Influence of Different Factors on the Oxidizing Polymerization of 3-Amino-3 ́-Nitrodiphenylazomethine and some Properties of the Received Polymer

Abstract:

The oxidative polymerization of 3-amino-3 ́-nitro-diphenylazomethine was carried out in various ways. In this case, the effect of the concentration of monomer and initiator, their ratio, temperature and reaction time, on the yield and molecular weight of the polymer was studied. The morphology is established, the size of the polymer particles and their distribution are determined. It is shown that the synthesized polymer has increased electrical conductivity and is active in redox processes.

• Periodical: Key Engineering Materials (Volume 869)
• Pages: 234-239
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.869.234
• Online since: October 2020
• Authors: Timur A. Borukaev*, Rauzat M. Otarova, Ali Kh. Salamov, Andrei V. Orlov
• Keywords: 3-Amino-3´-Nitro-Diphenylazomethine, Influence, Polymer, Polymerization, Properties

References

[1] A.S. Kolosova, M.K. Sokolskay, I.A. Vitkalova, A.S. Torlova, E.S. Pikalova, Modern polymer composite materials and their application, International Journal of Applied and Basic Research. 1 (2018) 245-256.

[2] A.A. Tager, Physical chemistry of polymers, Scientific world, Moscow, 2007, pp.76-150.

[3] Zh.A. Boeva, V.G. Sergeev, Polyaniline: Synthesis, Properties and Applications, Polymer Sci. Part C, 56 (2014) 153-164.

[4] T.A. Skotheim, J.R. Reynolds, Handbook of Conducting Polymers. 3rd ed. Conjugated Polymers. Processing and Applications, Taylor & Francis Group, London, New York, 2007. pp.156-257.

[5] A.G. Zabrodsky, M.E. Kompan, V.G. Malishkin, I.Yu. Sapurina, Carbon-based polyaniline as an anode catalyst - a way to create free fuel cells , Letters to the Journal of Thermophysics. 32 (2006) 50-59.

[6] M.E. Kompan, I.Yu. Sapurina, V. Babayan, N.E. Kazantceva, Electrically conductive polyaniline - a molecular magnet with the possibility of chemical control of magnetic properties, Solid state physics. 54 (2012) 2275-2281.

DOI: 10.1134/s1063783412120190

[7] Yu.N. Biglova, R.B. Salikhov, I.B. Abdrakhmanov, T.R. Salikhov, I.N. Saphargalin, A.G. Mustaphin, Preparation and study of soluble functionalized polyanilines, Solid State Physics. 59 (2017) 1228-1233.

DOI: 10.1134/s106378341706004x

[8] T.A. Borukaev, A.Kh. Shaov, A/Kh. Malamatov, Yu.A. Malkanduev, Obtaining azomethines based on m-phenylenediamine and substituted benzaldehydes capable of oxidative polymerization, KBSU News. 7 (2017) 17-21.

[9] A.V. Orlov, S.Zh. Ozkan, G.N. Bondarenko, G.P. Karpacheva, Oxidative polymerization of diphenylamine. Synthesis methods, polymer structure, Polimer Sci. Part B. 48 (2006) 126-130.

DOI: 10.1134/s1560090406010027

[10] S.Zh. Ozkan, G.N. Bondarenko, G.P. Karpacheva, Interfacial oxidative polymerization of phenothiazing, Polimer Sci. Part B. 51 (2009) 855-863.

[11] J. Stejskal, A. Riede, D. Hlavata, J. Prokes, M. Helmstedt, P. Holler, The Effect of Polymerization Temperature on Molecular Weight, Crystallinity and Electrical Conductivity of Polyaniline, Synthetic, Synth. Met. 96 (1998) 55-61.

DOI: 10.1016/s0379-6779(98)00064-2

[12] D.V. Zhuzhelsky, V.D. Ivanov, V.V. Maleev, Electrochemical study of polyaniline films formed on an ITO substrate during cathodic oxygen reduction, Electrochemistry. 42 (2006) 782-789.