Oxidative Copolymerization of o-Hydroxy-m-Phenylenediamine and O- Toluidine - Synthesis, Structure and Properties of Copolymers

Article Preview

Abstract:

Oxidative copolymerization of o-hydroxybenzylidene-m-phenylenediamine and o-toluidine in a solution of sulfuric acid synthesized new copolymers of different composition. Structures of the copolymers obtained were confirmed by IR spectroscopy. It is shown that the copolymers obtained are not fusible materials and acid-soluble materials. The synthesized copolymers have been found to possess sufficient thermostability. The process of decomposition of the copolymers occurs in several stages, the temperature ranges depending on their composition.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

134-138

Citation:

Online since:

August 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2019 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] E.R. Blythe, D. Boer. Electrical properties of polymers. Fizmatlit, Moscow: 2008, 375 p.

Google Scholar

[2] I.I. Zyatkov, A.I. Maksimov, V.A. Moshnikov. Field effect transistor sensors. SPBGETU, LETI, St. Petersburg, 2002, 56 p.

Google Scholar

[3] H.Bai, G Shi. Gas Sensors Based on Conducting Polymers, Sensors. 7 (3) (2007) 267-307.

DOI: 10.3390/s7030267

Google Scholar

[4] S. Bhadra, D. Khastgir, N.K. Singha, J.H. Lee. Progress in preparation, processing and polyaniline, Polym. Sci. 34 (8) (2009) 783-810.

DOI: 10.1016/j.progpolymsci.2009.04.003

Google Scholar

[5] E.M. Genies, A. Boyle, M. Lapkowski, C. Tsintavis. Polyaniline: a historical survey, Synth. Met. 36 (2) (1990) 139-182.

DOI: 10.1016/0379-6779(90)90050-u

Google Scholar

[6] D.V. Zhuzhelsky, V.D. Ivanov, V.V. Maleev. Electrochemical study of polyaniline films formed on an ITO substrate for cathodic oxygen reduction, Electrochemistry, 42 (7) (2006) 782-790.

Google Scholar

[7] A.V. Orlov, S.ZH. Ozkan, G.N. Bondarenko, G.P. Karpachev. Oxidative polymerization of diphenylamine. Synthesis methods, polymer structure, High Molecules. Comm. Serie B. 48 (1) (2006) 126-133.

Google Scholar

[8] L.I. Rudaya, V.V. Shamanin, V.D. Pautov, S.M. Ramsh, A.V. Cherniyenko. Fluorescent azomethins, Pa. No. 2455291 of the Russian Federation, Publ. 10.07.(2012).

Google Scholar

[9] Yu.N. Biglova, R.B. Salikhov, I.B. Abdrakhmanov, T.R. Salikhov, I.N., Safargalin, A.G. Mustafin. Preparation and study of soluble functionalized polyanilines, Solid State Physics. 59 (6) (2017) 1226-1233.

DOI: 10.1134/s106378341706004x

Google Scholar

[10] T.A. Borukaev, A.M. Mazloeva, R.M. Otarova, Yu.A. Malkanduev, A.Kh. Malamatov, A.V. Orlov. New azomethinic compounds on the basis of m-phenylenediamine and benzaldehydes capable of oxidative polymerization, Open J. of Polymer Chemistry (OJPCHEM). 8 (2) (2018) 34-39.

DOI: 10.4236/ojpchem.2018.82004

Google Scholar

[11] Berlin A.A. Chemistry of polyconjugated systems /A.A. Berlin, MA Heyderich. Features of the thermal properties of polyconjugated systems, M .: Chemistry. 1972. 368 c.

Google Scholar