Recovery of Fracture Toughness on Self-Healing Epoxies Using Ternary Nanomodified Microcapsules: A Parametric Study

Article Preview

Abstract:

This study is focused on the effect of the nanomodification of the microcapsules healing agent on the healing efficiency. In detail, nanomodified epoxy resin with both carbon nanotubes (CNTs) and carbon black (CB) diluted with a non-toxic solvent was encapsulated into UF capsules. The morphology of the external surface and the mean diameter was investigated via Scanning Electron Microscopy (SEM). In addition, the thermal stability was estimated with Thermogravimetric analysis and healing efficiency was evaluated for the polymer epoxy matrix. A parametric study was performed at various solvent percentages and catalyst percentages. Results indicated an increase of the healing efficiency with nanomodified capsules against of the use of conventional microcapsules.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

258-262

Citation:

Online since:

December 2019

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Bekas DG, Tsirka K, Baltzis D, Paipetis AS. Self-healing materials: A review of advances in materials, evaluation, characterization and monitoring techniques. Compos Part B Eng 2016;87:92–119.

DOI: 10.1016/j.compositesb.2015.09.057

Google Scholar

[2] White SR, Blaiszik BJ, Kramer SLB, Olugebefola SC, Moore JS, Sottos NR. Self-healing polymers and composites. Am Sci 2011; 99: 392–9.

DOI: 10.1179/095066010X12646898728408

Google Scholar

[3] Zhu DY, Rong MZ, Zhang MQ. Self-healing polymeric materials based on microencapsulated healing agents: From design to preparation. Prog Polym Sci 2015;49–50:175–220.

DOI: 10.1016/j.progpolymsci.2015.07.002

Google Scholar

[4] Blaiszik BJ, Caruso MM, McIlroy DA, Moore JS, White SR, Sottos NR. Microcapsules filled with reactive solutions for self-healing materials. Polymer (Guildf) 2009;50:990–7.

DOI: 10.1016/j.polymer.2008.12.040

Google Scholar

[5] Katoueizadeh E, Zebarjad SM, Janghorban K. Investigating the effect of synthesis conditions on the formation of urea-formaldehyde microcapsules. J Mater Res Technol 2018:1–12.

DOI: 10.1016/j.jmrt.2018.04.013

Google Scholar

[6] Hu J, Chen HQ, Zhang Z. Mechanical properties of melamine formaldehyde microcapsules for self-healing materials. Mater Chem Phys 2009;118:63–70.

DOI: 10.1016/j.matchemphys.2009.07.004

Google Scholar

[7] Liu X, Sheng X, Lee JK, Kessler MR. Synthesis and characterization of melamine- urea-formaldehyde microcapsules containing ENB-based self-healing agents. Macromol Mater Eng 2009;294:389–95.

DOI: 10.1002/mame.200900015

Google Scholar

[8] Icduygu MG, Asilturk M, Altan MC. Microcapsules of poly(methyl metharcylate) containing epoxy resin and multi-walled carbon nanotubes. AIP Conf Proc 2017;1914.

DOI: 10.1063/1.5016704

Google Scholar

[9] Sun G, Zhang Z. Mechanical strength of microcapsules made of different wall materials. Int J Pharm 2002;242:307–11.

DOI: 10.1016/S0378-5173(02)00193-X

Google Scholar

[10] Camino G, Operti L, Trossarelli L. Mechanism of thermal degradation of urea-formaldehyde polycondensates. Polym Degrad Stab 1983;5:161–72.

DOI: 10.1016/0141-3910(83)90007-1

Google Scholar