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HomeMaterials Science ForumMaterials Science Forum Vol. 1064XRD Analysis of LiFeO2 Formation from Li2CO3-Fe2O3...

XRD Analysis of LiFeO₂ Formation from Li₂CO₃-Fe₂O₃Mechanically Activated Reagents

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Abstract:

The formation of LiFeO₂ lithium ferrite from unmilled and milled Fe₂O₃-Li₂CO₃ mixture was studied by X-ray powder diffraction (XRD). The ball milling was perform via AGO-2S high-energy planetary ball mill at a rotational speed of 2220 rpm for 60 min. Solid-phase synthesis was carried out by conventional laboratory furnace at 600 °C. Using PowderCell 2.4 software, the structural parameters of the reagents and ferrite obtained from these were determined. According to the XRD data, the crystallite sizes of the milled reagents decreased, while the strains increased. It was found that the synthesized ferrite is characterized by multiphase composition consisting of unreacted initial reagents, α-LiFeO₂, γ-LiFeO₂ and α-Li_0.5Fe_2.5O₄ phases, the concentration of which depends on the prehistory of the mixture.

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Periodical:

Materials Science Forum (Volume 1064)

Pages:

129-138

DOI:

https://doi.org/10.4028/p-owy6gu

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Online since:

June 2022

Authors:

Elena Nikolaevna Lysenko, Vitaly A. Vlasov*, Anatoly P. Surzhikov, Anatoliy I. Kupchishin

Keywords:

LiFeO₂, Lithium Ferrites, Mechanical Milling, Solid-Phase Synthesis, X-Ray Powder Diffraction

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© 2022 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Barre, M. Catti. Neutron diffraction study of the β' and γ phases of LiFeO2, J. Solid St. Ch., 182 (2009) 2549-2554.

DOI: 10.1016/j.jssc.2009.06.029

[2] Y.T. Lee, C.S. Yoon, Y.S. Lee, Y.-K. Sun. Synthesis and structural changes of LixFeyOz material prepared by a solid-state method, J. Power Sour. 134 (2004) 88-94.

DOI: 10.1016/j.jpowsour.2004.02.001

[3] Y.S. Lee, C.S. Yoon, Y.K. Sun, K Kobayakawa, Y. Sato. Synthesis of nano-crystalline LiFeO2 material with advanced battery performance, Elect. Com. 4 (2002) 727-731.

DOI: 10.1016/s1388-2481(02)00436-8

[4] A.E. Abdel-Ghany, A. Mauger, H. Groult, K. Zaghib, C.M. Julien. Structural properties and electrochemistry of α-LiFeO2, J. Power Sour. 197 (2012) 285-291.

DOI: 10.1016/j.jpowsour.2011.09.054

[5] A.K. Tangra, G.S. Lotey. Synthesis and investigation of structural, optical, magnetic, and biocompatibility properties of nanoferrites AFeO2, Curr. Appl. Ph. 27 (2021) 103-116.

DOI: 10.1016/j.cap.2021.04.011

[6] R. Kanno, T. Shirane, Y. Kawamoto, Y. Takeda, M. Takano, M. Ohashi, Y. Yamaguchi. Synthesis, structure, and electrochemical properties of a new lithium iron oxide, LiFeO2, with a corrugated layer structure, J. Electrochem. Soc. 143 (1996) 2435-2442.

DOI: 10.1149/1.1837027

[7] T. Matsumura, R. Kanno, Y. Inaba, Y. Kawamoto, M. Takano. Synthesis, structure, and electrochemical properties of a new cathode material LiFeO2, with a tunnel structure, J. Electrochem. Soc. 149 (2002) A1509–A1513.

DOI: 10.1149/1.1516769

[8] Y. Sakurai, H. Arai, S. Okada, J. Yamaki. Low temperature synthesis and electrochemical characterization of LiFeO2 cathodes, J. Power Sour. 68 (1997) 711-715.

DOI: 10.1016/s0378-7753(96)02579-7

[9] J.R. Dahn, U. Von Sacken, C.A. Michal. Structure and electrochemistry of Li1 ± yNiO2 and a new Li2NiO2 phase with the Ni(OH)2 structure, Sol. St. Ion. 44 (1990) 87-97.

DOI: 10.1016/0167-2738(90)90049-w

[10] Y. Sakurai, H. Arai, J. Yamaki. Preparation of electrochemically active α-LiFeO2 at low temperature, Solid State Ion. 29 (1998) 113-115.

DOI: 10.1016/s0167-2738(98)00363-4

[11] M. Tabuchi, S. Tsutsui, C. Masquelier, R. Kanno, K. Ado, I. Matsubara, S. Nasu, H. Kageyama. Effect of Cation Arrangement on the Magnetic Properties of Lithium Ferrites (LiFeO2) Prepared by Hydrothermal Reaction and Post-annealing Method, J. Solid St. Ch., 140 (1998) 159-167.

DOI: 10.1006/jssc.1998.7725

[12] G.A. El-Shobaky, A.A. Ibrahim. Solid-solid interactions between ferric oxide and lithium carbonate and the thermal stability of the lithium ferrites produced, Thermoch. Acta. 118 (1987) 151-158.

DOI: 10.1016/0040-6031(87)80079-5

[13] S.K. Rakshit, S.C. Parida, Y.P. Naik, V. Venugopal. Thermodynamic studies on lithium ferrites, J. Solid State Chem. 184 (2011) 1186-1194.

DOI: 10.1016/j.jssc.2011.03.033

[14] A.P. Surzhikov, A.M. Pritulov, E.N. Lysenko, V.A. Vlasov, E.A. Vasendina, A.V. Malyshev. Analysis of the phase composition and homogeneity of ferrite lithium-substituted powders by the thermomagnetometry method, J. Therm. Anal. Calorim. 112 (2013) 739-745.

DOI: 10.1007/s10973-012-2618-6

[15] S.S. Teixeira, M.P.F. Grac, L.C. Costa. Dielectric, morphological and structural properties of lithium ferrite powders prepared by solid state method, J. Noncryst. Solids. 358 (2012) 1924-1929.

DOI: 10.1016/j.jnoncrysol.2012.06.003

[16] B.S. Randhawa, H.S. Dosanjh, N. Kumar. Synthesis of lithium ferrite by precursor and combustion methods: a comparative study, J. Radioanal. Nucl. Chem. 274 (2007) 581-591.

DOI: 10.1007/s10967-006-6924-y

[17] V. Verma, V. Pandey, R.P. Aloysius, S. Annapoorni, R.K. Kotanala. Comparative study of structural and magnetic properties of nanocrystalline Li0.5Fe2.5O4 prepared by various methods, Phys B. 404 (2009) 2309-2314.

DOI: 10.1016/j.physb.2009.04.034

[18] G. Aravind, M. Raghasudha, D.M. Ravinder, R. Manivel, S.S. Meena, P. Bhatt. Study of structural and magnetic properties of Li–Ni nanoferrites synthesized by citrate-gel auto combustion method, Ceram. Int. 42 (2016) 2941-2950.

DOI: 10.1016/j.ceramint.2015.10.077

[19] M. Tabuchi, K. Ado, H. Sakaebe, C. Masquelier, H. Kageyama, O. Nakamura. Preparation of AFeO2 (A = Li, Na) by hydrothermal method, Solid State Ion. 79 (1995) 220-226.

DOI: 10.1016/0167-2738(95)00065-e

[20] V. Berbenni, G. Bruni, C. Milanese, A. Girella, A. Marini. Synthesis and characterization of LaFeO3 powders prepared by a mixed mechanical/thermal processing route, J. Therm. Anal. Calorim. 133 (2018) 413-419.

DOI: 10.1007/s10973-017-6878-z

[21] T.T. Parlak, F. Apaydin, K. Yildiz. Formation of SrTiO3 in mechanically activated SrCO3–TiO2 system, J. Therm. Anal. Calorim. 127 (2017) 63-69.

DOI: 10.1007/s10973-016-5385-y

[22] V. Mihalache. Thermal analysis of ball-milled Fe–14Cr–3 W–0.4Ti–0.25Y2O3 ferritic steel powder, J Therm. Anal. Calorim. 124 (2016) 1179-1192.

DOI: 10.1007/s10973-016-5304-2

[23] V. Berbenni, A. Marini, P. Matteazzi, R. Ricceri, N.J. Welham. Solid-state formation of lithium ferrites from mechanically activated Li2CO3–Fe2O3 mixtures, J. Eur. Ceram. Soc. 23 (2003) 527-536.

DOI: 10.1016/s0955-2219(02)00150-4

[24] H.M. Widatallah, C. Johnson, F.J. Berry. The influence of ball milling and subsequent calcination on the formation of LiFeO2, J. Mater. Sci. 37 (2002) 4621-4625.

[25] M. Kavanlooee, B. Hashemi, H. Maleki-Ghaleh, J. Kavanlooee. Effect of annealing on phase evolution, microstructure, and magnetic properties of nanocrystalline ball-milled LiZnTi ferrite, J. Electron. Mater. 41 (2012) 3082-3086.

DOI: 10.1007/s11664-012-2235-y

[26] S.H. Gee, Y.K. Hong, M.H. Park, D.W. Erickson, P.J. Lamb. Synthesis of nanosized (Li0.5xFe0.5xZn1-x)Fe2O4 particles and magnetic properties, J. Appl. Phys. 91 (2002) 7586–7588.

[27] H.M. Widatallah, X.L. Ren, I.A. Al-Omari. The influence of TiO2 polymorph, mechanical milling and subsequent sintering on the formation of Ti-substituted spinel-related Li0.5Fe2.5O4, J. Mater. Sci. 41 (2006) 6333-6338.

DOI: 10.1007/s10853-006-0721-4

[28] A.P. Surzhikov, E.N. Lysenko, A.V. Malyshev, A.M. Pritulov, O.G. Kazakovskaya Influence of mechanical activation of initial reagents on synthesis of lithium ferrite, Russ. Phys. J. 6 (2012) 672-677.

DOI: 10.1007/s11182-012-9865-7

[29] A.P. Surzhikov, E.N. Lysenko, V.A. Vlasov, A.V. Malyshev, E.V. Nikolaev. Thermal analysis study of solid-phase synthesis of zinc- and titanium-substituted lithium ferrites from mechanically activated reagents, J. Therm. Anal. Calorim. 122 (2015) 1347-1353.

DOI: 10.1007/s10973-015-4849-9

[30] E.N. Lysenko, E.V. Nikolaev, V.A. Vlasov, A.P. Surzhikov, Microstructure and reactivity of Fe2O3-Li2CO3-ZnO ferrite system ball-milled in a planetary mill, Thermochim. Acta. 664 (2018) 100-107.

DOI: 10.1016/j.tca.2018.04.015

[31] E.N. Lysenko, A.P. Surzhikov, E.V. Nikolaev, V.A. Vlasov. Thermal analysis study of LiFeO2 formation from Li2CO3–Fe2O3 mechanically activated reagents, J. Therm. Anal. Calor. 134 (2018) 81-87.

DOI: 10.1007/s10973-018-7113-2

[32] V. Berbenni, A. Marini, P. Matteazzi, R. Ricceri, N.J. Welham. Solid-state formation of lithium ferrites from mechanically activated Li2CO3–Fe2O3 mixtures, J. Eur. Ceram. Soc. 23 (2003) 527-536.

DOI: 10.1016/s0955-2219(02)00150-4