New Mixed-Ligand Metal-Containing Monomer Based on Cobalt Acrylate and 4-Phenyl-2,2':6',2″-Terpyridine Ligand: Synthesis, Characteristics and Thermal Properties

Abstract:

New complex based on cobalt (II) acrylate and 4′-phenyl-2,2′:6′,2″-terpyridine (PhTpy) was synthesized and characterized using a number of analytical techniques including IR and UV- vis spectroscopy, elemental, X-Ray and TGA/DSC analysis. The complex has high thermal stability and crystallinity. It is found that decomposition of the complex is accompanied by thermal polymerization of acrylic fragments that is a potential way for the preparation nanoparticles of metals or their oxides stabilized by the polymer matrix.

• Periodical: Key Engineering Materials (Volume 899)
• Pages: 37-44
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.899.37
• Online since: September 2021
• Authors: Evgeny S. Sorin, Rose K. Baimuratova*, Dmitry A. Chernyayev, Denis V. Korchagin, Igor E. Uflyand, Gulzhian I. Dzhardimalieva
• Keywords: Metal-Containing Monomers, Mixed Ligand Complexes, Phenyl Terpyridine Complexes, Transition Metals

References

[1] N. Saifun, H. Md. Sajjad, N. Saiyad et all. Mixed ligand complexes: Synthesis, characterization and antibacterial activity investigation, Int. J. Chem. Stud.8 (2020) 306-312.

[2] A. D. Pomogailo. Development of Studies Devoted to Design of Polymer-Immobilized Catalysts, Polymer Science Ser. A 50 (2008) 1204-1213.

DOI: 10.1134/s0965545x08120031

[3] G. I. Dzhardimalieva, B. C. Yadav, S. Singh, I. E. Uflyand, Self-healing and shape memory metallopolymers: state-of-the-art and future perspectives, J. Chem. Soc., Dalton Trans. 49 (2020) 3042-3087.

DOI: 10.1039/c9dt04360h

[4] K. A. Williams, A. J. Boydston, C. W.Bielawski, Towards electrically conductive, self-healing materials, J. R. Soc. Inter. 4(13) (2007) 359–362.

DOI: 10.1098/rsif.2006.0202

[5] H. F. Abd El-Halim, G. G. Mohamed, E. A. M. Khalil. Synthesis, spectral, thermal and biological studies of mixed ligand complexes with newly prepared Schiff base and 1,10-phenanthroline ligands, J. Mol. Struct. 1146 (2017) 153-163.

DOI: 10.1016/j.molstruc.2017.05.092

[6] U. S. Schubert, M. Heller, Metallo-Supramolecular Initiators for the Preparation of Novel Functional Architectures. Chem. Eur. J. 7 (2001), 5252-5259.

DOI: 10.1002/1521-3765(20011217)7:24<5252::aid-chem5252>3.0.co;2-9

[7] G.V. Scaeteanu et all. Synthesis, Structural Characterization, Antimicrobial Activity, and In Vitro Biocompatibility of New Unsaturated Carboxylate Complexes with 2,2'-Bipyridine, Molecules 23 (2018) 157.

DOI: 10.3390/molecules23010157

[8] M. Badea, R. Olar, D. Marinescu, G. Vasile, Thermal behavior of some new complexes bearing ligands with polymerisable groups, J. Therm.Anal. Calorim. 85 (2006) 285-288.

DOI: 10.1007/s10973-005-7176-8

[9] T.J. Cai, W.-J. Jiang, Z.-S. Peng, Y.-F. Long, Q. Deng, Crystal structure of chloro(acrylato-O,O')bis(1,10-phenanthrolineN,-N')-cadmium(II), Z. Kristallogr. New Cryst. Struct. 21 (2006) 231-232.

DOI: 10.1524/ncrs.2006.0051

[10] M. Badea R. Olar, D. Marinescu, G. Vasile Some new acrylate complexes as a criterion in their selection for further co-polymerization reaction, J. Therm. Anal. Calorim. 80 (2005) 683-685.

DOI: 10.1007/s10973-005-0714-6

[11] R.K. Baimuratova, G.I. Dzhardimalieva V.A. Zhinzhilo, K.A. Kydralieva, I.E. Uflyand, Metal-Containing Monomers Based on Copper and Zinc Salts of Unsaturated Acids and Pendent 4-phenyl-2,2':6',2"-Terpyridine Ligands: Synthesis, Characterization and Thermal Properties, Key Eng. Mater. 869 (2020) 119-128.

DOI: 10.4028/www.scientific.net/kem.869.119

[12] S. Götz, M. Abend, S. Zechel,M. D. Hager, U. S. Schubert, Platinum-terpyridine complexes in polymers: A novel approach for the synthesis of self-healing metallopolymers, J. Appl. Polym. Sci. 136 (2019) 47064.

DOI: 10.1002/app.47064

[13] B. Sandmann, S. Bode, M. D. Hager, U. S. Schubert, Metallopolymers as an emerging class of self-healing materials. Adv. Polym. Sci. 262 (2013) 239-257.

DOI: 10.1007/12_2013_242

[14] S. Götz, S. Zechel, M.D. Hager, U.S. Schubert, Lanthanoids Goes Healing: Lanthanoidic Metallopolymers and Their Scratch Closure Behavior, Polymers. 12 (2020).

DOI: 10.3390/polym12040838

[15] Z Tang, J Huang, B Guo, L Zhang, F Liu. Bioinspired engineering of sacrificial metal–ligand bonds into elastomers with supramechanical performance and adaptive recovery. Macromolecules 49 (5), 1781-1789.

DOI: 10.1021/acs.macromol.5b02756

[16] N. Holten-Andersen, A. Jaishankar, M. J. Harrington, D. E. Fullenkamp, G. DiMarco, L. He, G. H. McKinley, P. B. Messersmith and K. Y. C. Lee. Metal-coordination: using one of nature's tricks to control soft material mechanics. J. Mater. Chem. B 2 (2014) 2467- 2472.

DOI: 10.1039/c3tb21374a

[17] I. E. Uflyand, V. A. Zhinzhilo. G. I. Dzhardimalieva. Coordination Polymer Based on Nickel (II) Maleate and 4'-Phenyl-2,2':6',2"-Terpyridine: Synthesis, Crystal Structure and Conjugated Thermolysis, J. Inorg. Organomet. Polym. 30 (2020) 965-975.

DOI: 10.1007/s10904-019-01227-8

[18] K. T. Potts, D.A. Usifer, A. Guadalupe, H.D. Abruna.4-Vinyl-, 6-Vinyl-, and 4'-Viny1-2,2':6',2''-terpyridinyl Ligands: Their Synthesis and the Electrochemistry of Their Transition-Metal Coordination Complexes, J. Am. Chem. Soc. 109 (1987) 3961-3967.

DOI: 10.1021/ja00247a021

[19] S.A. Moya, R. Pastene, H. Le Bozec, et al., Metallic carbonyl complexes containing heterocycles nitrogen ligands, Inorg. Chim. Acta. 312 (2001) 7-14.

DOI: 10.1016/s0020-1693(00)00292-9

[20] Yu.V. Karjakin, I.I. Angels, Pure Chemicals. Ed. 4th, add. and lane. - M .: Chemistry, Moscow, (1974).

[21] T. Giowiak, H. Kozlowski, I. S. Erre, and G. Micera, Inorg. Chim. Acta, Molecular structure and spectral properties of mono- and dinuclear complexes formed by manganese(II), 2,6-dimethoxybenzoate and 2,2' - bipyridine or 2-methylpyrazine. 236 (1995) 149-154.

DOI: 10.1016/0020-1693(95)04638-p

[22] H. Yamada, Y. Yamamoto, Ultraviolet excitation of Raman spectra of pyridines adsorbed on oxides, J. Chem. Soc., Faraday Trans. 75 (1979) 1215-1221.

DOI: 10.1039/f19797501215

[23] H. Sharghi, S. Ebrahimpourmoghaddam, M.M. Doroodmand & A. Purkhosrow (2012). Synthesis of Vasorelaxaing 1,4-Disubstituted 1,2,3-Triazoles Catalyzed by a 4'-Phenyl-2,2':6',2''-Terpyridine Copper(II) Complex Immobilized on Activated Multiwalled Carbon Nanotubes. Asian J. of Org. Chem.1 (2012) 377-388.

DOI: 10.1002/ajoc.201200012

[24] T. Nordvik, U. H Brinker, thermolysis of 1-(1-Aryl-1-bromomethyl) cyclopropyl Bromides: A Reinvestigation, J. Org. Chem. 68(18) (2003) 7092–7093.

DOI: 10.1021/jo034431m