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HomeKey Engineering MaterialsKey Engineering Materials Vol. 803Effects of Natural Clay on Ionic Conductivity,...

Effects of Natural Clay on Ionic Conductivity, Crystallinity and Thermal Properties of PEO-LiCF₃SO₃-Natural Clay as Solid Polymer Electrolyte Nanocomposites

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Abstract:

The polymer nanocomposites of PEO-LiCF₃SO₃ based solid polymer electrolyte were prepared using two kinds of natural clays, which are halloysite nanotube (HNT) and montmorillonite (MMT) nanoparticle. Different contents (0, 1, 5 and 10wt %) of halloysite nanotube (HNT) and montmorillonite (MMT) nanoparticle were explored. Solid polymer electrolyte nanocomposite film was prepared by solution casting method. The ionic conductivity, crystallinity and thermal properties of solid polymer electrolyte membranes were studied by impedance spectroscopy, X-ray diffraction (XRD) and differential scanning calorimetry (DSC), respectively. It was found that HNT provided higher ionic conductivity for solid polymer electrolyte nanocomposite than what MMT did. The highest ionic conductivity at room temperature was found at 5% HNT as 2.068 x 10^-5S.cm^-1. The ion-polymer interactions between PEO-LiCF₃SO₃ and natural clay nanoparticle were investigated by using Fourier transform infrared (FTIR) spectra. The PEO-LiCF₃SO₃-5%HNT showed good oxidative stability than PEO-LiCF₃SO₃composite.

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Periodical:

Key Engineering Materials (Volume 803)

Pages:

98-103

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.803.98

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Online since:

May 2019

Authors:

Pattranuch Pongsuk*, Jantrawan Pumchusak

Keywords:

Halloysite Nanotube, Montmorillonite, Natural Clay, Polyethylene Oxide, Solid Polymer Electrolyte, Solution Casting

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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[1] B.W. Zewde, G.A. Elia, S. Admassie, J. Zimmermann, M. Hagemann, C.S. Isfort, B. Scrosati, J. Hassoun: Solid State Ion Vol.268 (2014), p.174–178.

DOI: 10.1016/j.ssi.2014.10.030

[2] J. Suk, Y.H. Lee, D.Y. Kim, D.W. Kim, S.Y. Cho, J.M. Kim, Y. Kang: J. Power Sources Vol.334 (2016), p.154–161.

[3] J. Mohanta, D.K. Padhi, S. Si: J. Appl. Polym. Sci Vol.135 (2018), p.46336.

[4] A.S. Pandian, X.C. Chen, J. Chen, B.S. Lokitz, R.E. Ruther, G. Yang, K. Lou, J. Nanda, F.M. Delnick, N.J. Dudney: J. Power Sources Vol. 390 (2018), p.153–164.

DOI: 10.1016/j.jpowsour.2018.04.006

[5] A.R. Polu, H.-W. Rhee: J. Ind. Eng. Chem Vol.31 (2015), p.323–329.

[6] S. Choudhary, R.J. Sengwa: Ionics Vol.18 (2012), p.379–384.

[7] M. Abreha, A.R. Subrahmanyam, J. Siva Kumar: Chem. Phys. Lett Vol.658 (2016), p.240–247.

[8] S. Cho, W. Cha, H. Park, J.-M. Lee, E.-B. Kim, H.-W. Rhee, Z. Jiang, J. Strzalka, H. Kim: Synth. Met Vol.177 (2013), p.110–113.

[9] W. Wang, P. Alexandridis: Polymers Vol.8 (2016), p.387.

[10] H. Zhang, C. Liu, L. Zheng, F. Xu, W. Feng, H. Li, X. Huang, M. Armand, J. Nie, Z. Zhou: Electrochimica Acta Vol.133 (2014), p.529–538.

DOI: 10.1016/j.electacta.2014.04.099

[11] Y. Zhao, C. Wu, G. Peng, X. Chen, X. Yao, Y. Bai, F. Wu, S. Chen, X. Xu: J. Power Sources Vol.301 (2016), p.47–53.

[12] M. Liu, Z. Jia, D. Jia, C. Zhou: Prog. Polym Sci Vol.39 (2014), p.1498–1525.

[13] T. Winie, F. Muhammad, N. Hazwani: Adv. Mater. Res Vol.545 (2012), p.317–320.

[14] M.R. Johan, O.H. Shy, S. Ibrahim, S.M. Mohd Yassin, T.Y. Hui: Solid State Ion Vol.196 (2011), p.41–47.

[15] A.R. Polu, H.-W. Rhee: J. Ind. Eng. Chem Vol.37 (2016), p.347–353.

[16] R.J. Sengwa, P. Dhatarwal, S. Choudhary: Solid State Ion Vol.324 (2018), p.247–259.

[17] A.B. Reddy, B. Manjula, T. Jayaramudu, E.R. Sadiku, P. Anand Babu, S. Periyar Selvam: Nano-Micro Lett Vol.8 (2016), p.260–269.

DOI: 10.1007/s40820-016-0086-4

[18] O. Sheng, C. Jin, J. Luo, H. Yuan, H. Huang, Y. Gan, J. Zhang, Y. Xia, C. Liang, W. Zhang, X. Tao: Nano Lett Vol.18 (2018), p.3104–3112.

[19] L.N. Carli, J.S. Crespo, R.S. Mauler: Compos. Part Appl. Sci. Manuf Vol.42 (2011), p.1601–1608.

[20] A.R. Polu, H.-W. Rhee, D.K. Kim: J. Mater. Sci. Mater. Electron Vol.26 (2015), p.8548–8554.

[21] M. Amangah, M. Salami-Kalajahi, H. Roghani-Mamaqani: Diam. Relat. Mater Vol.83 (2018), p.177–183.

[22] D. Saikia, Y.-H. Chen, Y.-C. Pan, J. Fang, L.Y. Tsai, G. T. K. Fey, H.-M. Kao: J Mater Chem Vol.21 (2011), p.10542–10551.

[23] Y. Tong, Y. Xu, D. Chen, Y. Xie, L. Chen, M. Que, Y. Hou: RSC Adv Vol.7 (2017), p.22728–22734.

DOI: 10.1039/c7ra00112f