Study of Phosphorus-Containing Silica Coatings Based on Liquid Glass for Fire Protection of Textile Materials

Abstract:

By introducing, in addition to phosphorus, nitrogen and halogens into the structure of the organosilicon compound, a synergistic effect of the flame retardant effect of the fabric is achieved, but the issue of protecting the environment from the effects of thermal decomposition products of the flame retardant composition arises. In view of the numerous publications on the impact of thermal destruction products of flame retardants on the ecological state of the environment, the problem of finding safe types of flame retardants that do not release toxic decomposition products during thermal destruction has arisen. The aim of the work was to develop a phosphorus-and nitrogen-containing silicate fire-retardant composition based on safe components that do not produce toxic products during thermal destruction of the treated fabric. As a result of the conducted research, it was established the possibility of using modifying additives (orthophosphoric acid and ammonium dihydrogen phosphate) in the composition of protective sol based on liquid glass. It was established that the introduction of small additions of orthophosphoric acid into the SiO₂ золь сприяє утворенню суцільних тонких кремнеземних плівок на поверхні волокон ниток бавовняної тканини та значно збільшує час початку руйнування тканини під дією вогню. Позитивний результат досягався за умов одноразового просочування золем низької концентрації (8% SiO ₂ ). Встановлено, що додавання дигідрофосфату амонію також позитивно впливає на підвищення вогнезахисних властивостей тканини. Оптимальний діапазон концентрації розчину фосфоровмісної добавки становить 10-15%. Додаткове просочення вогнезахисним розчином підвищує вогнестійкі властивості текстильних матеріалів і перешкоджає остаточному прогоранню і тлінню.

• Periodical: Key Engineering Materials (Volume 954)
• Pages: 167-175
• DOI: https://doi.org/10.4028/p-hGYQ9v
• Online since: August 2023
• Authors: Olga Skorodumova*, Olena Tarakhno, Atabala M. Babayev, Anton Chernukha, Svitlana Shvydka
• Keywords: Cotton-Containing Textile Materials, Fire Resistance, Layer-by-Layer Assembly, Liquid Glass, Phosphorus-Containing Silica Coatings, Sol-Gel Method

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