Preparation and Properties of Formic Acid Intercalated Mg-Al Layered Double Hydroxides Deicing Additive

Article Preview

Abstract:

Formic acid intercalated Mg-Al layered double hydroxide (Mg-Al Fo-LDH) was prepared by calcination reduction intercalation assembly technology. The structure of the deicing additive was characterized by fourier transform infrared (FTIR) and X-ray diffraction (XRD). The freezing point of aqueous solution with different quality of deicing additive and the surface freezing point and adhesion of asphalt mixture were tested. The results show that formic acid ion has been intercalated into the interlayer of Mg-Al layered double hydroxide by FTIR and XRD patterns. The freezing point of 5wt% Mg-Al Fo-LDH aqueous solution reaches -9.32 °C, while the surface freezing point of the asphalt mixture mixed with 5wt% Mg-Al Fo-LDH is -6.5°C. At -8 °C, the adhesion force of the surface ice layer is 78.4N, and after the asphalt mixture is soaked in water, the surface freezing point and adhesion force of the ice layer do not change.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1035)

Pages:

966-971

Citation:

Online since:

June 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Fay L, Shi X. Environmental Impacts of Chemicals for Snow and Ice Control: State of the Knowledge[J]. Water Air & Soil Pollution, 2012, 223(5):2751-2770.

DOI: 10.1007/s11270-011-1064-6

Google Scholar

[2] Shi X, Fay L, Yang Z, et al. Corrosion of Deicers to Metals in Transportation Infrastructure: Introduction and Recent Developments[J]. Corrosion Reviews, 2009, 27(1-2).

DOI: 10.1515/corrrev.2009.27.1-2.23

Google Scholar

[3] Yu Y X. Development and prospect of pavement active ice (snow) melting technology[J]. Shanghai Jiaotong Daxue Xuebao/Journal of Shanghai Jiaotong University, 2011, 45:86-89.

Google Scholar

[4] Wang X Y, Gao Y X. Research on the preparation of conductive asphalt concrete for deicing and snow melting[J]. (2010).

Google Scholar

[5] Na L I, Hai-Feng W, Xi-Juan X U. Experiment Research of Asphalt Mixture with Salt for Melting Snow and Ice[J]. Transportation Standardization, (2014).

Google Scholar

[6] Arakiy T I,Suzuki S. Follow-up survey on powder/chloride freeze control pavement: survey cases of Europe and Japan [J]. Pavement, 1997, 32 (9): 8-14.

Google Scholar

[7] Wang Z, Zhang T, Shao M, et al. Investigation on snow-melting performance of asphalt mixtures incorporating with salt-storage aggregates [J]. Construction & Building Materials, 2017, 142: 187-198.

DOI: 10.1016/j.conbuildmat.2017.03.070

Google Scholar

[8] Dubois R. Road-surface additive for preventing ice and melting snow [P]. U.S. Patent: 4094686, 1978-6-13.

Google Scholar

[9] Cavani F.F. Trifirò V.A. Hydrotalcite-Type Anionic Clays: Preparation, Properties and Applications[J]. Catalysis Today, 1991, 11(2): 173-301.

DOI: 10.1016/0920-5861(91)80068-k

Google Scholar

[10] Khan A I, Lei L, Norquist A J, et al. Intercalation and controlled release of pharmaceutically active compounds from a layered double hydroxide[J]. Chemical Communications, 2001, 37.

Google Scholar

[11] Chibwe M, Pinnavaia T J. Stabilization of a cobalt(II) phthalocyanine oxidation catalyst by intercalation in a layered double hydroxide host[J]. Journal of the Chemical Society, Chemical Communications, 1993, 3(3):1837-1845.

DOI: 10.1039/c39930000278

Google Scholar