Self-Voluntary Polymerization with Formation of Quaternary Ammonium Groups

Yusuf A. Malkanduev; Madina B. Begieva; Aneta A. Kokoeva; Аblulakhat T. Dzhalilov

doi:10.4028/www.scientific.net/KEM.899.253

Paper Titles

Anionic Copolymerization of Acrylonitrile with Ethyl Acrylate under the Action of the Initiating System of 1,4-Diazabicyclo[2.2.2]Octane – Ethylene Oxide
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Polymerization of Styrene in the Presence of Polybutadiene as a Stabilizer
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Influence of Vulcanizing System on the Properties of Rubbers Based on Ethylenepropylene Rubber
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Study of the Influence of the Chemical Resistance of Polyphenylenesulphone from Radel on Mechanical Properties
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Self-Voluntary Polymerization with Formation of Quaternary Ammonium Groups
p.253

Peculiar Properties of Spontaneous Methacrylate Derivatives Polymerization with Haloidallyl Compounds
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Modification of the Hygroscopic Properties of Textile Materials Containing Polyurethane Threads
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Development of a Coating Method for Polydecylmethylsiloxane Selective Layer on Polysulfone Hollow Fiber Support
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Investigation of the Deformation and Strength Properties of Elastomeric Compositions with Urea-Based Additives
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HomeKey Engineering MaterialsKey Engineering Materials Vol. 899Self-Voluntary Polymerization with Formation of...

Self-Voluntary Polymerization with Formation of Quaternary Ammonium Groups

Abstract:

The reaction of spontaneous polymerization in the N, N-dialkylaminoethyl methacrylate - alkyl halide system in organic solvent solutions is considered. It is shown that polymerization in the system under study begins only after the formation of quaternary ammonium salt in the reaction medium (at a concentration of about 0.2 mol/L) by the Menshutkin reaction, as a result of quaternization of the unsaturated amine with an alkyl halide. For the explanation of the aggregate of the obtained experimental data, fundamental considerations were formulated, kinetic schemes were developed, and the corresponding mechanism of polymerization processes was proposed.

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Periodical:

Key Engineering Materials (Volume 899)

Pages:

253-261

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.899.253

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Online since:

September 2021

Authors:

Yusuf A. Malkanduev, Madina B. Begieva, Aneta A. Kokoeva*, Аblulakhat T. Dzhalilov

Keywords:

Menshutkin Reaction, Monomeric Quaternary Salt, N,N-Dialkylaminoethyl Methacrylate, Polymerization, Spontaneous Polymerization

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