Composition and Functional Groups Evaluation of Indonesian Grey Portland Cement as Material for Dental Application

Abstract:

Tricalcium silicates cement known as Mineral Trioxide Aggregate (MTA) was one of the influential materials in endodontics. At recent, MTA in dental application play an essential role in endodontics treatment due to its potential to regenerate tertiary dentine, apexification, and seal perforated root. However, MTA for dental application is still expensive. Portland cement has similarities with the MTA, especially portland cement fabricated in Indonesia. The purpose of this study is to investigate the composition and functional groups of tricalcium silicate from portland cement that fabricated in Indonesia. The Indonesian grey portland cement powder/portland cement type I (SNI-15-7064-2014) was used as a sample and commercialized MTA from Tehnodent (Rootdent) was used as a control for comparison. Powder and control samples were evaluated using X-ray fluorescence spectrometry (XRF) for composition test and Fourier-transform infrared spectroscopy (FTIR) for functional group analyses. The XRF evaluation showed that the composition and concentration of Indonesian grey portland cement powder almost has similarity with commercial MTA. Moreover, the Indonesian grey portland cement powder has higher Calcium and Silicon ions compared to MTA. The FTIR analyses revealed that the calcium silicate groups were detected. In conclusion, the Indonesian grey portland cement powder has high similarity to MTA, therefore, it has a possibility to be used as tricalcium silicate cement for MTA substitution. Further study is awaited based on this initial finding found in this study.

• Periodical: Key Engineering Materials (Volume 782)
• Pages: 256-261
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.782.256
• Online since: October 2018
• Authors: Indra Primathena, Denny Nurdin, Rahmi Alma Farah, Arief Cahyanto*
• Keywords: Composition, Functional Group, Grey Portland Cement, Rootdent MTA

References

[1] A.H. Borges, F.L.M. Pedro, C.E.S. Miranda, A. Semeno - Segundo, J.D. Pe ́cora, and A.M.C. Filho, Comparative study of physico-chemical properties of mta-based and portland cements, Acta Odontol Latinoam. 23 (2010) 175–181.

[2] C. Estrela, L.L. Bammann, C.R. Estrela, R.S. Silva, and J.D. Pe ́cora, Antimicrobial and chemical study of mta, portland cement, calcium hydroxide paste, sealapex and dycal, Braz. Dent. J. 11 (2000) 3–9.

[3] J. Camilleri and T.R.P. Ford, Mineral trioxide aggregate: a review of the constituents and biological properties of the material, Int. Endod. J. 39 (2006) 747–754.

DOI: 10.1111/j.1365-2591.2006.01135.x

[4] J.D.S. Neto, T.B. Schnaider, A. Gragnani, A.P. de Paiva, N.F. Novo, and L.M. Ferreira, Portland cement with additives in the repair of furcation perforations in dogs, Acta Cir. Bras. 27 (2012) 809–814.

DOI: 10.1590/s0102-86502012001100011

[5] L. Qiu, J.C. Nicola. The hydration chemistry of proroot mta, Dent. Mater. J. 34 (2015) 458-465.

[6] P. Taddei, E. Modena, A. Tinti, F. Siboni, C. Prati, and M.G. Gandolfi, Vibrational investigation of calcium-silicate cements for endodontics in simulated body fluids, J. Mol. Struc. 993 (2011) 367–375.

DOI: 10.1016/j.molstruc.2010.12.058

[7] L. Radev, V. Hristov, I. Michailova, H.M.V. Fernandes, and M.I.M. Salvado, In vitro bioactivity of biphasic calcium phosphate silicate glass-ceramic in CaO-SiO2-P2O5 system, Processing and Application of Ceramics. 4 (2010) 15–24.

DOI: 10.2298/pac1001015r

[8] J. Bensted, S.P. Varma. Some applications of infrared and raman spectroscopy in cement chemistry: hydration of portland cement and its constituents, Cem. Technol. 5 (1974) 440-450.

[9] B.C. Liga and B. Natalija, Research of calcium phosphates using fourier transform infrared spectroscopy, Intech Open Access Pub., (2012).

[10] M.L. Franquelo, A. Duran, L.K. Herrera, M.C.J. deHaro, and J.L. Perez-Rodriguez, Comparison between micro-Raman and micro-ftir spectroscopy techniques for the characterization of pigments from southern spain cultural heritage, J. Mol. Struc. 924 (2009).

DOI: 10.1016/j.molstruc.2008.11.041

[11] E.J. Garboczi and J.W. Bullard, Shape analysis of a reference cement, Cement and Concrete Research. 34 (2004) 1933–(1937).

DOI: 10.1016/j.cemconres.2004.01.006

[12] K.S. Coomaraswamy, P.J. Lumley, and M.P. Hofmann, Effect of bismuth oxide radioopacifer content on the material properties of an endodontic portland cement-based (mta-like) system, J. Endod. 33 (2007) 295–298.

DOI: 10.1016/j.joen.2006.11.018

[13] J. Camilleri, A. Cutajar, and B. Mallia, Hydration characteristics of zirconium oxide replaced portland cement for use as a root-end filling material, Dent. Mater. J. 27 (2011) 845–854.

DOI: 10.1016/j.dental.2011.04.011

[14] S.W. Chang, S.H. Baek, H.C. Yang et al., Heavy metal analysis of ortho mta and proroot mta, J. Endod. 37 (2011)1673–1676.

DOI: 10.1016/j.joen.2011.08.020

[15] J.J.R.F. Silva and R.J.P. Williams, The biological chemistry of the elements: the inorganic chemistry of life, 2nd ed., Oxford, UK, (2001).

[16] C. Estrela, M.D. Sousa-Neto, O.A. Guedes, A.H.G. Alencar, M.A.H. Duarte, and J.D. Pe ́cora, Characterization of calcium oxide in root perforation sealer materials, Braz. Dent. J. 23 (2012) 539–546.

DOI: 10.1590/s0103-64402012000500012

[17] S.W. Chang, W.J. Shon, W. Lee, K.Y. Kum, S.H. Baek, and K.S. Bae, Analysis of heavy metal contents in gray and white mta and two kinds of portland cement: a preliminary study, Oral surg. Oral Med. Oral Pathol. Oral Radiol. Endod. 109 (2010).

DOI: 10.1016/j.tripleo.2009.12.017

[18] G.D. Pecharki, J.A. Cury, A.F. Paes Leme, C.P. Tabchoury, A.A Del Bel Cury, P.L. Rosalen, W.H. Bowen. Effect of sucrose containing iron (II) on dental biofilm and enamel demineralization in situ, Caries Res. 39 (2005) 123.

DOI: 10.1159/000083157

[19] A.R. Eshghi, R. Koswari-Isfahan, M. Rezaiefer, M. Razavi, and S. Zeighami. Effect of iron containing supplements on rats' dental caries progression, J. Dent. 9 (2012) 14–19.

[20] International Standardization Organization 9917-1, Dentistry: water-based cements-part 1: powder/liquid acid-base cements, International Standardization Organization, Geneva, Switzerland, (2007).

DOI: 10.3403/30169263

[21] M.A.H. Duarte, A.C. deOliveira Demarchi, J.C. Yamashita, M.C. Kuga, and S. De Campos Fraga, Arsenic release provided by mta and portland cement, Oral surg. Oral Med. Oral Pathol. Oral Radiol. Endod. 99 (2005) 648–650.

DOI: 10.1016/j.tripleo.2004.09.015

[22] J. Camilleri, The physical properties of accelerated portland cement for endodontic use, Int. Endod. J. 41 (2008) 151–157.

DOI: 10.1111/j.1365-2591.2007.01330.x

[23] M. Tanomaru, R. Viapiana, J. Guerreiro, From mta to new biomaterials based on calcium silicate. Int. J. Dental Sc. 18-1 (2016) 18-22.

DOI: 10.15517/ijds.v18i1.23483

[24] T. Dammaschke, H.U. Gerth, H. Zachner, and E. Schafer, Chemical and physical surface and bulk material characterization of white proroot mta and two portland cements. Dent. Mater. J. 21 (2005) 731–738.

DOI: 10.1016/j.dental.2005.01.019