Effect of Graphene Content on the Micromorphology, Microhardness and Micro Frictional Resistance of Co-Ni-Graphene Composite Coating

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Abstract:

In order to obtain the alloy composite material with high hardness, good anti-friction property and low friction coefficient, the electrodeposition technology was used to prepare nanocrystalline Co-Ni-graphene composite coating on the surface of low carbon steel by means of ultrasonic dispersion combined with mechanical agitation. The influence of graphene content in electrolyte on composite coating was studied. The surface microstructure, composition, phase structure, micro-hardness and micro-wear properties of composite coating were measured by scanning electron microscopy, energy spectrometer, X-ray diffractometer, micro-hardness tester and UNMT-1 comprehensive mechanical testing system for micro-nanometer materials. The results show that with the increase of the content of graphene in the electrolyte the graphene particles were embedded in the alloy coating, which changes the crystal structure of the alloy coating and improves the microhardness and micro friction resistance of the coating. When the content of graphene in the electrolyte was 0.9g/L the microstructure of the composite coating was fine and uniform, the highest microhardness value was 678 HV, the minimum average friction coefficient was 0.15, and the composite coating had good wear resistance.

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Materials Science Forum (Volume 1035)

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608-614

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June 2021

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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[1] Kim S J, Kim J K. Effects of temperature and contactstress on the sliding wear of Ni-base Deloro 50 hardfacing alloy. Journal of Nuclear Materials, 2001, 288(2-3): 163−169.

DOI: 10.1016/s0022-3115(00)00711-x

Google Scholar

[2] Ma Zhao-hai. Electrodeposition and structure and properties of nickel base alloy and composite coating. Xiamen, Xiamen University, 2006. (in Chinese).

Google Scholar

[3] Li Ai-lian, Guo Zhong-cheng, Zhang Guang-li. Research status of electrodeposited nickel-base alloys and their composite coatings. Plating & Environmen-tal Protection, 2003, 23(1):1-7. (in Chinese).

Google Scholar

[4] Guo Zhong-cheng, Li Ailian, Zhang Guangli. Research status and development trend of electrodeposited ni-based alloys and their composite coatings. 2002 Proceedings of the Beijing electroplating industry cleaner production symposium. 2002. (in Chinese).

Google Scholar

[5] Siokou A, Ravani F, Karakalos S, et al. Surface refinement andelectronic properties of graphene layers grown on copper sub-strate: An XPS, UPS and EELS study. Appl. Surf. Sci., 2011, 257: 9785.

DOI: 10.1016/j.apsusc.2011.06.017

Google Scholar

[6] Ramanathan T, Abdala A A, Stankovich S, et al. Functionalized graphene sheets for polymer nanocomposites. Nature Nanotechnology, 2008, 3(6): 327-331.

Google Scholar

[7] Feng C, Wang Y, Yang J. Effects of Reorientation of Graphene Platelets (GPLs) on Young's Modulus of Polymer Composites under Bi-Axial Stretching. Nanomaterials, 2018, 8(1): 532.

DOI: 10.3390/nano8010027

Google Scholar

[8] Cogal S, Calio L, Cogal G C, et al. RF plasma-enhanced graphene-polymer composites as hole transport materials for perovskite solar cells. Polymer Bulletin, 2018: 1-15.

DOI: 10.1007/s00289-018-2275-4

Google Scholar

[9] Hussein A, Kim B. Graphene/polymer nanocomposites: the active role of the matrix in stiffening mechanics[J]. Composite Structures, (2018).

DOI: 10.1016/j.compstruct.2018.01.023

Google Scholar

[10] Qi S, Li X, Zhang Z, et al. Fabrication and characterisation of electro-brush plated nickel-graphene oxide nano-compos-ite coatings. Thin Solid Films, 2017, 644.

DOI: 10.1016/j.tsf.2017.06.064

Google Scholar

[11] B Szeptycka, A Gajewskamidzialek. Nickel-graphene composite coatings. Composites Theory and Practice, 2015, 15(2): 107-111.

Google Scholar

[12] Zhang F, Luo P, Guo J, et al. Synthesis and dispersion stability of Cu/rGO nanofluids. Science & Technology in Chemical Industry, (2017).

Google Scholar

[13] Wu Hui-hui. Preparation and properties of Ni-P-GO chemical composite deposits. Shanghai Institute of Technology, (2015).

Google Scholar