Effect of Non-Sulfur Stabilizer on Performance of SBS Modified Bitumen

Article Preview

Abstract:

Based on the reason that SBS modified bitumen (SMB) with sulfur stabilizer is easy to degrade during aging, a novel non-sulfur stabilizer, P-benzoquinone oxime (GMF), was used to modify SMB. The effects of GMF and sulfur stabilizer on the thermal storage stability, low-temperature performance and aging resistance of SMB were investigated. The results indicate that GMF is more beneficial to improve the thermal storage stability, the low temperature flexibility and softening point of SMB than that of sulfur. And GMF can restrain the degradation of the low temperature flexibility of SMB after thermal aging as compared with sulfur. Fourier transform infrared spectroscopy indicates that the aging growth index of GMF/SBS modified bitumen is 33.5% lower than that of sulfur/SBS modified bitumen after aging. Fluorescence microscope proves that the addition of GMF can prevent the destruction of cross-linking network structure of SBS in bitumen during aging process, which also demonstrates that GMF can improve the aging resistance of SMB. Therefore, GMF can be more suitable as a stabilizer for SMB.

You might also be interested in these eBooks

Info:

Periodical:

Materials Science Forum (Volume 1035)

Pages:

944-950

Citation:

Online since:

June 2021

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2021 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Navarro, F.J., Partal, P., Gallegos, C., and Areizaga, J. Effect of processing variables on the linear viscoelastic properties of SBS-oil blends. Polym Eng Sci. 41(12) (2001): 2216-25.

DOI: 10.1002/pen.10917

Google Scholar

[2] Norrman, J., Rosén, L., and Norin, M. Decision analysis for storage for reclaimed bitumen. Environ. Eng. Sci. 22(2005), 783-801.

DOI: 10.1089/ees.2005.22.783

Google Scholar

[3] Yang, Z.X., Zhang, S., and Xian, M. Impact of nanoclay and carbon microfiber in combating the deterioration of asphalt concrete by non-chloride deicers. Constr. Build. Mater. 160, (2018) 514-525.

DOI: 10.1016/j.conbuildmat.2017.11.059

Google Scholar

[4] Liang, Xin. X., Fan, W.Y., Ren, S.S., Liang, M., and Wang, H. Effects of polymerized sulfur on rheological properties, morphology and stability of SBS modified bitumen.Constr. Build. Mater. 150(sep.30), (2017), 860-871.

DOI: 10.1016/j.conbuildmat.2017.06.069

Google Scholar

[5] Ho, R. M., Adedeji, A., Giles, D. W., Hajduk, D. A., Macosko, C. W. and Bates, F. S. Microstructure of triblock copolymers in asphalt oligomers.J Polym Sci: Part B Polym Phys. 35(1997): 2857–2877.

DOI: 10.1002/(sici)1099-0488(199712)35:17<2857::aid-polb10>3.0.co;2-6

Google Scholar

[6] Lu, X., U. Isacsson. Compatibility and storage stability of styrene-butadiene-styrene copolymer modified bitumens. Mater Struct Mater Constr. 30(10) (1997): 618-26.

DOI: 10.1007/bf02486904

Google Scholar

[7] Chen, J.S., Hang, C.C. Fundamental characterization of SBS-modified bitumen mixed with sulfur. J. Appl. Polym. Sci. 103(2007): 2817-2825.

DOI: 10.1002/app.24621

Google Scholar

[8] Sun, D.Q., Ye, F., Shi, F.Z, and Lu, W.M. Storage Stability of SBS-Modified Road Bitumen: Preparation, Morphology, and Rheological Properties. Petrol Sci Technol. 24(9) (2006): 1067-1077.

DOI: 10.1081/lft-200048186

Google Scholar

[9] Zhang, F., Yu, J.Y., and Wu, S.P. Effect of ageing on rheological properties of storage-stable SBS/sulfur-modified bitumens. J Hazard Mater. 182 (1-3) (2010): 507-517.

DOI: 10.1016/j.jhazmat.2010.06.061

Google Scholar

[10] Ong K.L. Curing mechanism of p-benzoquinone dioxime. Journal of IRI. 6(1) (1972):16-18.

Google Scholar