Effect of Sulfurization Process on Octahedral Molybdenum Cluster from Mo₆ Cluster to MoS₂ Nanosheet

Abstract:

The Mo₆ cluster which has the great optical properties and chemical activity because of their unique electronic structure have been attracted attention in many fields such as phosphor and photocatalyst. However, the Mo₆ cluster it’s hard to recycling which limited its industry application because of its such small nanoscale. Immobilizing the Mo₆ cluster on 2-D material has a great value to challenge it. In this research, we study on the sulfurization process of Mo₆Br₁₂ cluster to investigate the more possibility of the immobilization of Mo₆ cluster.

• Periodical: Key Engineering Materials (Volume 904)
• Pages: 334-338
• DOI: https://doi.org/10.4028/www.scientific.net/KEM.904.334
• Online since: November 2021
• Authors: Mei Qi Zhang*, Fabien Grasset, Noée Dumait, Stephane Cordier, Toshihiro Shimada, Tetsuo Uchikoshi
• Keywords: Chemical Vapor Transport (CVT), Gas Flow Method, Metal Cluster, Nanosheet

References

[1] R. Boukherroub, O.P. Khatri, S.L. Jain, Hexamolybdenum clusters supported on graphene oxide : Visible-light induced photocatalytic reduction of carbon dioxide into methanol, 4 (2015).

DOI: 10.1016/j.carbon.2015.06.029

[2] M. Feliz, M. Puche, P. Atienzar, P. Concepción, S. Cordier, In Situ Generation of Active Molybdenum Octahedral Clusters for Photocatalytic Hydrogen Production from Water, (2016) 1963–1971.

DOI: 10.1002/cssc.201600381

[3] B. Fabre, Y. Molard, P. Turban, S. Tricot, S. Ababou-girard, C. Godet, Elaboration , Characterizations , and Energetics of Robust Mo6 Cluster-Terminated Silicon-Bound Molecular Junctions Ste p, (2016).

DOI: 10.1021/acs.jpcc.5b12481

[4] M. Kepenekian, S. Cordier, Materials Horizons, 6 (2019).

[5] A.B. Review, Synthesis Methods of Two-Dimensional MoS2 : A Brief Review, (n.d.) 1–11.

[6] S. Barua, H.S. Dutta, S. Gogoi, R. Devi, R. Khan, Nanostructured MoS2 ‑ Based Advanced Biosensors : A Review, (2018).

[7] Z. Li, X. Meng, Z. Zhang, Journal of Photochemistry and Photobiology C : Photochemistry Reviews Recent development on MoS2 -based photocatalysis : A review, "Journal Photochem. Photobiol. C Photochem. Rev. 35 (2018) 39–55.

DOI: 10.1016/j.jphotochemrev.2017.12.002

[8] B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, A. Kis, Single-layer MoS2 transistors, 6 (2011).

DOI: 10.1038/nnano.2010.279

[9] W. Zhang, J. Huang, C. Chen, Y. Chang, High-Gain Phototransistors Based on a CVD MoS2 Monolayer, (2013) 3456–3461.

[10] B. Chen, Preparation of MoS2/TiO2 based nanocomposites for photocatalysis and rechargeable batteries: progress, challenges, and perspective, (2018) 34–68.

[11] F.W. Koknat, T.J. Adaway, S.I. Erzerum, S. Syed, 44555 (1980) 307–310.

[12] K. Guy, F. Tessier, H. Kaper, F. Grasset, M. Nishio, Y. Matsushita, Y. Matsui, T. Takei, D. Lechevalier, Original Synthesis of Molybdenum Nitrides Using Metal Cluster Compounds as Precursors: Applications in Heterogeneous Catalysis ́, (2020).

DOI: 10.1021/acs.chemmater.0c01369