Conductive Silicone Rubber Coated by Reduced Graphene Oxide Pseudo-Photonic Crystal Film

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Graphene aqueous dispersion is difficult to be prepared as conductive film by simple solvent evaporation deposition, not only because of the agglomeration in its aqueous solution, but also caused by the “coffee ring” phenomenon during solvent evaporation process. Herein, as a derivative of graphene, graphene oxide (GO) would be used as film forming material due to its good dispersion in aqueous solution and its liquid crystallinity. If GO can self-assemble as a compact pseudo-photonic crystal film by solvent evaporation deposition, it will be converted into a conducive graphene film after thermal reduction. In order to prepare a flexible and conductive elastomer material covered with graphene film, compact GO pseudo-photonic crystal film can be transferred onto the surface of a 10% stretched silicone rubber plate. After releasing the stretched force, GO pseudo-photonic crystal film can form a lot of folds, which provide allowance of shrinkage for this GO pseudo-photonic crystal film to avoid cracking during the high temperature reduction. Benefiting from transferring the GO film onto a stretched silicone rubber, a flexible, colored and conductive graphene/SR can be obtained.

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67-72

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March 2022

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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[1] Wassei J K, Kaner R B. Graphene, a promising transparent conductor. Materials today, 13(3) (2010) 52-59.

DOI: 10.1016/s1369-7021(10)70034-1

Google Scholar

[2] Su C-Y, Lu A-Y, Xu Y, et al. High-quality thin graphene films from fast electrochemical exfoliation. ACS nano, 5(3) (2011) 2332-2339.

DOI: 10.1021/nn200025p

Google Scholar

[3] Bonaccorso F, Sun Z, Hasan T, et al. Graphene photonics and optoelectronics. Nature Photonics, 4(9) (2010) 611-622.

DOI: 10.1038/nphoton.2010.186

Google Scholar

[4] Choudhary S, Crosby A J. Controlled evaporative self-assembly of polymer nanoribbons using oscillating capillary bridges. Journal of Polymer Science Part B: Polymer Physics, 56(23) (2018) 1545-1551.

DOI: 10.1002/polb.24730

Google Scholar

[5] Shao J J, Lv W, Yang Q H. Self-assembly of graphene oxide at interfaces. Advanced Materials, 26(32) (2014) 5586-5612.

DOI: 10.1002/adma.201400267

Google Scholar

[6] Paek K, Yang H, Lee J, et al. Efficient colorimetric pH sensor based on responsive polymer–quantum dot integrated graphene oxide. ACS nano, 8(3) (2014) 2848-2856.

DOI: 10.1021/nn406657b

Google Scholar

[7] Dreyer D R, Park S, Bielawski C W, et al. The chemistry of graphene oxide. Chemical society reviews, 39(1) (2010) 228-240.

Google Scholar

[8] Xu Z, Gao C. Aqueous liquid crystals of graphene oxide. Acs Nano, 5(4) (2011) 2908-2915.

DOI: 10.1021/nn200069w

Google Scholar

[9] Narayan R, Kim J E, Kim J Y, et al. Graphene oxide liquid crystals: discovery, evolution and applications. Advanced Materials, 28(16) (2016) 3045-3068.

DOI: 10.1002/adma.201505122

Google Scholar

[10] Jalili R, Aboutalebi S H, Esrafilzadeh D, et al. Scalable one-step wet-spinning of graphene fibers and yarns from liquid crystalline dispersions of graphene oxide: towards multifunctional textiles. Advanced functional materials, 23(43) (2013) 5345-5354.

DOI: 10.1002/adfm.201300765

Google Scholar

[11] Vlasov Y A, Bo X-Z, Sturm J C, et al. On-chip natural assembly of silicon photonic bandgap crystals. Nature, 414(6861) (2001) 289.

DOI: 10.1038/35104529

Google Scholar

[12] Zhu J, Wang J, Lv F, et al. Synthesis and self-assembly of photonic materials from nanocrystalline titania sheets. Journal of the American Chemical Society, 135(12) (2013) 4719-4721.

DOI: 10.1021/ja401334j

Google Scholar

[13] Tong L, Qi W, Wang M, et al. Tunable Design of Structural Colors Produced by Pseudo-1D Photonic Crystals of Graphene Oxide. Small, 12(25) (2016) 3433-3443.

DOI: 10.1002/smll.201600148

Google Scholar

[14] Okoshi M, Iyono M, Inoue N, et al. Photochemical welding of silica microspheres to silicone rubber by ArF excimer laser. Applied Surface Science, 255(24) (2009) 9796-9799.

DOI: 10.1016/j.apsusc.2009.04.072

Google Scholar

[15] Wang Y, Gregory C, Minor M A. Improving mechanical properties of molded silicone rubber for soft robotics through fabric compositing. Soft robotics, 5(3) (2018) 272-290.

DOI: 10.1089/soro.2017.0035

Google Scholar