The Transformation of Green Rusts on the Surface of Portland Cement Hydration Materials

Bo Jiang

doi:10.4028/www.scientific.net/KEM.905.344

Paper Titles

Optimization of the Pozzolanic Activity of Coal Gangue Waste for Eco-Efficient Cementitious Materials
p.303

Test and Calculation Model of Thermal Conductivity of Concrete
p.314

Effect of Ether-Typed Polycarboxylate Superplasticizer on the Adsorption, Rheology and Concrete Properties
p.320

Study on the Synthesis, Properties and Characterization of EPEG Slump Retaining Typed Polycarboxylate Superplasticizer
p.325

Reclamation of Abrasive Slurry to Obtain SiC Ceramic Material
p.333

The Adsorption and Regeneration of Magnetic Modified Bentonite Composite for Dye Wastewater
p.338

The Transformation of Green Rusts on the Surface of Portland Cement Hydration Materials
p.344

Effects of Phosphorus on Growth and Development of Soybean Seedlings
p.353

Effect of Different Factors on Callus Induction from Leaf Explants of Jatropha curcas L.
p.359

HomeKey Engineering MaterialsKey Engineering Materials Vol. 905The Transformation of Green Rusts on the Surface...

The Transformation of Green Rusts on the Surface of Portland Cement Hydration Materials

Abstract:

Ordinary Portland cement (OPC) is widely used building material, and its hydration products can be recycling as low-cost absorbents. The loading of iron oxide is helpful to further improve their adsorption performance. In view of the fact that green rusts are frequently occurrence intermediate products in the co-precipitation of iron salt and prone to be oxidized into stable iron minerals. This study simulated co-precipitation to carry out iron-modification on hydration OPC. The results demonstrate that as the carrier materials, hydration OPC behaves excellent affinity with green rusts. Under the conditions of high temperature (70 oC) and high alklinity (pH=11), green rusts mainly transformed into feroxydrate, and a minor part are into magnetite. The enrichment and transformation of green rust can be regarded as an efficient approach for immobilization of iron oxide (oxyhydroxide).

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Key Engineering Materials (Volume 905)

Pages:

344-349

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.905.344

Citation:

Cite this paper

Online since:

January 2022

Authors:

Bo Jiang*

Keywords:

Green Rusts, Hydration, Ordinary Portland Cement (OPC), Transformantion

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

* - Corresponding Author

References

[1] J.H. Ramirez, F.J. Maldonado-Hódar, A.F. Pérez-Cadenas, C. Moreno-Castilla, C.A. Costa, L.M. Madeira, Azo-dye Orange II degradation by heterogeneous Fenton-like reaction using carbon-Fe catalysts, Applied Catalysis B: Environmental 75 (2007) 312-323.

DOI: 10.1016/j.apcatb.2007.05.003

Google Scholar

[2] Y. Flores, R. Flores, A. A. Gallegos, Heterogeneous catalysis in the Fenton-type system reactive black5/H2O2, Journal of Molecular Catalysis A: Chemical. 281 (2008) 184-191.

DOI: 10.1016/j.molcata.2007.10.019

Google Scholar

[3] E.Guélou, J.Barrault, J.Fournier, J.M. Tatibouët, Active iron species in the catalytic wet peroxide oxidation of phenol over pillared clays containing iron, Applied Catalysis B: Environmental 44 (2003) 1-8.

DOI: 10.1016/s0926-3373(03)00003-1

Google Scholar

[4] Q.Q. Chen, P.X Wu, Z. Dang, N.W. Zhu, P. Li, J.H Wu, X.D. Wang, Iron pillared vermiculite as a heterogeneous photo-Fenton catalyst for photocatalytic degradation of azo dye reactive brilliant orange X-GN, Separation and Purification Technology. 71 (2010) 315-323.

DOI: 10.1016/j.seppur.2009.12.017

Google Scholar

[5] H. Hassan, B.H. Hameed, Oxidative decolorization of Acid Red 1 solutions by Fe-zeolite Y type catalyst, Desalination 276 (2011) 45-52.

DOI: 10.1016/j.desal.2011.03.018

Google Scholar

[6] S.S Chou, C.C Liao, S.H. Perng, S.H. Chang, Factors influencing the preparation of supported iron oxide in fluidized-bed crystallization, Chemosphere. 54 (2004) 859-866.

DOI: 10.1016/j.chemosphere.2003.09.034

Google Scholar

[7] F.V. de Andrade, G.M. de Lima, R. Augusti, M.G. Coelho, J.D. Ardisson, O.B. Romero, A versatile approach to treat aqueous residues of textile industry: The photocatalytic degradation of Indigo Carmine dye employing the autoclaved cellular concrete/Fe2O3 system, Chemical Engineering Journal. 180 (2012) 25-31.

DOI: 10.1016/j.cej.2011.10.089

Google Scholar

[8] P.Refait, J.M.R. Génin. The mechanisms of oxidation of ferrous hydroxychloride β-Fe2(OH)3Cl in aqueous solution: The formation of akaganeite vs goethite, Corrosion Science. 6 (1997) 539-553.

DOI: 10.1016/s0010-938x(97)86102-1

Google Scholar

[9] S. Kwon, K. Kimijima, K. Kanie, S. Suzuki, A.I. Muramatsu, M.I. Saito, K. Shinoda, Y.O. Waseda. Influence of silicate ions on the formation of goethite from green rust in aqueous solution, Corrosion Science. 6 (2007) 2946-2961.

DOI: 10.1016/j.corsci.2007.01.007

Google Scholar

[10] P. Refait, O. Benali, M. Abdelmoula, J.M.R. Genin, Formation of ferric green rust and/or ferrihydrite by fast oxidation of iron(II-III) hydroxychloride green rust,Corrosion Science. 3(2003) 2435-2449.

DOI: 10.1016/s0010-938x(03)00073-8

Google Scholar

[11] X.Wang, F. Liu, W.Tan, X.Feng, L.K. Koopal, Transformation of hydroxycarbonate green rust into crystalline iron (hydr)oxides:Influences of reaction conditions and underlying mechanisms, Chemical Geology. 6 (2013) 57-65.

DOI: 10.1016/j.chemgeo.2013.05.003

Google Scholar

[12] O.Benali, M. Abdelmoula, P. Refait, J.M, R. Genin, Effect of orthophosphate on the oxidation products of Fe(II)-Fe(III) hydroxycarbonate: The transformation of green rust to ferrihydrite, Geochimica et Cosmochimica Acta. 65 (2001) 1715-1726.

DOI: 10.1016/s0016-7037(01)00556-7

Google Scholar