The Influence of the Synthesis Method on the Formation of Phase Composition and Catalytic Centers Gd2Zr2O7

Ekaterina Borisovna Markova; Alexander Genrihovich Cherednichenko; V.V. Kurilkin; J.M. Serov

doi:10.4028/www.scientific.net/MSF.1009.69

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HomeMaterials Science ForumMaterials Science Forum Vol. 1009The Influence of the Synthesis Method on the...

The Influence of the Synthesis Method on the Formation of Phase Composition and Catalytic Centers Gd₂Zr₂O₇

Abstract:

The influence of the type of crystal structure of complex gadolinium oxides on their catalytic activity was studied using a wide range of physicochemical methods. It was shown that the synthesized nanocrystalline powders Gd₂Zr₂O₇ form highly symmetric face-centered cubic crystal structures. In the course of catalytic experiments, it was found that the formation of a cubic structure increases the degree of conversion of propane and the shift of cracking temperatures to a lower area. The formation of various defects contributes to the course of the dehydrogenation or degradation reaction due to the different number of catalytic centers.

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Periodical:

Materials Science Forum (Volume 1009)

Pages:

69-74

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.1009.69

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Online since:

August 2020

Authors:

Ekaterina Borisovna Markova*, Alexander Genrihovich Cherednichenko, V.V. Kurilkin, J.M. Serov

Keywords:

Catalytic Centers, Complex Oxides, Light Olefins, Propane

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References

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