Physico-Mechanical Properties and Durability Aspects of Alkali-Activated Calcareous Fly Ash/Slag Mortars

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In this paper, the physico-mechanical properties of alkali-activated mortars (CF/S) containing calcareous fly ash (CF) from the combustion of lignite and ladle furnace slag (S) from the steelmaking process as binders as well as sand and glass cullet as inert material have been studied. The constituents were mixed with the alkaline activator (NaOH:Na2SiO3 was 1:1). The binders and aggregates were used in a ratio 1:3 while a part of sand was replaced by glass aggregates (60%). The specimens (dimensions 40x40x160 mm) of alkali-activated mixtures CF/S: 100/0, 80/20 and 50/50 were cured at 25 °C for 2 days and then were placed in humid environment (95±5 % RH, 25 °C). Then the mechanical strength and porosity at 7-d, 28-d and 90-d age were measured. All of the CF/S specimens exhibited compressive strength around 15 MPa at 28 days. After the 28-d age the specimens of CF/S mortars were exposed to wetting/drying and freeze/thaw cycles to have an estimation of durability of alkali-activated CF/S mortars and compared to the Portland I42.5 cement mortars (PC) of high strength 43 MPa. Mass loss of specimens was measured by weighing them. The results showed that alkali-activated CF/S mortars appear to have similar or slight lower behavior to wetting/drying and freeze/thaw cycles compared to net cement mortars.

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87-91

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January 2018

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[1] P. Duxson, J. L. Provis, G. C. Lukey, J. S. J. van Deventer, The role of inorganic polymer technology in the development of green concrete, Cem. Concr. Res. 37 (2007) 1590-1597.

DOI: 10.1016/j.cemconres.2007.08.018

Google Scholar

[2] C. Shi, A. Fernández-Jiménez, A. Palomo, New cements for the 21st century: The pursuit of an alternative to Portland cement, Cement and Concrete Research 41 (2011) 750-763.

DOI: 10.1016/j.cemconres.2011.03.016

Google Scholar

[3] P. K. Mehta, P. J. M. Monteiro, Concrete: Structure, Properties, and Materials", third ed., The McGraw-Hill Companies, Inc., (2006).

Google Scholar

[4] P. Chindaprasirt, P. De Silva, K. Sagoe-Crentsil, S. Hanjitsuwan, Effect of SiO2 and Al2O3 on the setting and hardening of high calcium fly ash-based geopolymer systems, J. Mater. Sci. 47 (2012) 4876 - 4883.

DOI: 10.1007/s10853-012-6353-y

Google Scholar

[5] X.L. Guo, H.S. Shi, W.A. Dick, Compressive strength and microstructural characteristics of class C fly ash geopolymer, Cem. Concr. Compos. 32 (2010) 142-147.

DOI: 10.1016/j.cemconcomp.2009.11.003

Google Scholar

[6] E. Rodríguez, S. Bernal, R. Mejía de Gutierrez, F. Puertas, Alternative concrete based on alkali-activated slag, Mater. Constr. 58 (2008) 53-67.

DOI: 10.3989/mc.2008.v58.i291.104

Google Scholar

[7] A. Fernández-Jiménez, J.G. Palomo, F. Puertas, Alkali-activated slag mortars. Mechanical strength behavior, Cem. Concr. Res. 29 (1999) 1313-1321.

DOI: 10.1016/s0008-8846(99)00154-4

Google Scholar

[8] V. M. Malhotra, P. K. Mehta, High-Performance, High-Volume Fly Ash Concrete: Materials, Mixture Proportioning, Properties, Construction Practice, and Case Histories, Marquardt Printing Ltd, Ottawa, Canada, (2002).

Google Scholar

[9] S. Konopisi, F. Kesikidou, K. Datsiou, I. Papayianni, Alkali activation of industrial by-products with high lime content, 1st ECI Conference, on Geopolymers: The route to eliminate waste and emissions in ceramic and cement manufacturing, Hernstein, Austria, (2015).

Google Scholar

[10] I. Papayianni, S. Konopisi, K. Datsiou, F. Kesikidou, Products of alkali-activated calcareous fly ash and glass cullet, Int. JRET 03 (2014) 43-51.

DOI: 10.4028/www.scientific.net/kem.761.87

Google Scholar

[11] M. Torres-Carrasco, F. Puertas, Waste glass in the geopolymer preparation. Mechanical and microstructural characterization, Journal of Cleaner Production 90 (2015) 397-408.

DOI: 10.1016/j.jclepro.2014.11.074

Google Scholar