Recovery of Light Rare Earth Elements (LREE) from Monazite by Alkaline Fusion

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Malaysia has many potential mineral resources including some rare earth elements (REE) minerals such as monazite. REE play critical roles in the applications of advanced materials. Alkaline fusion was introduce to monazite to break the bonding between Light Rare Earth Elements (LREE) and phosphate. In this study, critical parameter such as fusion temperature (100 °C to 250 °C) and duration (1 to 4 hours) were studied. The results shows that it is possible to recover nearly 100% of Neodymium after 2 hours fusion at 150 °C. In the other hand, more than 99% of Cerium and Lanthanum were recovered after 3 hours fusion at similar temperature. By recover most of the element, expectantly high yield of single LREE can be achieved in the forthcoming.

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503-508

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January 2022

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. M. Xaba, M. Nete and W. Purcell, Concentration of rare earth elements from monazite by selective precipitation, IOP Conf. Series: Mater. Sci. and Eng. 430 (2018) 012006.

DOI: 10.1088/1757-899x/430/1/012006

Google Scholar

[2] R. D. Abreu, and C. A. Morais, Purification of rare earth elements from monazite sulphuric acid leach liquor and the production of high-purity ceric oxide, Miner. Eng. 23 (2010) 536–540.

DOI: 10.1016/j.mineng.2010.03.010

Google Scholar

[3] F. Xie, T. A. Zhang, D. Dreisinger and F. Doyle, A critical review on solvent extraction of rare earths from aqueous solutions, Miner. Eng. 56 (2014) 10-28.

DOI: 10.1016/j.mineng.2013.10.021

Google Scholar

[4] R. S. Dybczynski and K. Kulisa, Nomadic behavior of Sc and Y with respect to lanthanide series in chromatographic separations. Analytical and technological aspects, a review, Trends in Anal. Chem. 115 (2019) 23-38.

DOI: 10.1016/j.trac.2019.03.001

Google Scholar

[5] A. Kumari, S. Jha, J. N. Patel, S. Chakravarty, M. K. Jha and D. D. Pathak, Processing of monazite leach liquor for the recovery of light rare earth metals (LREMs), Miner. Eng.129 (2018) 9–14.

DOI: 10.1016/j.mineng.2018.09.008

Google Scholar

[6] D. Beltrami, G. J. P. Deblonde, S. Bélair and V. Weigel, Recovery of yttrium and lanthanides from sulfate solutions with high concentration of iron and low rare earth content, Hydrometallurgy 157 (2015) 356-362.

DOI: 10.1016/j.hydromet.2015.07.015

Google Scholar

[7] M. Mohammadi, K. Forsberg, L. Kloo, J. M. D. L. Cruz and Å. Rasmuson, Separation of ND (III), DY(III) and Y(III) by solvent extraction using D2EHPA and EHEHPA, Hydrometallurgy 156 (2015) 215-224.

DOI: 10.1016/j.hydromet.2015.05.004

Google Scholar

[8] V. Innocenzi, I. D. Michelis, B. Kopacek and F. Vegliò, Yttrium recovery from primary and secondary sources: A review of main hydrometallurgical processes, Waste Manage. 34 (2014) 1237-1250.

DOI: 10.1016/j.wasman.2014.02.010

Google Scholar

[9] N. Devi and L. B. Sukla, Studies on liquid-liquid extraction of yttrium and separation from other rare earth elements using bifunctional ionic liquids, Miner. Process. Extract. Metall. Rev. 40 (2019) 46-55.

DOI: 10.1080/08827508.2018.1481058

Google Scholar

[10] A. M. Wai, Selective precipitation of Neodymium oxide (Nd2O3) from Monozite, Int. J. Sci. Eng. Technol. Res. 7 (2018) 2278-7798.

Google Scholar

[11] L. A. Teixeira, R. G. Avelar, D. Majuste and V. S. Ciminelli, Selective Extraction of Rare Earth Elements from Monazite Ores with High Iron Content, Min. Metal. Exploration 3 (2019) 235.

DOI: 10.1007/s42461-018-0035-5

Google Scholar

[12] N. Faris, R. Ram, J. Tardio, S. Bhargava, S. McMaster and M. I. Pownceby, Application of ferrous pyrometallurgy to the beneficiation of rare earth bearing iron ores – A review, Miner. Eng. 110 (2017) 20–30.

DOI: 10.1016/j.mineng.2017.04.005

Google Scholar

[13] A. H. J. Mohd Salehuddin, A. F. Ismail, C. N. A. Che Zainul Bahri and E. S. Aziman, Economic analysis of thorium extraction from monazite. Nuclear Eng. Technol. 51 (2019) 631-640.

DOI: 10.1016/j.net.2018.11.005

Google Scholar

[14] E. M. El-Sheikh, Selective recovery of yttrium and ytterbium oxides from Abu Rusheid REEs concentrate via alkaline leaching and solvent extraction, Arab J. Nuclear Sci. App. 50 (2017) 67-78.

Google Scholar

[15] G. T. Lapidus and F. M. Doyle, Selective thorium and uranium extraction from monazite: I. Single-stage oxalate leaching. Hydrometallurgy, 154 (2015) 102–110.

DOI: 10.1016/j.hydromet.2015.04.006

Google Scholar

[16] J. Temuujin, G. Burmaa, B. Davaabal, D. S. Kim and H. J. Lee, Preparation of rare earth oxides Synchysite oxidized ore by acid leaching, J. Chem. 18 (2017) 1-4.

DOI: 10.5564/mjc.v18i44.931

Google Scholar