Layer-Thickness Dependence of Hardness and Local Bucking Behavior in Electrodeposited Ni-Co-Cu/Cu Multilayered Films

Article Preview

Abstract:

The effect of layer thickness on hardness and buckling behavior was investigated on Ni-Co-Cu/Cu multilayered films. The Ni-Co-Cu/Cu multilayered films were grown on annealed copper substrates by electrodeposition. We fabricated the multilayered films with various layer thicknesses ranging from 10 nm to 1000 nm. First, dependence of Vickers hardness on the Cu layer thickness was investigated. When the Ni-Co-Cu layer had the constant thickness of 75 nm and the Cu layer thickness was smaller than 75 nm, the hardness increased rapidly with decreasing Cu layer thickness. Subsequently, compressive tests were conducted on the multilayered films having the component layers ranging from100 nm to 1000 nm, where the hardness values did not change rapidly with layer thickness. The copper substrates coated with the multilayered films were compressed until 20% strain. From SEM surface observations after the compressive tests, formations of band-like structures having a certain thickness were recognized. Cross-sectional observation revealed that some band-like structures were formed as a result of local buckling of the multilayered film. The vertical thickness of the bank-like structures increased linearly with increasing component layer thickness.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1016)

Pages:

170-176

Citation:

Online since:

January 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Y. Kawamura, M. Yamasaki, Formation and mechanical properties of Mg97Zn1RE2 alloys with long-period stacking ordered structure, Mater.Trans. 48 (2007) 2986-2992.

DOI: 10.2320/matertrans.mer2007142

Google Scholar

[2] S. Yoshimoto, M. Yamasaki, Y. Kawamura, Microstructure and mechanical properties of extruded Mg-Zn-Y alloys with 14H long period ordered structure, Mater.Trans. 47 (2006) 959-965.

DOI: 10.2320/matertrans.47.959

Google Scholar

[3] M. Hirano, M. Yamasaki, K. Hagihara, K. Higashida, Y. Kawamura, Effect of extrusion parameters on mechanical properties of Mg97Zn1Y2 alloys at room and elevated temperatures, Mater.Trans. 51 (2010) 1640-1647.

DOI: 10.2320/matertrans.maw201026

Google Scholar

[4] J. Wang, P. Song, X. Zhou, X. Huang, F. Pan, Influence of the morphology of long-period stacking ordered phase on the mechanical properties of as-extruded Mg–5Zn–5Y–0.6Zr magnesium alloy, Mater.Sci.Eng.A 556 (2012) 68-75.

DOI: 10.1016/j.msea.2012.06.059

Google Scholar

[5] X.H. Shao, Z.Q. Yang, X.L. Ma, Strengthening and toughening mechanisms in Mg–Zn–Y alloy with a long period stacking ordered structure, Acta Mater. 58 (2010) 4760-4771.

DOI: 10.1016/j.actamat.2010.05.012

Google Scholar

[6] E. Oñorbe, G. Garcés, P. Pérez, P. Adeva, Effect of the LPSO volume fraction on the microstructure and mechanical properties of Mg–Y2X–ZnX alloys, J.Mater.Sci. 47 (2012) 1085-1093.

DOI: 10.1007/s10853-011-5899-4

Google Scholar

[7] E. Oñorbe, G. Garcés, F. Dobes, P. Pérez, P. Adeva, High-temperature mechanical behavior of extruded Mg-Y-Zn alloy containing LPSO phases, Metall.Mater.Trans.A 44A (2013) 2869-2883.

DOI: 10.1007/s11661-013-1628-8

Google Scholar

[8] J-K. Kim, S. Sandlöbes, D. Raabe, On the room temperature deformation mechanisms of a Mg–Y–Zn alloy with long-period-stacking-ordered structures, Acta Mater. 82 (2015) 414-423.

DOI: 10.1016/j.actamat.2014.09.036

Google Scholar

[9] K. Hagihara, Z. Li, M. Yamasaki, Y. Kawamura, T. Nakano, Strengthening mechanisms acting in extruded Mg-based long-period stacking ordered (LPSO)-phase alloys, Acta Mater. 163 (2019) 226-239.

DOI: 10.1016/j.actamat.2018.10.016

Google Scholar

[10] S. Menezes, D.P. Anderson, Wavelength-Property correlation in electrodeposited ultrastructured Cu-Ni multilayers., J.Electrochem.Soc. 137 (1990) 440-444.

DOI: 10.1149/1.2086459

Google Scholar

[11] D.M. Tench, J.T. White, Tensile properties of nanostructured Ni-Cu multilayered materials prepared by electrodeposition, J.Electrochem.Soc. 138 (1991) 3757-3758.

DOI: 10.1149/1.2085495

Google Scholar

[12] R.C. Cammarata, T.E. Schlesinger, C. Kim, S.B. Qadri, A.S. Edelstein, Nanoindentation study of the mechanical properties of copper-nickel multilayered thin films, Appl.Phys.Lett. 56 (1990) 1862-1864.

DOI: 10.1063/1.103070

Google Scholar

[13] R.R. Oberle, R.C. Cammarata, Dependence of hardness on modulation amplitude in electrodeposited Cu-Ni compositionally modulated thin films, Scripta Metall.Mater. 32 (1995) 583-588.

DOI: 10.1016/0956-716x(95)90841-7

Google Scholar

[14] A. Misra, M. Verdier, Y.C. Lu, H. Kung, T.E. Mitchell, M. Nastasi, J.D. Embury, Structure and mechanical properties of Cu-X (X = Nb, Cr, Ni) nanolayered composites, Scripta Mater. 39 (1998) 555-560.

DOI: 10.1016/s1359-6462(98)00196-1

Google Scholar

[15] Y. Kaneko, Y. Mizuta, Y. Nishijima, S. Hashimoto, Vickers hardness and deformation of Ni/Cu nano-multilayers electrodeposited on copper substrate, J.Mater.Sci. 40 (2005) 3231-3236.

DOI: 10.1007/s10853-005-2690-4

Google Scholar

[16] H. Hagiwara, N. Kawakami, Y. Kaneko, M. Uchida, Dependence of Vickers hardness on layer thickness in electrodeposited Ni-Co-Cu/Cu multilayered films, Mater.Trans. 60 (2019) 2569-2575.

DOI: 10.2320/matertrans.mt-m2019165

Google Scholar

[17] J.B. Hess, C.S. Barrett, Structure and nature of kink bands in zinc, Trans. AM. Inst. Min. Met. Eng. 185 (1949) 599-606.

DOI: 10.1007/bf03398902

Google Scholar

[18] R.G. Budynas, J.K. Nisbett, Shigley's mechanical engineering design, Ninth edition, McGraw-Hill, New York, 2008, pp.181-184.

Google Scholar