Characterization of Cements Produced from Clinker Co-Processed with TiO2 Waste (UOW)

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The aim of the present study is to evaluate the properties of cements produced from clinkers co-processed with unreacted ore waste (UOW), that is a waste generated in TiO2 production. A commercial CP V ARI RS cement and four different cements produced in the laboratory were characterized. The cements produced in the laboratory were made from raw mixes with a Lime Saturation Factor (LSF) fixed in 98% and varying the incorporation content of TiO2 in 0% (reference); 0.5%; 1.0% and 2.0% from the incorporation of UOW, by weight. The raw mixes were calcined at 1340°C and the resulting clinkers were mixed and interground with gypsum, thus resulting in the laboratory cements. These cements were characterized physically and mineralogically, besides tests of loss on ignition, expansibility (Le Chatelier’s needle) and compressive strength at 1, 3, 7, 28 and 91 days. It was observed that the incorporation of the UOW enhanced the formation of alite, due to the mineralizing effect of the titanium, and cement with 0.5% TiO2 (1.3% of UOW) presented the highest strength.

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278-283

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May 2019

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] MARIANI, B.B.; ANDRADE NETO, J. S.; AMORIM JÚNIOR, N. S.; RIBEIRO, D. V. Produção de clínquer Portland com incorporação de resíduo de TiO2. Proceedings of 61° Congresso Brasileiro de Cerâmica, Gramado Brazil, RS, (2017).

DOI: 10.1590/s1678-86212019000100293

Google Scholar

[2] KATYAL, N. K.; PARKASH, R.; AHLUWALIA, S. C.; SAMUEL, G. Influence of titânia on the formation of tricalcium silicate. Cem. Concr. Res.. Vol. 29, pp.355-359, (1999).

DOI: 10.1016/s0008-8846(98)00231-2

Google Scholar

[3] ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS – NBR 11582: cimento Portland – determinação da expansibilidade Le Chatelier. Rio de Janeiro, Brazil, (2016).

Google Scholar

[4] MEHTA, P. K.; GJTCRV, O. E. A new test for sulfate resistance of cements. J. Test. Eval, Vol. 2, pp.510-514, (1974).

Google Scholar

[5] MA, X.; CHEN, H.; WANG, P. Effect of TiO2 on the Formation of Clinker with High C3S. J. Wuhan Univ. Technol.-Mater., Sci., Vol. 24. No. 5, (2009).

DOI: 10.1007/s11595-009-5830-x

Google Scholar

[6] WINTER, N. B. Understanding Cement. WHD Microanalysis Consultants Ltd. Woodbridge, United Kingdom, (2012).

Google Scholar

[7] ASSOCIAÇÃO BRASILEIRA DE NORMAS TÉCNICAS – NBR 16697: cimento Portland – requisitos. Rio de Janeiro, Brazil, (2018).

Google Scholar

[8] SOHN, I.; WANG, W.; MATSUURA, H.; TSUKIHASHI, F.; MIN, D. J. Influence of TiO2 on the Viscous Behavior of Calcium Silicates Melts Containing 17 mass% Al2O3 and 10 mass% MgO. ISIJ International, Vol. 52, No. 1, pp.158-160, (2012).

DOI: 10.2355/isijinternational.52.158

Google Scholar

[9] ENGELSEN, C. J. Advanced cementing materials Reduced CO2 – emissions – Effect of mineralizers in cement production. Building and Infrastructure. Norway: SINTEF, 2007. 25p. (Technical report series, COIN/P1/SO1.1F).

Google Scholar

[10] ANDRADE NETO, J. S.; MARIANI, B. B.; AMORIM JÚNIOR, N. S.; COELHO, R. E.; RIBEIRO, D. V. Analyze of the hydration process of cement produced from clinker co-processed with TiO2 waste. 7th International Congress on Ceramics, pp.181-193, Foz do Iguaçu, Brazil, (2018).

DOI: 10.1016/j.cement.2022.100036

Google Scholar