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HomeKey Engineering MaterialsKey Engineering Materials Vol. 727Metal-Organic Frameworks/Carboxyl Graphene Derived...

Metal-Organic Frameworks/Carboxyl Graphene Derived Porous Carbon as a Promising Supercapacitor Electrode Material

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Abstract:

A UiO-66-NO₂/carboxyl graphene composite (UiO-66-NO₂/CXYG) was synthesized using a simple solvothermal reaction. The composite was then calcined to obtain series of all-carbon mixture of carbonized UiO-66-NO₂/reduced carboxyl graphene (CUiO-66-NO₂/rCXYG). The obtained carbon materials were characterized by X-ray diffraction (XRD), nitrogen sorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM). Then their electrochemical properties were systematically tested. The results indicated that UiO-66-NO₂/CXYG derived Carbon-700 as an electrode for the electrochemical capacitor exhibited a high specific capacitance of 302 F g^-1 in 6 M KOH at a current density of 0.15 A g^-1, even 170 F g^-1 at a high current of 10 A g^-1 and good stability (retaining 94% capacitance after 5000 cycles). These UiO-derived porous carbon materials may offer a new insight into the various fields, such as fuel cells, supercapacitors and lithium batteries.

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Periodical:

Key Engineering Materials (Volume 727)

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756-763

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.727.756

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Online since:

January 2017

Authors:

Min Lin Mao, Li Xian Sun*, Fen Xu

Keywords:

Carboxyl Graphene, MOFs, Porous Carbon, Supercapacitor

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© 2017 Trans Tech Publications Ltd. All Rights Reserved

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