respectively. Particles of PtPd are distributed symmetrically on C by TEM, of which are very small and the average granularity is less than 3nm. The nanoelectrocatalysts have high stabilization and lots of catalysis nuclei through CV.

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Key Engineering Materials (Volume 727)

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764-769

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https://doi.org/10.4028/www.scientific.net/KEM.727.764

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Online since:

January 2017

Authors:

Bing Jie Jin, Yu Hui Zhang, Ke Pan Gao, Cheng Yan Wang

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Electrocatalysis, Electroless, Nanoelectrocatalyst, Preparation, Pt_0.5Pd_0.5/C

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References

[1] K. A. Starz, E. Auer, T. Lehmann, R. Zuber: J. Power Sources, Vol. 84 (1999), pp.167-172.

Google Scholar

[2] A. Brouzgou, S.Q. Song and P. Tsiakaras: Appl. Catal., B: Environ., Vol. 127 (2012), P. 371-388.

Google Scholar

[3] S. Sharma and B. G. Pollet: J. Power Sources, Vol. 208 (2012), P. 96-119.

Google Scholar

[4] T. Lim, O.H. Kim, Y.E. Sung, H.J. Kim, H.N. Lee and Y.H. Cho, O.J. Kwon: J. Power Sources, Vol. 316 (2016), P. 124-131.

Google Scholar

[5] W. Zhang, M. Wang, J. Chen, T. Romeo, A. T. Harris and A. I. Minett: Electrochem. Commun., Vol. 34 (2013), P. 73-76.

Google Scholar

[6] Y. Tang, H. Zhang, H. Zhong, T. Xu and H. Jin: J. Power Sources, Vol. 196 (2011), P. 3523-3529.

Google Scholar

[7] R. Lin, C. Cao, T. Zhao, Z. Huang, B. Li, A. Wieckowski and J. Ma: J. Power Sources, Vol. 223 (2013), P. 190-198.

Google Scholar

[8] W. Li, Z. Chen, L. Xu and Y. Yan: J. Power Sources, Vol. 195 (2010) No. 9, P. 2534-2540.

Google Scholar

[9] D. Puthusseri, T. T. Baby, V. B. Parambhath, R. Natarajan and R. Sundara: Int. J. Hydrogen Energy, Vol. 38 (2013) No. 15, P. 6460-6468.

DOI: 10.1016/j.ijhydene.2013.02.094

Google Scholar

[10] B. Li and S. H. Chan: Int. J. Hydrogen Energy, Vol. 38 (2013) No. 8, P. 338-3345.

Google Scholar

[11] J. Zhao, K. Jarvis, P. Ferreira and A. Manthiram: J. Power Sources, Vol. 196 (2011), P. 4515-4523.

Google Scholar

[12] J.J. Salvador-Pascual, V. Collins-Martínez, A. López-Ortíz and O. Solorza-Feria: J. Power Sources, Vol. 195 (2010) No. 11, P. 3374-3379.

DOI: 10.1016/j.jpowsour.2009.12.045

Google Scholar

[13] N. Ruiz, A.R. Pierna and M. Sanchez: Int. J. Hydrogen Energy, Vol. 39 (2014) No. 10, P. 5319-5325.

Google Scholar

[14] E. Auer, A. Freund, J. Pietsch and T. Tacke: Appl. Catal. A: Gen., Vol. 173 (1998), pp.259-271.

Google Scholar