Research on the Contaminants Adsorption and Removal by Macroporous Resins in the Textile and Dyeing

Abstract:

Textile and dyeing wastewater is the major source of environmental water pollution all over the world, which has complex composition so that conventional methods are difficult to remove and degrade. Based on the relevant research, this paper proposes to add further treatment by using macroporous resins on the basic of the conventional treatment and explore the effects of the adsorption and desorption, such as the pH value, initial concentration of , temperature and the flow rate. The performance of six kinds of macroporous resins (DA-2, D280, DA201, D3520, AB-8 and DA-201) for the advanced treatment in the textile and dyeing wastewater has been evaluated. The adsorption and desorption properties of the contaminants, which tested by the six kinds of the macroporous resins in the textile and dyeing, have been compared. According to the results, D3520 resin holds the highest adsorption and desorption capacity. (15.6mg/g for adsorption capacity, 15.1mg/g for desorption capacity). The effects of the pH value, initial concentration of , temperature and the flow rate on removal of by D3520 macroporous resin have been tested. The results showed that the removal of increased with the pH value and initial concentration of COD increasing and the data of its adsorption fitted the Langmuir isotherm best. Besides, 92.49% could be removed after 8h of adsorption at 25 °C. Dynamic adsorption and desorption experiments have been carried out on the packed column of D3520 resins as a reference for engineering applications, the results showed that the D3520 resin could still reach 79.5% removal rate after adsorptions-regeneration for five times.

• Periodical: Key Engineering Materials (Volume 852)
• Pages: 32-40
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.852.32
• Online since: July 2020
• Authors: Shuang Han, Meng Li*, Qian Zhang, Min Zhong, Fang Lu
• Keywords: Adsorption, D3520 Macroporous Resin, Desorption, Dyeing Wastewater

References

[1] Marcucci M, Nosenzo G, Capannelli G, et al. Treatment and reuse of textile effluents based on new ultrafiltration and other membrane technologies ☆[J]. Desalination, 2001, 138(1):75-82.

DOI: 10.1016/s0011-9164(01)00247-8

[2] Pinheiro H M, Touraud E, Thomas O. Aromatic amines from azo dye reduction: status review with emphasis on direct UV spectrophotometric detection in textile industry wastewaters[J]. Dyes & Pigments, 2004, 61(2):121-139.

DOI: 10.1016/j.dyepig.2003.10.009

[3] Kumar P, Prasad B, Mishra I M, et al. Decolorization and COD reduction of dyeing wastewater from a cotton textile mill using thermolysis and coagulation[J]. J Hazard Mater. 2008, 153(1-2):635-645.

DOI: 10.1016/j.jhazmat.2007.09.007

[4] Anjaneyulu Y, Chary N S, Raj D S S. Decolourization of Industrial Effluents – Available Methods and Emerging Technologies – A Review[J]. Reviews in Environmental Science and Bio/Technology, 2005, 4(4):245-273.

DOI: 10.1007/s11157-005-1246-z

[5] Haberkamp J, Ernst M, Böckelmann U, et al. Complexity of ultrafiltration membrane fouling caused by macromolecular dissolved organic compounds in secondary effluents.[J]. 2008, 42(12):3153-3161.

DOI: 10.1016/j.watres.2008.03.007

[6] Parmar V.S, Jain R, Simonsen O, et al. Synthesis and Characterization of Strong Polar Macroporous Resin Made from Cellulose[J]. Advanced Materials Research, 2011, 346(18):743-750.

DOI: 10.4028/www.scientific.net/amr.346.743

[7] Ryy C, Beuchat L R. Immobilization of papain on an anion exchange resin by physical adsorption followed by cross linking with glutaraldehyde.[J]. Journal of Food Biochemistry, 2007, 11(2):163-176.

DOI: 10.1111/j.1745-4514.1987.tb00120.x

[8] Silva E M,Pompeu D R,Larondelle Y, et al. Optimisation of the adsorption of polyphenols from Inga edulis, leaves on macroporous resins using an experimental design methodology[J]. Separation & Purification Technology, 2007, 53(3):274-280.

DOI: 10.1016/j.seppur.2006.07.012

[9] Abburi K.Adsorption of phenol and p -chlorophenol from their single and bisolute aqueous solutions on Amberlite XAD-16 resin[J]. Journal of Hazardous Materials, 2004, 105(1-3):143-156.

DOI: 10.1016/j.jhazmat.2003.08.004

[10] Iqbal M J,Ashiq M N. Adsorption of dyes from aqueous solutions on activated charcoal.[J]. Journal of Hazardous Materials, 2007, 139(1):57-66.

DOI: 10.1016/j.jhazmat.2006.06.007

[11] Carmo A M,And L S H,Thompson M L. Sorption of Hydrophobic Organic Compounds by Soil Materials:  Application of Unit Equivalent Freundlich Coefficients[J]. Environmental Science & Technology, 2016, 34(20):4363-4369.

DOI: 10.1021/es000968v

[12] Teo W K,Ruthven D M. ChemInform Abstract: Adsorption of Water from Aqueous Ethanol Using 3‐Å Molecular‐Sieves.[J]. Industrial & Engineering Chemistry Process Design & Development, 1986, 25(1):no-no.

DOI: 10.1002/chin.198624340

[13] Westwater J W,Drickamer H G. The Mathematics of Diffusion. [J]. Mathematical Gazette, 1956, 7(10):276.

[14] Boyd G E,Schubert J,Adamson A W. The exchange adsorption of ions from aqueous solutions by organic zeolites; ion-exchange equilibria. [J]. Journal of the American Chemical Society, 1947, 69(11): 2818.

DOI: 10.1021/ja01203a064

[15] Gemeay A H. Adsorption characteristics and the kinetics of the cation exchange of rhodamine-6G with Na+-montmorillonite [J]. Journal of Colloid & Interface Science, 2002, 251(2):235-241.

DOI: 10.1006/jcis.2002.8410