The Effect of Various Nanoclay Surface Modifications on the Thermal and Mechanical Properties of Amorphous Polyamide Nanocomposites

Article Preview

Abstract:

The addition of nanoclay within polymer matrix is anticipate to enhance the properties of the polymer system. Nonetheless, one of the key elements in property enhancements of a polymer nanocomposites is the surface modifications of the nanoclay. This is due to the affinity between polymer matrix and nanoclay is of important factors should be considered. In this study, amorphous polyamide were melt blended with different nanoclay grades with different surface modifications in order to evaluate the best clay grade for the polymer system. The thermal analysis carried out on the amorphous polyamide nanocomposites were carried out by means of differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) whereas the mechanical properties were investigated using tensile testing. It was observed that there were changes in the glass transition temperature (Tg) of the nanocomposites due to clay additions. Further, the storage modulus was found to increase as a result of nanoclay incorporation. The type of clay grades significantly affects the mechanical properties of the amorphous polyamide nanocomposites.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1010)

Pages:

154-159

Citation:

Online since:

September 2020

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Sinha Ray and M. Okamoto, Polymer/layered silicate nanocomposites: a review from preparation to processing,, Progress in Polymer Science, vol. 28, no. 11, pp.1539-1641, 2003,.

DOI: 10.1016/j.progpolymsci.2003.08.002

Google Scholar

[2] S. Pavlidou and C. D. Papaspyrides, A review on polymer-layered silicate nanocomposites,, Progress in Polymer Science, vol. 33, no. 12, pp.1119-1198, 2008,.

DOI: 10.1016/j.progpolymsci.2008.07.008

Google Scholar

[3] M. Alexandre and P. Dubois, Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials,, Materials Science and Engineering: R: Reports, vol. 28, no. 1-2, pp.1-63, 2000,.

DOI: 10.1016/s0927-796x(00)00012-7

Google Scholar

[4] T. D. Fornes, P. J. Yoon, D. L. Hunter, H. Keskkula, and D. R. Paul, Effect of organoclay structure on nylon 6 nanocomposite morphology and properties,, Polymer, vol. 43, no. 22, pp.5915-5933, 2002,.

DOI: 10.1016/s0032-3861(02)00400-7

Google Scholar

[5] T. Liu, K. Ping Lim, W. Chauhari Tjiu, K. P. Pramoda, and Z.-K. Chen, Preparation and characterization of nylon 11/organoclay nanocomposites,, Polymer, vol. 44, no. 12, pp.3529-3535, 2003,.

DOI: 10.1016/s0032-3861(03)00252-0

Google Scholar

[6] T. McNally, W. Raymond Murphy, C. Y. Lew, R. J. Turner, and G. P. Brennan, Polyamide-12 layered silicate nanocomposites by melt blending,, Polymer, vol. 44, no. 9, pp.2761-2772, 2003,.

DOI: 10.1016/s0032-3861(03)00170-8

Google Scholar

[7] N. Aït Hocine, P. Médéric, and T. Aubry, Mechanical properties of polyamide-12 layered silicate nanocomposites and their relations with structure,, Polymer Testing, vol. 27, no. 3, pp.330-339, 2008, doi:.

DOI: 10.1016/j.polymertesting.2007.12.002

Google Scholar

[8] W. Yu et al., Crystallization behavior of poly(vinylidene fluoride)/montmorillonite nanocomposite,, Polymer Engineering & Science, vol. 49, no. 3, pp.491-498, 2009,.

DOI: 10.1002/pen.21308

Google Scholar

[9] T. D. Fornes and D. R. Paul, Crystallization behavior of nylon 6 nanocomposites,, Polymer, vol. 44, no. 14, pp.3945-3961, 2003, doi:.

DOI: 10.1016/s0032-3861(03)00344-6

Google Scholar

[10] L. Shen, I. Y. Phang, L. Chen, T. Liu, and K. Zeng, Nanoindentation and morphological studies on nylon 66 nanocomposites. I. Effect of clay loading,, Polymer, vol. 45, no. 10, pp.3341-3349, 2004, doi:.

DOI: 10.1016/j.polymer.2004.03.036

Google Scholar

[11] T. G. Gopakumar, J. A. Lee, M. Kontopoulou, and J. S. Parent, Influence of clay exfoliation on the physical properties of montmorillonite/polyethylene composites,, Polymer, vol. 43, no. 20, pp.5483-5491, 2002, doi:.

DOI: 10.1016/s0032-3861(02)00403-2

Google Scholar

[12] G. Choudalakis and A. D. Gotsis, Free volume and mass transport in polymer nanocomposites,, Current Opinion in Colloid & Interface Science, vol. 17, no. 3, pp.132-140, 2012, doi: http://dx.doi.org/10.1016/j.cocis.2012.01.004.

DOI: 10.1016/j.cocis.2012.01.004

Google Scholar

[13] D. R. Paul and L. M. Robeson, Polymer nanotechnology: Nanocomposites,, Polymer, vol. 49, no. 15, pp.3187-3204, 2008, doi:.

DOI: 10.1016/j.polymer.2008.04.017

Google Scholar