Investigation of the Regularities of the Synthesis of Unsaturated Polyesters by the Method of Acceptor-Catalytic Polycondensation

Abstract:

The regularities of acceptor-catalytic polycondensation in the synthesis of copolymers containing arylate, sulfone, and dichloroethylene groups in the main chain have been studied. The optimal conditions for their production have been found. Infrared spectroscopy, elemental analysis, turbidimetric titration and other methods confirmed the formation of copolymers of the proposed structure.

• Periodical: Key Engineering Materials (Volume 899)
• Pages: 24-30
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.899.24
• Online since: September 2021
• Authors: Zakhirat Sultigova, Zareta Inarkieva, Rima Bazheva*, Arsen Kharaev, Madina Yalkhoroeva
• Keywords: 1,1-Dichloro-2,2-Di(4-Hydroxyphenyl) Ethylene, 4,4'-Dihydroxy-2,2-Diphenylpropane, Acceptor-Catalytic Polycondensation, Copolymerization, Dichloroethylene Group

References

[1] Zenitova L. A. Polysulfone as a functional polymer material and its production / L. A. Zenitova, E. M. Steinberg // International Research Journal.  2012, No.6 (6).  pp.23-28.

[2] Takashi Akahane, Miftakhul Huda, You Yin, Sumio Hosaka. 2010. Guide Pattern for Long- Range-Order Nanofabrication of Self-Assembled Block Copolymers. Key Engineering Materials. 459. 124-128. https://doi.org/10.4028/www.scientific.net/KEM.459.124.

DOI: 10.4028/www.scientific.net/kem.459.124

[3] Kablov E.N. Materials And Chemical Technologies For Aircraft Engineering. Herald of the Russian Academy of Sciences. 2012.82.(3). 158-167.

DOI: 10.1134/s1019331612030069

[4] Kablov E.N. New Generation Materials And Technologies For Their Digital Processing. Herald of the Russian Academy of Sciences. 2020. 90 (2). 225-228.

DOI: 10.1134/s1019331620020124

[5] Bulai A.K., Klyuchnikov V.N., Urman Y.G., Slonim I.Y., Bolotina L.M., Kozhina V.A., Gol'der M.M., Kulichikhin S.G., Beghishev V.P., Malkin A.Y. Kinetics of polysulphone synthesis: nuclear magnetic resonance spectroscopy and rheological investigation. Polymer. 1987. Т. 28. № 8. pp.1349-1357.

DOI: 10.1016/0032-3861(87)90451-4

[6] Shteinberg EM, Sergeeva EA, Zenitova, L. A., Abdullin I. Sh. Application and production of polysulfone.  Overview.  // Bulletin of Kazan Technological University.  2012.Vol. 15. No. 20. pp.168-171.

[7] Baranov A.B., Peksimov O.E., Prudskova T.N., Andreeva T.I., Simonov-Emelyanov I.D., Shembel N.L.  Study of the technological characteristics of polysulfone-based materials // Thin Chemical Technologies.  2016.Vol. 11. No. 5. pp.87-90.

DOI: 10.32362/2410-6593-2016-11-5-87-90

[8] Peksimov O.E., Balabanova V.A., Dinzburg I.L., Kazakov S.I.  Heat-resistant structural thermoplastics - polysulfones of the PSF-190, UDEL P-1700 brand.  Thermophysical, dielectric, physical and mechanical properties in a wide range of temperatures and test speeds // Plastics.  2013, No. 11. S. 20-21.

[9] Barokova E.B., Bazheva R.Ch., Haraev A.M.  Oligosulphones on the basis of 1,1-Dichlor-2,2-di (4-oxyphenyl) -Ethylene and 4,4'-dichlordiphenyl-sulphone obtained by high temperature polycondensation.  // J.  of the Ttibological Association.  V. 16, No. 2. 2010. - P. 284-287.

[10] Bartenev G.M., Zelenev Yu.V. Physics and mechanics of polymers. M .: Higher school. 1983.- 391 p.

[11] Godovsky Yu.K. // Synthesis and properties of block copolymers. Kiev: Naukova Dumka, 1983. - P.85-98.

[12] Pesetskii S.S, Jurkowski B., Olkhov Y.A, Olkhova O.M, Storozhuk I.P, Mozheiko U.M. Molecular and topological structures in polyester block copolymers. //European Polymer Journal. 2001. Т. 37. № 11. pp.2187-2199.

DOI: 10.1016/s0014-3057(01)00120-3

[13] Borodulin A.S. Polyester resins for production of goods from polymer composite materials by pressing methods. //Polymer Science. Series D. 2013. 6(3). pp.269-270.

DOI: 10.1134/s1995421213030052

[14] Borodulin A.S., Kalinnikov A.N., Scherbin S.N., Alekseev V.M. Aromatic polyethersulfone for the creation of polymer structural materials with high physical and mechanical characteristics. In the collection: Scientific works of the VI International Scientific Conference Basic Research and Innovative Technologies in Mechanical Engineering, 2019. P. 73-75.

[15] Shirokova L.B., Storozhuk I.P., Voishchev V.S., Beloglazov V.A., Yeremin V.S., Valetskii P.M., Rogovina L.Z., Slonimskii G.L., Vinogradova S.V., Korshak V.V. Properties of irregular poly-(arylate-arylene sulphonoxides) based on oligoarylene sulphonoxides with various degrees of polymerization. //Polymer Science U.S.S.R. 1982. Т. 24. № 9. pp.2259-2266.

DOI: 10.1016/0032-3950(82)90287-8

[16] Godovskii Y.K., Volegova I.A., Aksenov A.I., Storozhuk I.P., Korshak V.V. The phase composition of polyblock block-copolymers of polyarylene sulphonoxide and polyethylene oxide. //Polymer Science U.S.S.R. 1983. Т. 25. № 9. С. 2326-2336.

DOI: 10.1016/0032-3950(83)90434-3

[17] Sultigova Z., Inarkieva Z., Kharaev A., Bazheva R., Parchieva M. Synthesis of aromatic polyethersulfones. Key Engineering Materials, 2020, 869 KEM, P. 15–20.

DOI: 10.4028/www.scientific.net/kem.869.15

[18] Dizman, C. Recent advances in the preparation of functionalized polysulfones / C. Dizman, M. A. Tasdelen, A. Yagci //Polymer International. 2013. Vol. 62, iss. 7. p.991–1007. doi.org/10.1002/pi.4525.

DOI: 10.1002/pi.4525