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HomeKey Engineering MaterialsKey Engineering Materials Vol. 816Kinetic Study of the Polyaddition of Azide-Alkyne...

Kinetic Study of the Polyaddition of Azide-Alkyne AB₂ Monomers in Nonisotermic Conditions

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Abstract:

Nowadays, hyperbranched polymers (HBP) are obtained by different polycondensation and polyaddition reactions [1]. Almost interest is the reaction of 1,3-dipolar cycloaddition of azides to alkynes (1,3-DCA) [2, 3]. There is a series of papers dedicated to the preparation of triazine-triazole HBPs [4, 5, 6]. These polymers were obtained by the reaction of azido-acetylene AB₂ monomers polyaddition: 2-azido-4,6-bis (propyne-2-yloxy) -1,3,5-triazine (ABPOT) and 2,4-diazido-6- (propine-2-yloxy) -1,3,5-triazine (DAPOT) (Fig. 1).

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Periodical:

Key Engineering Materials (Volume 816)

Pages:

151-156

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.816.151

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Online since:

August 2019

Authors:

artyom Petrov*, Georgiy V. Malkov, Sergei V. Karpov, A.V. Shastin, A.V. Bakeshko

Keywords:

Hyperbranched Polymers, Isoconversional Methods, Nonisotermal Kinetic, Polyaddition in Bulk

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© 2019 Trans Tech Publications Ltd. All Rights Reserved

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