Effect of Structural Modification on Corrosion Behavior of Hypo Eutectic Al-Si Alloy

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Abstract:

Al-Si eutectic cast alloys are widely used in aeronautical and automobile industries where significantly high strength, toughness and wear resistance are required. This class of cast alloys exhibit relatively low corrosion resistance in brine environments. The mechanical properties of the alloy system mainly depend upon the shape of Si rich eutectic phase, which mainly has acicular geometry. In present research, the effect of modified microstructure of 12 wt. % Si-Al alloy on corrosion behavior was studied. The needle like Si rich eutectic phase was modified to disperse spherical structure using rare earth metal halides. The corrosion rate and pitting behavior of modified and unmodified alloy were evaluated in 3.5% NaCl solution by general corrosion for calculated time. It was observed that the corrosion rate and pitting tendency of modified alloy had been appreciably reduced as compare to unmodified alloy. The improvement of corrosion properties were the attributes of changed morphology and distribution of Si rich eutectic phase.

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