Peculiar Properties of Spontaneous Methacrylate Derivatives Polymerization with Haloidallyl Compounds

Yusuf A. Malkanduev; Aneta A. Kokoeva; Аblulakhat T. Dzhalilov

doi:10.4028/www.scientific.net/KEM.899.262

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HomeKey Engineering MaterialsKey Engineering Materials Vol. 899Peculiar Properties of Spontaneous Methacrylate...

Peculiar Properties of Spontaneous Methacrylate Derivatives Polymerization with Haloidallyl Compounds

Abstract:

The reaction of spontaneous polymerization in the system of N, N-diethylaminoethyl methacrylate with allyl chloride and bromide, orthophosphoric acid in ethanol and dimethyl sulfoxide solutions is considered. Spontaneous polymerization proceeds, consisting of two stages: the quaternization reaction and the polymerization reaction. It was shown that the accompanying reaction of quaternization, spontaneous polymerization, takes place both in a mixture of reagents and in the presence of a solvent, in other words, and by mixing an unsaturated amine and an alkyl halide.

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Periodical:

Key Engineering Materials (Volume 899)

Pages:

262-268

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.899.262

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Online since:

September 2021

Authors:

Yusuf A. Malkanduev, Aneta A. Kokoeva*, Аblulakhat T. Dzhalilov

Keywords:

N,N-Dimethylaminoethyl Methacrylate, Polymerization Kinetics, Quaternary Ammonium Compounds, Quaternization Reaction, Spontaneous Polymerization

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