Investigation of the Deformation and Strength Properties of Elastomeric Compositions with Urea-Based Additives

Article Preview

Abstract:

The effect of blocked diisocyanates on the elastic-strength properties of elastomeric compositions based on SKI-3 isoprene rubber has been investigated. The synthesized additives are 2-isocyanato-4-phenylcarbamidotoluene (IPCT) and 2,4-diphenylcarbamidotoluene (DPCT). Tests were carried out to determine the physical and mechanical (conditional tensile strength, elongation at break, hardness) properties depending on the type and dosage of additives. It was found that samples with synthesized additives have strength and elongation at break higher than those of a sample without additives by 30 % and 200 %, respectively. There was also an increase in the tear resistance of all samples compared to the control (from 49.9 to 81.9 kN/m). An assumption is made about the formation of a network of physical connections, which provides an increase in these indicators. TMA analysis results showed a wider temperature range for reversible deformations (up to 180 °С).

You might also be interested in these eBooks

Info:

Periodical:

Pages:

281-286

Citation:

Online since:

September 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] A.V. Kasperovich, O.A. Krotova, E.E. Potapov, S.V. Reznichenko, V.F. Shkodich. A Study of the Influence of a New Promoter on the Adhesion of Rubber to a Metal Cord // Polymer Science, Series D. Glues and Sealing Materials. 9. (I) (2016) 68–71.

DOI: 10.1134/s1995421215040061

Google Scholar

[2] A.G. Sharrtz, V.G. Frolikova, V.A. Sapronov, Effect of epoxy resins on rubber adhesion properties, Proceedings from the International Rubber Conference: IRC 86; Goteborg, Swed; (1986) 236-237.

Google Scholar

[3] T. Hotaka, Y. Ishikawa, K. Mori. Effect of compound ingredients on adhesion between rubber and brass-plated steel cord. Rubber Chemistry and Technology. 78 (2) (2005) 175-187.

DOI: 10.5254/1.3547876

Google Scholar

[4] R.N. Aznabaev, N.N. Shishkina, L.Yu. Zakirova, M.E. Zakirov, Sintez 2,4-difenilkarbamidotoluola I ego ispolzovanie dlya modificazii rezin. Butlerov communications. 48 (12) (2016) 133-136.

Google Scholar

[5] L.Yu. Zakirova, N.N. Shishkina, Ya.D. Samuilov, The effect of adhesive additives on the properties of isoprene rubber. Key Engineering Materials. 816 (2019) 255-259.

DOI: 10.4028/www.scientific.net/kem.816.255

Google Scholar

[6] T.F. Irzhak at all, Model fizicheskoi setki: relaksatsionnye svoistva polymerov v vysokoelasticheskom sostoyanii. Vysokomolekulyarnye soedineniya, seriya A, 39(4) (1997) 671-676.

Google Scholar

[7] M.D. Petunova at all, Kompozitsionnye materialy na osnove polyizotsianatizotsianuratnyh polymerov, poluchennye modifitsirovannym sposobom sinteza. Konstruktsii iz kompozitsionnyh materialov. 3 (2011) 27-38.

Google Scholar

[8] I.G. Ryzhykova at all, Analiz smesei PP/SKEPT, modifitsirovannyh sistemoi peroksid/ TMPTA metodom dinamicheskogo mehanicheskogo analiza. Vestnik tehnologicheskogo universiteta. 16 (10) (2013) 128-130.

Google Scholar

[9] A.N. Blaznov, E.V. Atyasova, V.V. Samoilenko, Analiz metodov termomechanicheskih ispytanii kompozitnyh materialov I sravnenie rezultatov. Yuzhno-sibirskii nauchnyi vestnik. 1 (17) (2017) 54-69.

Google Scholar

[10] Volfson S.I., Zakirova L.Yu., Karaseva Yu.S., Nigmatullina A.I. Еffect of the technological additives on the properties of recycled polyolefins. Key Engineering Materials. 816 (2019) 114-118.

DOI: 10.4028/www.scientific.net/kem.816.90

Google Scholar

[11] D.I. Fazylova, l.A. Zenitova, Polymeric Composite Material for Medical Purposes, Key Engineering Materials. 816 (2019) 250-254.

DOI: 10.4028/www.scientific.net/kem.816.250

Google Scholar

[12] D.I. Fazylova, L.A. Zenitova. Polymeric Composites for Filling Bone Cavities // Key Engineering Materials, 869 (2020) 419-424.

DOI: 10.4028/www.scientific.net/kem.869.419

Google Scholar

[13] I.A. Novakov at all, Reologicheskie I vulkanizatsyonnye svoistva elastomernyh kompozitsii, IKTS Akademkniga,, Moskow, (2006).

Google Scholar